8.10 Referring to the description of bonding in diborane in Figure 8.12: a. Show that the representation I (p2) reduces to Ag + B₁u b. Show that the representation I(p) reduces to B2g + Bзu c. Show that the representation F(1s) reduces to Ag + Bзu d. Using the D2h character table, verify that the sketches for the group orbitals match their respective symmetry designations (Ag, B2g, B1, B3).
8.10 Referring to the description of bonding in diborane in Figure 8.12: a. Show that the representation I (p2) reduces to Ag + B₁u b. Show that the representation I(p) reduces to B2g + Bзu c. Show that the representation F(1s) reduces to Ag + Bзu d. Using the D2h character table, verify that the sketches for the group orbitals match their respective symmetry designations (Ag, B2g, B1, B3).
Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter6: Quantum Mechanics And Molecular Structure
Section: Chapter Questions
Problem 39P: The photoelectron spectrum of HBr has two main groups of peaks. The first has ionization energy...
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