A postgraduate student was given the task of predicting the 1H NMR spectrum for compound A.
A postgraduate student was given the task of predicting the 1H NMR spectrum for compound A.
Biochemistry
9th Edition
ISBN:9781319114671
Author:Lubert Stryer, Jeremy M. Berg, John L. Tymoczko, Gregory J. Gatto Jr.
Publisher:Lubert Stryer, Jeremy M. Berg, John L. Tymoczko, Gregory J. Gatto Jr.
Chapter1: Biochemistry: An Evolving Science
Section: Chapter Questions
Problem 1P
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A postgraduate student was given the task of predicting the 1H NMR spectrum for compound A. Compound A is one of the basic amino acid. Tripeptide B is formed through a condensation process between compounds A, C, and D, while monomers E and F are formed by modifying compounds C and A by maintaining the basic structure of amino acid. Compounds C and D are neutral and acidic amino acids, respectively. The addition reaction of monomers E and F forms polymer G.
(a) Illutsrate the potential 1H NMR spectrum for compound A.
(b) Identify the possible structural formula of compound A (according to the
type of hydrogen and carbon) based on your proposed 1H NMR spectrum.
(c) Identify the possible structural formula of compounds B, C, D, E, F and G.
(d) Identify the possible structural formula for repeating unit of polymer G.
(e) Discuss the differences between compound C and cyclic alcohol.
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