8.10 Referring to the description of bonding in diborane inFigure 8.12:a. Show that the representation I (p2) reduces to Ag + B₁ub. Show that the representation I(p) reduces to B2g + Bзuc. Show that the representation F(1s) reduces to Ag + Bзud. Using the D2h character table, verify that the sketchesfor the group orbitals match their respective symmetrydesignations (Ag, B2g, B1, B3).

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Answered: 8.10 Referring to the description of…

Chemistry

9th Edition

ISBN:9781133611097

Author:Steven S. Zumdahl

Publisher:Steven S. Zumdahl

Chapter9: Covalent Bonding: Orbitals

Section: Chapter Questions

Problem 2ALQ: Explain the difference between the and MOs for homonuclear diatomic molecules. How are bonding and...

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Using the accompanying figure, state which molecular orbital (2s, 2p, or 2p) has an ionization energy of 15.6 eV.
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8.2 The species He₂+ and HeH* have been observed spectro- scopically. Prepare molecular orbital diagrams for these two ions. What would you predict for the bond order of each?
About the special type of hybridization involved in complexation (all are correct except Select one: 1- in case of d2sp3 hybridization trigonal (square planner) shape complex is obtained while in case of dsp2 hybridization a hexagonal shape complex is obtained 2- dsp2 hybridization is obtained when the transient metal orbitals d orbitals , one S and 2 p orbitals are mixed together to obtain six equivalent d2sp3 orbitals forming a hexagonal shape complex 3- in case of six guests containing complex like ormaplatine d2sp3 hybridization is encountered while in case of cisplatin dsp2 hybridization is encountered 4- d2sp3 hybridization is obtained when the transient metal orbitals 2 d orbitals , one S and 3 p orbitals are mixed together to obtain six equivalent d2sp3 orbitals forming a hexagonal shape complex
Indicate FALSE and TRUE statements. Explain briefly your each answer. ………Bond energy of N2 is larger than that of O2. ……… 24Cr and 29Cu have the electron configurations 3d44s2 and 3d94s2. ………The symmetry species for doubly and triply degenerate representations are designated as A and B. ………NCl5 is a stable molecule but PCl5 is not stable. ………The point group of GeCl4 is Oh. ………The ionization energies of the group II A metals are in the order Ba>Sr>Ca>Mg. ………The radius increases as nuclear charge increases for ions with the same electronic structure such as O2-, F-, Na+, Mg2+.
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Which species contain a C4 axis and a on plane? XeF4 [ICI,] SiF 4 [SO,j?- SnH,
4
Sagggg
Second-row diatomics For molecules containing atoms with electrons in p orbitals, energy-level diagrams become more complex. Core electrons are usually omitted from MO energy level diagrams. Discuss with your group or the class the following: (a) (b) Why are core electrons usually omitted? For the second-row diatomics what is the lowest MO formed from valence shell orbitals? Describe how molecular orbitals are formed from atomic orbitals. Would you expect them to be higher or lower in energy than a (sigma) molecular orbitals? (c) As the nuclear charge increases, the energies of all orbitals are lowered, as shown in the figure below for homonuclear diatomics. Why does this happen? 620x Li₂ Bez 1 0₂ F₂ Ne₂ p #p 29 620 625 #20 Note: For molecules smaller than 02, the 2p orbital is higher in energy than the #2p orbitals. An explanation of this can be found on your Moodle course page for those of you who are interested...
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