5) For the following reaction, provide the expected mechanism leading to the major substitution product. Please show all intermediates and use arrows to show the movement of electrons (you do not need to show transition states). (1 pt) CH3OH 25 °C Br
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- In the presence of light or heat, diazomethane (CH,N2) creates a carbene, which then adds to an alkene to make a cyclopropane. In the boxes below. draw the mechanism arrows for the reaction. H INEN: INE N:Consider the reaction scheme below. (i) H3COCHN CO₂Et A H₂N OH EtO OEt B C6H₁1 NO2 base Ha Identify the reagent(s) and conditions A and the intermediate B in this reaction scheme.When treated with NaOH, the bromide below gives an alkene by the E2 mechanism, by elimination of the H atom indicated by the arrow: (a) Draw the Newman projection from which elimination takes place. (b) Draw the mechanism. (c) Draw the product with the proper stereochemistry. (d) Assign the proper stereochemical descriptor to the product. (e) Give the rate equation
- The following reaction can be described by a THREE step mechanism. A drawing of the energy diagram for this reaction is shown below. OH H, SO4 В A Reaction coordinate (i) Write out the three steps in this mechanism. For each step, draw structures for the reactants and products and curved arrows to show bonds formed and bonds broken. (ii) Indicate which of the drawings in your mechanism corresponds to points A, B and C on the energy diagram. Draw the structure of the MAJOR product in the following reaction and an arrow pushing reaction mechanism to showhow the product is formed. H;O+ Potential energy5) 2-methyl-1,3-cyclohexadiene is treated with 1 equivalent of HCl. There are two major products. One product predominates at high temperature, and the other at low temperature. HCI a) Write the mechanism for this reaction. b) Label one product as the high temperature product and one as the low temperature product.N(CH2CH3)3 + HNO3 --------> a.) rewrite the reaction using bond-line structure of reagents and products of the reaction b.) supply the curved arrows explaining the mechanism of the reaction
- 4) Draw the complete electron-pushing arrow mechanism for the following reductions. Explain, using resonance contributors, the regiochemistry that results in each case. ỌMe Na, MeOH ? NH3 CHO Na, MeOH ? NH3Please give the main substitution product for each of the following reactions, and indicate the dominant mechanism: (a) 1-bromopropane + NaOCH3 → (b) 3-bromo-3-methylpentane + NaOC2H5 →For the following sets of substitution reactions that occur via an SN2 mechanism, draw the main organic substitution product (i.e., not the leaving group, for each reaction draw the product, though the products may be equivalent) and indicate which reaction occurs at the faster rate. (a) H3C CH₂O H3C E H3C Br (b) Br CH3O H3C + H3C-Br CH3O- H3C-Br
- (b) Show the mechanism of this reaction using proper arrow push notation. You must show all intermediates, formal charges, and necessary arrows. CH3 CH3 CH3 H20 H2SO4Provide detailed step-wise mechanism for the following reaction. Be sure to show all intermediates, formal charges, and show the movement of electrons with curved arrows. a 4+H₂Q 044 OHNonconjugated , -unsaturated ketones, such as 3-cyclohexenone, are in an acid-catalyzed equilibrium with their conjugated , -unsaturated isomers. Propose a mechanism for this isomerization.