General Chemistry
General Chemistry
4th Edition
ISBN: 9781891389603
Author: Donald A. McQuarrie, Peter A. Rock, Ethan B. Gallogly
Publisher: University Science Books
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Chapter 1, Problem 1.33P
Interpretation Introduction

Interpretation:

Area of circle that is 20.55cm in diameter has to be calculated to correct number of significant figures.

Concept Introduction:

Precision of the quantities that are measured use the significant figures to express the result.  There are six rules for determining the number of significant figures.  They are given as follows.

  • Nonzero digits and the zeros that are present between nonzero digits are significant.
  • Zeros that are used merely to position the decimal are not significant.
  • If zeros are present in the right end of the decimal point, then the zeros are significant.
  • If zeros are present in the result are not in right of the decimal point, then the zeros may or may not be significant.
  • If the zeros disappear when scientific notation is used means then those zeros are not significant.
  • Exact numbers have no limit to their precision and they do not obey the rules given for significant figures.

Answer for a calculation should be always expressed in least significant figures in case of multiplication and division.

In case of addition and subtraction, the answer should have least significant figures after the decimal point.

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3. a. Use the periodic table to add up the molecular weight of thionyl chloride (SOCl2) and show your work. b. The actual value obtained for the molecular ion on a high resolution mass spectrometer is 117.9041. Explain the discrepancy. c. Show the calculations that correctly result in the exact mass of 117.9041 for SOC₁₂. Use Table 11.2 or Appendix E in your calculations.
6. Draw the molecular orbital diagram shown to determine which of the following is paramagnetic. B₂2+ B22+, B2, C22, B22- and N22+ Molecular Orbital Diagram B2 C22- B22- N22+ Which molecule is paramagnetic?
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