Provide the complete mechanism for the reaction below. You must include appropriate arrows, intermediates, and formal charges. I xylenes, 110 °C
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Provide the complete mechanism for the reaction below. You must include appropriate arrows,
intermediates, and formal charges. Please draw out.
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- Provide the structure(s) of the expected major organic product of the reaction shown. 1) Disiamylborane 2) H₂O₂, NaOH OI O II ||| O IV OV CH3CH₂C(CH3)2C=CH OH OH xx xo IVa) b) - Fill in the reagents above/below the arrow in the following reactions. c) CN F CO₂H OH Хон1) Draw the complete electron-pushing arrow mechanism for the following reductions. Explain, using resonance contributors (structures), the regiochemistry that results in each case. OMe Na, MeOH ? NH3 CHO Na, MeOH ? NH3
- CH3 CH3 CH3 CH;=ĊCH,CHCH;OH H2SO4, H3C H3C Referring to the above reaction: 1. Which atom does the H2SO4 first remove? 2. Identify the reaction if it's hydrogenation, hydrohalogenation, etc. 3. Propose a mechanism for the reaction, using the arrow formalism to indicate the flow of electrons.Predict the product and draw the complete mechanism for the Wittig reaction shown below. Show all lone pairs of electrons and formal charges where applicable. Remember to pay attention to E/Z stereochemistry of the alkene.4) Draw the complete electron-pushing arrow mechanism for the following reductions. Explain, using resonance contributors, the regiochemistry that results in each case. ỌMe Na, MeOH ? NH3 CHO Na, MeOH ? NH3
- МЕСНANISMS 1,2-epoxy-1-methylcyclopentane undergoes both acid-catalyzed and base-catalyzed opening of the epoxide ring to form two different products. > Using ethanol as the solvent and an appropriate acid, show the steps in the acid catalyzed mechanism, writing structures for all products of the steps. Circle the major product(s). > Using ethanol as the solvent and an appropriate base, show the steps in the base- catalyzed mechanism, writing structures for all products of the steps. Circle the major product(s). 1,2-epoxy-1-methylcyclopentane CH3Acid-catalyzed a-halogenation is a useful reaction for synthesis, especially regarding substitution and elimination reactions. Provide the missing structures (A-C) for the following mini road map. H Br₂ H3O+ A E2 | NaNH2 C NaO SN2 BWrite the appropriate reagents, conditions and products for the following transformations, in a single step. KMNO, OH', heat
- 7. Give a Mechanism for the following reaction; show formal charges and significant intermediates. e CH3CH₂NH2 H3O+ N CH₂CH3 + H₂O12) Use the curved arrow formalism to show the movement of electron pairs in the following reaction and label each reactant as a nucleophile or an electrophile. CHÍNH CHỊCH, + CO Học Nha CH₂CH₂CIBelow is a mechanism that represents the following single reaction sequence: a certain alcohol undergoes acid- catalyzed dehydration (conversion that involves the loss of water from the reacting molecule or ion) to form an alkene product. Write the IUPAC name of the product. Include E/Z stereochemistry. Hint: Name of the substituent of the product is similar to that of reactant.