● Electrophilic Addition Reactions Recognizing common alkene addition reactions Explanation Check aption N W H₂ Pd OH 1) Hg(OAc)2, H₂O 2) NaBH4 Cl₂ HBr CI CI Bro hydrohalogenation addition ☐ oxyhydration halogenation ☐ hydrogenation Ohalohydrin formation halohydrin formation addition ☐ dihydrination hydrohalogenation halogenation hydrogenation hydrogenation addition halogenation halohydrin formation hydrohalogenation inhalation hydrogenation halohydrin formation hydrohalogenation addition hydroxation halogenation X * 20 © 2024 McGraw Hill LLC. All Rights Reserved. Terms of Use | Priva B 2 D V K

● Electrophilic Addition Reactions Recognizing common alkene addition reactions Explanation Check aption N W H₂ Pd OH 1) Hg(OAc)2, H₂O 2) NaBH4 Cl₂ HBr CI CI Bro hydrohalogenation addition ☐ oxyhydration halogenation ☐ hydrogenation Ohalohydrin formation halohydrin formation addition ☐ dihydrination hydrohalogenation halogenation hydrogenation hydrogenation addition halogenation halohydrin formation hydrohalogenation inhalation hydrogenation halohydrin formation hydrohalogenation addition hydroxation halogenation X * 20 © 2024 McGraw Hill LLC. All Rights Reserved. Terms of Use | Priva B 2 D V K

Introduction to General, Organic and Biochemistry

11th Edition

ISBN:9781285869759

Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres

Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres

Chapter10: Organic Chemistry

Section: Chapter Questions

Problem 10.40P

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7 Identify the functional group and the IUPAC name for each of the three compounds in the reaction below: H₂SO4(aq) Compound 1 CH₂COOH (1) + CH₂(CH₂)₂OH(1) I || || Functional Group carboxyl hydroxyl Ester linkage + CH3COO(CH₂) CH₂(1) + H₂O(1) IV III IUPAC Name → + +
Classify each chemical reaction as an addition, elimination, isomerization, or nucleophilic substitution. -- H3C-C-O-CH3 + H₂O 11 H3C-C-OH+H3C-OH H₂C=C-COO™ O-P=O OH + H₂O OH ī H H₂C-C-Coo O O-P=O I OH COO™ HC-OH CH₂ COO™ HC=0 H-C-OH CH₂OH COO™ CH || + H₂O CH COO™ CH₂OH C=O I CH₂OH
Ch19. Aldehydes and Ketones: Nucleophilic Addition Reactions Nucleophilic Addition Reaction Aldehydes and ketones are reduced to yield 1° and 2° alcohols, respectively - Reduction (hydride attack: H): NaBH, or LIAIH, (stronger) _H 1) NaBH4 2) HⓇ - Grignard reagents (R-MgX) give alcohols MgBr 1) + - Addition of HCN yields cyanohydrins, RCH(OH)CEN NaCN 2) H₂0* HCN
During multistep syntheses, reduction reactions are often performed. Functional groups react differently with these reagents. With this in mind, draw the structure of the product of this reaction: NH2 NH2 LIAIH4 OH HO2C CO2H ČO2H For your convenience, the starting material has been drawn for you in the sketchpad. P aste opy C NH2 NH2 OH HO, HO
16-17 Propylamine (bp 48°C), ethylmethylamine (bp 37°C), and trimethylamine (bp 3°C) are constitutional isomers with the molecular formula C3HgN. Account for the fact that trimethylamine has the lowest boiling point of the three and propylamine has the highest.
Methyl isocyanate, CH3 -N= C = O, is used in the industrial synthesis of a type of pesticide and herbicide known as a carbamate. As a historical note, an industrial accident in Bhopal, India, in 1984 resulted in leakage of an unknown quantity of this chemical into the air. An estimated 200,000 people were exposed to its vapors, and over 2000 of these people died. Q.) Methyl isocyanate reacts with strong acids, such as sulfuric acid, to form a cation. Will this molecule undergo protonation more readily on its oxygen or nitrogen atom? In considering contributing structures to each hybrid, do not consider structures in which more than one atom has an incomplete octet
c9
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The non-sedating antihistamine cetirizine (trade name Zyrtec) is prepared by a reaction sequence that involves two consecutive substitution reactions. Identify N and O in the following reaction sequence.
Identify the type of reaction mechanism. CH3CH2CHO + HCN→→ CH3CH2CH(OH)CN Nucleophilic Substitution Reaction Elimination Reaction Nucleophilic Addition Reaction
Criteria for satisfactory score Reactants, products, and reagents that complete a reaction scheme must specific compounds, not generic categories. Reagents and structures must be valid Lewis structures. Tasks 1. Complete the synthetic sequences by drawing products/substrates/reagents in empty spaces in reactions below. 2. Draw the mechanism of tautomerization (line 3).
Intramolecular H-bonding (IHB) are interactions that occur within one single molecule. IHB is also known as chelation, since it involves ring formation. Which of the following is (are) stabilized by IHB? a b c d