A 25.00 mL sample containing an unknown amount of Al³ + and Pb² + required 15.73 mL of 0.05631 M EDTA to reach the end point. A 50.00 mL sample of the unknown was then treated with F to mask the A1³ +. To the 50.00 mL sample, 25.00 mL of 0.05631 M EDTA was added. The excess EDTA was then titrated with 0.02203 M Mn² +. A total of 25.9 mL was required to reach the methylthymol blue end point. Determine pAl³ + and pPb² + in the unknown sample.

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
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Chapter17: Complexation And Precipitation Reactions And Titrations
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A 25.00 mL sample containing an unknown amount of Al³ + and Pb² + required 15.73 mL of 0.05631 M EDTA to reach the end
point. A 50.00 mL sample of the unknown was then treated with F to mask the A1³ +. To the 50.00 mL sample, 25.00 mL of
0.05631 M EDTA was added. The excess EDTA was then titrated with 0.02203 M Mn² +. A total of 25.9 mL was required to
reach the methylthymol blue end point. Determine pAl³ + and pPb² + in the unknown sample.
Transcribed Image Text:A 25.00 mL sample containing an unknown amount of Al³ + and Pb² + required 15.73 mL of 0.05631 M EDTA to reach the end point. A 50.00 mL sample of the unknown was then treated with F to mask the A1³ +. To the 50.00 mL sample, 25.00 mL of 0.05631 M EDTA was added. The excess EDTA was then titrated with 0.02203 M Mn² +. A total of 25.9 mL was required to reach the methylthymol blue end point. Determine pAl³ + and pPb² + in the unknown sample.
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