2. Write structural formulas for the products you expect from Friedel-Crafts alkylation or Acylation of benzene with O a) (CH3)3CCCI b) b) CH3CH2CH2Cl CI c) CHCH3
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- Which of the following best describes a key step in the mechanism for the reaction below? HO, ... -CH3 -CH3 + en dihydroxylation H3C- H3C- OH (A) free-radical substitution at the carbonyl carbon B elimination reaction by abstraction of a beta-hydrogen nucleophilic attack by an alkene to form a cyclic (epoxide) intermediate electrophilic addition reaction to form a carbocation intermediate3) Draw the structures of the major organic product(s) for the following reactions. HI in CH₂Cl₂ 3 excess Cl₂ in H₂O H₂SO4 in H₂O (Two products) Br-Cl in THF 1) BH3 2) alkaline H₂O₂ OSO4 + HOOHWhich conditions are best for preparing isopropyl methyl ether? H₂C H₂C c) b) NOCH d) Oa Na Ob 8CH'3 CH3 CH3 CH₂OH CH₂OH + + CH3Br H₂C H₂C CHBr H₂C H₂C CHBr CHOH heat acid catalysis
- Which is the MAJOR product of the following reaction? Et 1) BH3:THF 2) H2O2, NaOH Which of the following best describes a key step in the mechanism for the reaction below? HO ... CH3 -CH3 dihydroxylation + en H3C- H3C- HO. electrophilic addition reaction to form a carbocation intermediate B nucleophilic attack by an alkene to form a cyclic (epoxide) intermediate elimination reaction by abstraction of a beta-hydrogen D free-radical substitution at the carbonyl carbon Which alkene will produce the HIGHEST yield of the alkyl halide below? Br. alkene HBr |the following reaction scheme leads to the formation of compound B. give the structure of the final products and of the intermediate product A and justify, using the mechanism, the formation of theseWrite the mechanism for the following reactions. Explain detail each steps of reactions.a) Halogenation of benzene b) Nitration of benzene c) Sulfonation of benzene
- A 1-butene reacts with can yield butan-1,2-diol when it reacts with potassium permanganate in a basic medium. True or FalseA problem often encountered in the oxidation of primary alcohols to acids is that esters are sometimes produced as by-products. For example, oxidation of ethanol yields acetic acid and ethyl acetate: Propose a mechanism to account for the formation of ethyl acetate. Take into account the reversible reaction between aldehydes and alcohols:Wittig reactions with the following -chloroethers can be used for the synthesis of aldehydes and ketones. (a) Draw the structure of the triphenylphosphonium salt and Wittig reagent formed from each chloroether. (b) Draw the structural formula of the product formed by treating each Wittig reagent with cyclopentanone. Note that the functional group is an enol ether or, alternatively, a vinyl ether. (c) Draw the structural formula of the product formed on acid-catalyzed hydrolysis of each enol ether from part (b).
- Modify the structure of the compound provided to show the skeletal structure of the product that forms when this compound is treated with K₂Cr₂O₂. & 0, XDiazonium salts: From benzene and whatever reagent you want to synthesize the following moleculew how enols, enolate ions, andenamines act as nucleophiles. Predictthe products of their reactions withhalogens, alkyl halides, and otherelectrophiles. Show how they areuseful in synthesis.
