Concept explainers
(a)
Interpretation:
The IUPAC name for the given halogenated hydrocarbon has to be given.
Concept Introduction:
The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.
Similar to the alkyl groups, the halogen is also treated as substituents present on the carbon chain. They are called as fluoro-, chloro-, bromo-, and iodo-.
If the carbon chain contains both alkyl and halogen, they both are considered of equal ranks. The numbering is done in a way so that the substituents get the least number, whether it is an alkyl or a halo group.
In IUPAC names, the groups that are present on the carbon chain are written in alphabetical order.
Common names:
Halogenated alkanes are also named as
(b)
Interpretation:
The IUPAC name for the given halogenated hydrocarbon has to be given.
Concept Introduction:
The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.
IUPAC nomenclature for halogenated alkanes/cycloalkanes:
Similar to the alkyl groups, the halogen is also treated as substituents present on the carbon chain. They are called as fluoro-, chloro-, bromo-, and iodo-.
If the carbon chain contains both alkyl and halogen, they both are considered of equal ranks. The numbering is done in a way so that the substituents get the least number, whether it is an alkyl or a halo group.
In IUPAC names, the groups that are present on the carbon chain are written in alphabetical order.
Common names:
Halogenated alkanes are also named as alkyl halides. These are not IUPAC names. They are common names. In a common name, two parts are present. First part is the name of the hydrocarbon (alkyl group). Second part gives the halogen present in the compound. The halogen is considered as though it is present as an ion even though no ions are present.
(c)
Interpretation:
The IUPAC name for the given halogenated hydrocarbon has to be given.
Concept Introduction:
The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.
IUPAC nomenclature for halogenated alkanes/cycloalkanes:
Similar to the alkyl groups, the halogen is also treated as substituents present on the carbon chain. They are called as fluoro-, chloro-, bromo-, and iodo-.
If the carbon chain contains both alkyl and halogen, they both are considered of equal ranks. The numbering is done in a way so that the substituents get the least number, whether it is an alkyl or a halo group.
In IUPAC names, the groups that are present on the carbon chain are written in alphabetical order.
Common names:
Halogenated alkanes are also named as alkyl halides. These are not IUPAC names. They are common names. In a common name, two parts are present. First part is the name of the hydrocarbon (alkyl group). Second part gives the halogen present in the compound. The halogen is considered as though it is present as an ion even though no ions are present.
(d)
Interpretation:
The IUPAC name for the given halogenated hydrocarbon has to be given.
Concept Introduction:
The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.
IUPAC nomenclature for halogenated alkanes/cycloalkanes:
Similar to the alkyl groups, the halogen is also treated as substituents present on the carbon chain. They are called as fluoro-, chloro-, bromo-, and iodo-.
If the carbon chain contains both alkyl and halogen, they both are considered of equal ranks. The numbering is done in a way so that the substituents get the least number, whether it is an alkyl or a halo group.
In IUPAC names, the groups that are present on the carbon chain are written in alphabetical order.
Common names:
Halogenated alkanes are also named as alkyl halides. These are not IUPAC names. They are common names. In a common name, two parts are present. First part is the name of the hydrocarbon (alkyl group). Second part gives the halogen present in the compound. The halogen is considered as though it is present as an ion even though no ions are present.
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Chapter 1 Solutions
EBK ORGANIC AND BIOLOGICAL CHEMISTRY
- Q4: Rank the relative nucleophilicity of halide ions in water solution and DMF solution, respectively. F CI Br | Q5: Determine which of the substrates will and will not react with NaSCH3 in an SN2 reaction to have a reasonable yield of product. NH2 Br Br Br .OH Brarrow_forwardClassify each molecule as optically active or inactive. Determine the configuration at each H соон Chirality center OH 애 He OH H3C Ноос H H COOH A K B.arrow_forwardQ1: Rank the relative nucleophilicity of the following species in ethanol. CH3O¯, CH3OH, CH3COO, CH3COOH, CH3S Q2: Group these solvents into either protic solvents or aprotic solvents. Acetonitrile (CH3CN), H₂O, Acetic acid (CH3COOH), Acetone (CH3COCH3), CH3CH2OH, DMSO (CH3SOCH3), DMF (HCON(CH3)2), CH3OHarrow_forward
- Don't used hand raiting and don't used Ai solutionarrow_forward10. The main product of the following reaction is [1.1:4',1"-terphenyl]-2'-yl(1h-pyrazol-4- yl)methanone Ph N-H Pharrow_forwardDraw the Fischer projection for a D-aldo-pentose. (aldehyde pentose). How many total stereoisomers are there? Name the sugar you drew. Draw the Fischer projection for a L-keto-hexose. (ketone pentose). How many total stereoisomers are there? Draw the enantiomer.arrow_forward
- Draw a structure using wedges and dashes for the following compound: H- Et OH HO- H H- Me OHarrow_forwardWhich of the following molecules are NOT typical carbohydrates? For the molecules that are carbohydrates, label them as an aldose or ketose. HO Он ОН ОН Он ОН но ΤΗ HO ОН HO eve Он он ОН ОН ОН If polyethylene has an average molecular weight of 25,000 g/mol, how many repeat units are present?arrow_forwardDraw the a-anomer cyclized pyranose Haworth projection of the below hexose. Circle the anomeric carbons. Number the carbons on the Fischer and Haworth projections. Assign R and S for each chiral center. HO CHO -H HO -H H- -OH H -OH CH₂OH Draw the ẞ-anomer cyclized furanose Haworth projection for the below hexose. Circle the anomeric carbons. Number the carbons on the Fischer and Haworth projections. HO CHO -H H -OH HO -H H -OH CH₂OHarrow_forward
- Name the below disaccharide. Circle any hemiacetals. Identify the numbering of glycosidic linkage, and identify it as a or ẞ. OH HO HO OH HO HO HO OHarrow_forwardWhat are the monomers used to make the following polymers? F. а. b. с. d. Вецер хочому なarrow_forward1. Propose a reasonable mechanism for the following transformation. I'm looking for curved mechanistic arrows and appropriate formal charges on intermediates. OMe MeO OMe Me2N NMe2 OTBS OH xylenes OMe 'OTBSarrow_forward
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