Macmillan Learning A 0.4400 g sample of pewter, containing tin, lead, copper, and zinc, was dissolved in acid. Tin was precipitated as SnO2 · 4 H₂O and removed by filtration. The resulting filtrate and washings were diluted to a total volume of 250.0 mL. A 15.00 mL aliquot of this solution was buffered, and titration of the lead, copper, and zinc in solution required 35.84 mL of 0.001532 M EDTA. Thiosulfate was used to mask the copper in a second 20.00 mL aliquot. Titration of the lead and zinc in this aliquot required 34.09 mL of the 0.001532 M EDTA solution. Finally, cyanide was used to mask the copper and the zinc in a third 25.00 mL aliquot. Titration of the lead in this aliquot required 25.01 mL of the 0.001532 M EDTA solution. Determine the percent composition by mass of each metal in the pewter sample.

Macmillan Learning A 0.4400 g sample of pewter, containing tin, lead, copper, and zinc, was dissolved in acid. Tin was precipitated as SnO2 · 4 H₂O and removed by filtration. The resulting filtrate and washings were diluted to a total volume of 250.0 mL. A 15.00 mL aliquot of this solution was buffered, and titration of the lead, copper, and zinc in solution required 35.84 mL of 0.001532 M EDTA. Thiosulfate was used to mask the copper in a second 20.00 mL aliquot. Titration of the lead and zinc in this aliquot required 34.09 mL of the 0.001532 M EDTA solution. Finally, cyanide was used to mask the copper and the zinc in a third 25.00 mL aliquot. Titration of the lead in this aliquot required 25.01 mL of the 0.001532 M EDTA solution. Determine the percent composition by mass of each metal in the pewter sample.

Chemistry by OpenStax (2015-05-04)

1st Edition

ISBN:9781938168390

Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser

Publisher:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser

Chapter18: Representative Metals, Metalloids, And Nonmetals

Section: Chapter Questions

Problem 25E: A chemist dissolves a 1.497-g sample of a type of metal (an alloy of Sn, Pb, Sb, and Cu) in nitric...

See similar textbooks

Similar questions

Magnesium metal (a component of alloys used in aircraft and a reducing agent used in the production of uranium, titanium, and other active metals) is isolated from sea water by the following sequence of reactions: Mg2+(aq)+Ca(OH)2(aq)Mg(OH)2(s)+Ca2+(aq)Mg(OH)2(s)+2HCl(aq)MgCl2(s)+2H2O(l)MgCl2(l)electrolysisMg(s)+Cl2+Cl2(g) Sea water has a density of 1.026 g/cm3 and contains 1272 parts per million of magnesium a5 Mg2+(aq) by mass. What mass, in kilograms, of Ca(OH)2; is required to precipitate 99.9% of the magnesium in 1.00103 L of sea water?
What volume of 0.200 M NaOH is necessary to neutralize the solution produced by dissolving 2.00 g of PCl3 is an excess of water? Note that when H3PO3 i5 titrated under these conditions, only one proton of the acid molecule reacts.
Lead poisoning has been a hazard for centuries. Some scholars believe that the decline of the Roman Empire can be traced, in part, to high levels of lead in water from containers and pipes, and from wine that was stored in leadglazed containers. If we presume that the typical Roman water supply was saturated with lead carbonate, PbCO3 (Ksp = 7.4 1014), how much lead will a Roman ingest in a year if he or she drinks 1 L/day from the container?
1. Sometimes a reaction can fall in more than one category. Into what category (or categories) does the reaction of Ba(OH)2(aq) + H+PO4(aq) fit? acid-base and oxidation-reduction oxidation-reduction acid-base and precipitation precipitation
When 85.0 mL of 0.250 M Ba(OH)2 solution is added to 85.00 mL of 0.250 M Al (NO3)3 solution, a white gelatinous precipitate of Al(OH)3; is formed. Assuming 100% yield, (a) what mass (in grams) of Al(OH)3 is formed? (b) what is the molarity of each of the ions Ba2+, OH-, Al3+, NO3- in the resulting solution?
68. Aluminum ion may be precipitated from aqueous solution by addition of hydroxide ion, forming Al(OH)3. A large excess of hydroxide ion must not be added, however, because the precipitate of Al(OH)3 will redissolve as a soluble compound containing aluminum ions and hydroxide ions begins to form. How many grains of solid NaOH should be added to 10.0 mL of 0.250 M A1Cl3 to just precipitate all the aluminum?
Gold metal will dissolve only in aqua regia, a mixture of concentrated hydrochloric acid and concentrated nitric acid in a 3:1 volume ratio. The products of the reaction between gold and the concentrated acids are AuCl4-(aq), NO(g), and H2O. The equation for this reaction where HNO3 and HCl are strong acids is Au(s)+4Cl(aq)+4H+(aq)+NO3(aq)AuCl4(aq)+NO(g)+2H2O(a) What stoichiometric ratio of hydrochloric acid to nitric acid should be used? (b) What volumes of 12 M HCl and 16 M are HNO3 required to furnish the Cl- and NO3- ions to react with 25.0 g of gold?
A 2.5624-g sample of a pure solid alkali metal chloride is dissolved in water and treated with excess silver nitrate. The resulting precipitate, filtered and dried, weighs 3.03707 g. What was the percent by mass of chloride ion in the original compound? What is the identity of the salt?
Write a balanced net ionic equation for the disproportionation reaction of (a) hypochlorous acid to chlorine gas and chlorous acid in acidic solution. (b) chlorate ion to perchlorate and chlorite ions.
The equivalence point for the titration of a 25.00-mL sample of CSOH solution with 0.1062 M HNO3 is at 35.27 mL. What is the concentration of the CsOH solution?
Iron (II) can be oxidized to iron (III) by dichromate ion, which is reduced to chromium (III) in acid solution. A 2.5000-g sample of iron ore is dissolved and the iron converted into iron(II). Exactly 19.17? ml. of 0.0100 M Na2Cr2O7 is required in the titration. What percentage of the ore sample was iron?
Use the appropriate tables to calculate H for (a) the reaction between MgC03(s) and a strong acid to give Mg2+(aq), CO2(g), and water. (b) the precipitation of iron(III) hydroxide from the reaction between iron(III) and hydroxide ions.