Answered: D D ОН A НО. B で رات 16-12-31 ↓ 01O ↑…

Science

Biochemistry

D D ОН A НО. B で رات 16-12-31 ↓ 01O ↑ 010 0. + FIO Tyrosine radical Tyr OH H- HO. 02 04. 04 OH

Body Structures & Functions Updated

13th Edition

ISBN:9780357191606

Author:Scott

Publisher:Scott

Chapter6: Skeletal System

Section: Chapter Questions

Problem 3CS

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Question

the two derivatives of arachidonic acid shown below (A and B) have been prepared. These derivatives are
selectively deuterated (i.e. the H atoms at these doubly allylic positions have been replaced with deuterium atoms. This is a very common strategy to elucidate reaction mechanisms. Please predict where the deuterium atoms would end up in the product of the cyclization reaction catalyzed by the enzyme.

initiated by a tyrosyl radical by the enzyme

Im stuck on it

で
رات
16-12-31
↓
01O
↑
010
0.
+
FIO
Tyrosine radical
Tyr
OH
H-
HO.
02
04.
04
OH

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