(b) Assign the priorities (as either high and low, or 1 and 2) for the groups of the alkene. Based on those assigned priorities, predict the configuration (E or Z). Include the priority directly adjacent to the corresponding group. -Br OH
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- Draw the major organic product(s) for the following reactions, including stereochemistry when appropriate5 (a) (8 pts) (a) Box the most stable Z alkene (make sure it's Z!). (b) Circle the least stable E alkene. (c) Label two alkenes which are neither E or Z. NH₂ 5 Je č F HO NH₂ SH 5(b) (4 pts) Draw an example of two conformations of a molecule of your choice, and then draw a separate example of two stereoisomers of another molecule of your choice.Please answer very soon will give rating surely
- Consider the reaction between (1S,3S)-1-chloro-3-methylcyclopentane and methanethiol in the presence of sodium hydroxide. (a) Draw the organic product and clearly indicate stereochemistry by showing the hydrogen on the chirality centers and using wedge and dash bonds. (b) Then analyze the stereochemistry of the product. -SH C NaOH Draw only the organic product. Select /// Draw Rings More C H S Erase:Draw an approximate energy diagram withannotations for the rotamers of 1,2-dibromoethanefrom 0-180°. Give the Newman projections andnames of the most important rotamers.Hw.198.
- #6). Second picture shows how to use arrows correctly.An alkene having the molecular formula C11H20 is treated sequentially with ozone (O3) and zinc/acetic acid to give the product/s shown. CH;CH2ČCH,CH3 Draw a structural formula for the alkene. • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. In cases where there is more than one answer, just draw one. C opy aste ChemDoodleNot sure what substitution goes here for the SN2 reaction
- Arrange the substituents in order of decreasing priority when determining E/Z stereochemistry of an alkene (i.e., 1 is the highest priority substituent, 4 is the lowest priority substituent). – NHCH3 II - CH v - OCH3 -CH,CI >1-Chloro-1,2-diphenylethane can undergo E2 elimination to give either cis- or trans-1,2-diphenylethylene (stilbene). Draw Newman projections of the reactive conformations leading to both possible products, and suggest a rea- son why the trans alkene is the major product. 1) -CHCH2- "OCH3 -CH=CH- 1-Chloro-1,2-diphenylethane trans-1,2-Diphenylethylene 2) 1 Predict the major alkene product of the following E1 reaction: HOAC CH3CHCBr ? Heat ČH;CH3Macmillan Learning Alkenes can be converted to alcohols by hydroboration-oxidation. (a) Draw the structure of the alcohol or alcohols formed in the reaction sequence. Clearly indicate stereochemistry by drawing a wedged bond, a dashed bond and two in-plane bonds per each chiral carbon. Draw hydrogen atoms that are connected to wedge-and-dash bonds.(b) Characterize the product or products of the reactions. e 1. B₂H6, diglyme 2. H₂O₂, HO™, H₂O Be sure to draw hydrogens on oxygen, where applicable. Select Draw Rings More C H O Erase