Between these orbitals: s, px, py, pz, dxy, dyz, dxz, dx2-y2, and dz2. Which of them absolutely cannot overlap, and why? If you can, please give me clear explanation (rather than their symmetry doesn't match, please say something like because this orbital approach in this plane/axis, which doesn't match with the one from the other orbital, etc).
Between these orbitals: s, px, py, pz, dxy, dyz, dxz, dx2-y2, and dz2. Which of them absolutely cannot overlap, and why? If you can, please give me clear explanation (rather than their symmetry doesn't match, please say something like because this orbital approach in this plane/axis, which doesn't match with the one from the other orbital, etc).
Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter14: Rotational And Vibrational Spectroscopy
Section: Chapter Questions
Problem 14.13E
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Between these orbitals: s, px, py, pz, dxy, dyz, dxz, dx2-y2, and dz2. Which of them absolutely cannot overlap, and why? If you can, please give me clear explanation (rather than their symmetry doesn't match, please say something like because this orbital approach in this plane/axis, which doesn't match with the one from the other orbital, etc).
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