4. The infrared absorption spectrum of a diatomic molecule is shown in the figure. (a) Give the initial (J") and final (J') rotational quantum numbers corresponding to the peaks labeled A and B. (b) Estimate the vibrational frequency in wavenumbers (v) and the rotational constant in wavenumbers (B). (c) From the spacings of the peaks near 2700 cm and near 3050 cm', determine whether the average bond length increases or decreases with increasing vibrational quantum number. 20 18 A B 2500 2600 2700 2800 2900 3000 3100 3200 wavenumber absorption intensity

4. The infrared absorption spectrum of a diatomic molecule is shown in the figure. (a) Give the initial (J") and final (J') rotational quantum numbers corresponding to the peaks labeled A and B. (b) Estimate the vibrational frequency in wavenumbers (v) and the rotational constant in wavenumbers (B). (c) From the spacings of the peaks near 2700 cm and near 3050 cm', determine whether the average bond length increases or decreases with increasing vibrational quantum number. 20 18 A B 2500 2600 2700 2800 2900 3000 3100 3200 wavenumber absorption intensity

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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