Please correct answer and don't use hand raiting Consider the 14N-160 molecule whose fundamental frequency has a value of 0.0064 cm¹.The equilibrium bond length for the molecule is 115 pm.a) Estimate the ratio of the number of molecules in the first excited vibrational state to thenumber in the ground state, at a temperature of 450 K.(5)b) Take 14N-160 molecule as a linear rigid rotor and determine the ratio of the number ofmolecules in the first excited rotational state to the number in the ground state, at a temperatureof 450 K(10)c) Use the Sackur-Tetrode equation to calculate the molar entropy of the molecule at 1atm and 298 K(10)

Solution:a) Ratio of molecules in the first excited vibrational state to the ground state at 450…

Answered: Consider the 14N-160 molecule whose…

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter20: Molecular Spectroscopy And Photochemistry

Section: Chapter Questions

Problem 58AP

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[References) The vibrational temperature of a molecule prepared in a supersonic jet can be estimated from the observed populations of its vibrational levels, assuming a Boltzmann distribution. The vibrational frequency of CuBr is 9.44×1012 s1, and the ratio of the number of molecules in the n = 1 state to the number in the n = 0 state is 2.59x10 2. Estimate the vibrational temperature under these conditions. (Enter your answer to three significant figures.) K
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