CHEMICAL PRINCIPLES (LL) W/ACCESS
CHEMICAL PRINCIPLES (LL) W/ACCESS
7th Edition
ISBN: 9781319421175
Author: ATKINS
Publisher: MAC HIGHER
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Chapter 1, Problem 1C.2E

(a)

Interpretation Introduction

Interpretation:

The wavelength for the transition for helium atom from forth energy level to first energy level has to be determined.

Concept Introduction:

Energy separation between the levels can be calculated using following equation.

    En2En1=(n22n12)h28mL2=hν

The frequency (ν), wavelength (λ) and velocity of light (c) are related by following equation.

    λ=cν

(a)

Expert Solution
Check Mark

Answer to Problem 1C.2E

The wavelength for the transition for helium atom is 2.192nm.

Explanation of Solution

Transition is taking place from forth energy level to first energy level.

The length of the box is given as 100pm.

The energy difference for the transition is given below.

    En2En1=(n22n12)h28mL2=hνE4E1=15h28mL2=hν15h8mL2=ν

Therefore the wavelength can be calculated as follows,

    λ=cνλ=8mcL215h=8(9.10939×1031kg)×(2.988×108m/s)(1010m)215×(6.626×1034J.s)=2.192×109m=2.192nm.

Wavelength is 2.192nm.

(b)

Interpretation Introduction

Interpretation:

The wavelength for the transition for hydrogen atom from forth energy level to second energy level has to be determined.

Concept Introduction:

Refer to part (a).

(b)

Expert Solution
Check Mark

Answer to Problem 1C.2E

The wavelength for the transition for helium atom is 2.74nm.

Explanation of Solution

Transition is taking place from forth energy level to second energy level.

The length of the box is given as 100pm.

The energy difference for the transition is given below.

    En2En1=(n22n12)h28mL2=hνE4E2=12h28mL2=hν12h8mL2=ν

Therefore the wavelength can be calculated as follows,

    λ=cνλ=8mcL212h=8(9.10939×1031kg)×(2.988×108m/s)(1010m)212×(6.626×1034J.s)=2.74×109m=2.74nm.

Wavelength is 2.74nm.

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Chapter 1 Solutions

CHEMICAL PRINCIPLES (LL) W/ACCESS

Ch. 1 - Prob. 1A.8ECh. 1 - Prob. 1A.9ECh. 1 - Prob. 1A.10ECh. 1 - Prob. 1A.11ECh. 1 - Prob. 1A.12ECh. 1 - Prob. 1A.13ECh. 1 - Prob. 1A.14ECh. 1 - Prob. 1A.15ECh. 1 - Prob. 1A.16ECh. 1 - Prob. 1A.17ECh. 1 - Prob. 1B.1ASTCh. 1 - Prob. 1B.1BSTCh. 1 - Prob. 1B.2ASTCh. 1 - Prob. 1B.2BSTCh. 1 - Prob. 1B.3ASTCh. 1 - Prob. 1B.3BSTCh. 1 - Prob. 1B.4ASTCh. 1 - Prob. 1B.4BSTCh. 1 - Prob. 1B.5ASTCh. 1 - Prob. 1B.5BSTCh. 1 - Prob. 1B.1ECh. 1 - Prob. 1B.2ECh. 1 - Prob. 1B.3ECh. 1 - Prob. 1B.4ECh. 1 - Prob. 1B.5ECh. 1 - Prob. 1B.6ECh. 1 - Prob. 1B.7ECh. 1 - Prob. 1B.8ECh. 1 - Prob. 1B.9ECh. 1 - Prob. 1B.10ECh. 1 - Prob. 1B.11ECh. 1 - Prob. 1B.12ECh. 1 - Prob. 1B.13ECh. 1 - Prob. 1B.14ECh. 1 - Prob. 1B.15ECh. 1 - Prob. 1B.16ECh. 1 - Prob. 1B.17ECh. 1 - Prob. 1B.18ECh. 1 - Prob. 1B.19ECh. 1 - Prob. 1B.21ECh. 1 - Prob. 1B.22ECh. 1 - Prob. 1B.23ECh. 1 - Prob. 1B.24ECh. 1 - Prob. 1B.25ECh. 1 - Prob. 1B.26ECh. 1 - Prob. 1B.27ECh. 1 - Prob. 1B.28ECh. 1 - Prob. 1C.1ASTCh. 1 - Prob. 1C.1BSTCh. 1 - Prob. 1C.1ECh. 1 - Prob. 1C.2ECh. 1 - Prob. 1C.3ECh. 1 - Prob. 1C.7ECh. 1 - Prob. 1D.1ASTCh. 1 - Prob. 1D.1BSTCh. 1 - Prob. 1D.2ASTCh. 1 - Prob. 1D.2BSTCh. 1 - Prob. 1D.1ECh. 1 - Prob. 1D.2ECh. 1 - Prob. 1D.3ECh. 1 - Prob. 1D.4ECh. 1 - Prob. 1D.5ECh. 1 - Prob. 1D.6ECh. 1 - Prob. 1D.7ECh. 1 - Prob. 1D.9ECh. 1 - Prob. 1D.10ECh. 1 - Prob. 1D.11ECh. 1 - Prob. 1D.12ECh. 1 - Prob. 1D.13ECh. 1 - Prob. 1D.14ECh. 1 - Prob. 1D.15ECh. 1 - Prob. 1D.16ECh. 1 - Prob. 1D.17ECh. 1 - Prob. 1D.18ECh. 1 - Prob. 1D.19ECh. 1 - Prob. 1D.20ECh. 1 - Prob. 1D.21ECh. 1 - Prob. 1D.22ECh. 1 - Prob. 1D.23ECh. 1 - Prob. 1D.24ECh. 1 - Prob. 1D.25ECh. 1 - Prob. 1D.26ECh. 1 - Prob. 1E.1ASTCh. 1 - Prob. 1E.1BSTCh. 1 - Prob. 1E.2ASTCh. 1 - Prob. 1E.2BSTCh. 1 - Prob. 1E.1ECh. 1 - Prob. 1E.2ECh. 1 - Prob. 1E.3ECh. 1 - Prob. 1E.4ECh. 1 - Prob. 1E.5ECh. 1 - Prob. 1E.7ECh. 1 - Prob. 1E.8ECh. 1 - Prob. 1E.9ECh. 1 - Prob. 1E.10ECh. 1 - Prob. 1E.11ECh. 1 - Prob. 1E.12ECh. 1 - Prob. 1E.13ECh. 1 - Prob. 1E.14ECh. 1 - Prob. 1E.15ECh. 1 - Prob. 1E.16ECh. 1 - Prob. 1E.17ECh. 1 - Prob. 1E.18ECh. 1 - Prob. 1E.19ECh. 1 - Prob. 1E.20ECh. 1 - Prob. 1E.21ECh. 1 - Prob. 1E.22ECh. 1 - Prob. 1E.23ECh. 1 - Prob. 1E.24ECh. 1 - Prob. 1E.25ECh. 1 - Prob. 1E.26ECh. 1 - Prob. 1F.1ASTCh. 1 - Prob. 1F.1BSTCh. 1 - Prob. 1F.2ASTCh. 1 - Prob. 1F.2BSTCh. 1 - Prob. 1F.3BSTCh. 1 - Prob. 1F.1ECh. 1 - Prob. 1F.2ECh. 1 - Prob. 1F.3ECh. 1 - Prob. 1F.4ECh. 1 - Prob. 1F.5ECh. 1 - Prob. 1F.6ECh. 1 - Prob. 1F.7ECh. 1 - Prob. 1F.8ECh. 1 - Prob. 1F.10ECh. 1 - Prob. 1F.11ECh. 1 - Prob. 1F.12ECh. 1 - Prob. 1F.13ECh. 1 - Prob. 1F.14ECh. 1 - Prob. 1F.15ECh. 1 - Prob. 1F.17ECh. 1 - Prob. 1F.18ECh. 1 - Prob. 1F.19ECh. 1 - Prob. 1F.22ECh. 1 - Prob. 1.1ECh. 1 - Prob. 1.2ECh. 1 - Prob. 1.3ECh. 1 - Prob. 1.9ECh. 1 - Prob. 1.10ECh. 1 - Prob. 1.11ECh. 1 - Prob. 1.12ECh. 1 - Prob. 1.13ECh. 1 - Prob. 1.14ECh. 1 - Prob. 1.15ECh. 1 - Prob. 1.17ECh. 1 - Prob. 1.19ECh. 1 - Prob. 1.21ECh. 1 - Prob. 1.22ECh. 1 - Prob. 1.23ECh. 1 - Prob. 1.24ECh. 1 - Prob. 1.25ECh. 1 - Prob. 1.27ECh. 1 - Prob. 1.28ECh. 1 - Prob. 1.31E
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