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H₂N OH 1) Boc₂O, DMAP 2) 2 eq. NaH 1) Cbz-Cl, DMAP 2) NaH, BnBr 3) 2 eq. CH₂l OH 3) NaH OH OH 4) NaOH 5) TFA H₂N 4) CH₂l 5) H₂, Pd cat. 1) LOH BocHN OH 2) BocHN 3) 5) 5) OH OH Bn Cbz OH BocHN Cbz 2) Bn Cbz BocHN 3) Cbz Bn NH ΗΝ ΟΗ ΝΗ MK-0616 NH ΗΝ

H₂N OH 1) Boc₂O, DMAP 2) 2 eq. NaH 1) Cbz-Cl, DMAP 2) NaH, BnBr 3) 2 eq. CH₂l OH 3) NaH OH OH 4) NaOH 5) TFA H₂N 4) CH₂l 5) H₂, Pd cat. 1) LOH BocHN OH 2) BocHN 3) 5) 5) OH OH Bn Cbz OH BocHN Cbz 2) Bn Cbz BocHN 3) Cbz Bn NH ΗΝ ΟΗ ΝΗ MK-0616 NH ΗΝ

Biochemistry
Biochemistry
9th Edition
ISBN:9781319114671
Author:Lubert Stryer, Jeremy M. Berg, John L. Tymoczko, Gregory J. Gatto Jr.
Publisher:Lubert Stryer, Jeremy M. Berg, John L. Tymoczko, Gregory J. Gatto Jr.
Chapter1: Biochemistry: An Evolving Science
Section: Chapter Questions
Problem 1P
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Perform a peptide coupling reaction to connect the two amino acids together plus if any other reagents to create the green molecule
H₂N OH 1) Boc₂O, DMAP 2) 2 eq. NaH 1) Cbz-Cl, DMAP 2) NaH, BnBr 3) 2 eq. CH₂l OH 3) NaH OH OH 4) NaOH 5) TFA H₂N 4) CH₂l 5) H₂, Pd cat. 1) LOH BocHN OH 2) BocHN 3) 5) 5) OH OH Bn Cbz OH BocHN Cbz 2) Bn Cbz BocHN 3) Cbz Bn
Transcribed Image Text:H₂N OH 1) Boc₂O, DMAP 2) 2 eq. NaH 1) Cbz-Cl, DMAP 2) NaH, BnBr 3) 2 eq. CH₂l OH 3) NaH OH OH 4) NaOH 5) TFA H₂N 4) CH₂l 5) H₂, Pd cat. 1) LOH BocHN OH 2) BocHN 3) 5) 5) OH OH Bn Cbz OH BocHN Cbz 2) Bn Cbz BocHN 3) Cbz Bn
NH ΗΝ ΟΗ ΝΗ MK-0616 NH ΗΝ
Transcribed Image Text:NH ΗΝ ΟΗ ΝΗ MK-0616 NH ΗΝ
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