Prelab Introduction to Qualitative Analysis part 2
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Name: Guillermo Rumbos Panther ID: 6206887 Course and section number: CHM 1045L U01 TA Name: Giselle Castano Date: 05 /28/ 2024 Prelab Introduction to Qualitative Analysis part 2
Purpose
This lab's objective was to use the flowchart created in the first part of this experiment to
analyze an unknown sample that contained some of the ions previously investigated. After
analyzing the unknown sample, the recollected data was used to identify what ions were present
and explain how that conclusion was achieved.
Flowchart
Deep orange precipitate was formed
Procedure When introducing SO4, add the unknown sample in a labeled test tube and add 10 drops
of 3 M H2SO4 with a dropper. Record any visual changes and be sure to stir the sample if
precipitate forms. Afterwards, centrifugate the sample and record the data. Safely dispose of the
sample before cleaning tubes. Ag+, Pb+2, Ni+2, Ba+2, Fe+3
Add HCL
Add Heat
PPT
Ag+
+K2CO
4
Formed white precipitate, light yellow supernatant
SP
N
pB
+2
+K2CO
4
Formed precipitate in a cloudy darker yellow supernatant.
Supernatant
Ni+2, Ba+2, Fe+3
+H2SO
4
PPT
Ba+2
SPN
Ni+2, Fe+3
PPT
Fe+3
Red precipitate was formed
NH3+DMG
SPN
Ni+2
Turned clear blue supernatant
+NaO
H
Formed precipitate
Ag+, Pb+2
White precipitate
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When introducing HCl to the sample, add 20 drops of the test solution to the labeled test
tube. Add 10 drops of 6 MHCl. After recording the data, proceed to centrifugate the sample and
follow the same steps as for SO4. When heating Precipitate and adding K2CrO4: If precipitate forms in the previous step,
add 4 mL of deionized water and mix. Heat the mix in a water bath for 5 min. Centrifuge the test
tube and pour off the supernatant from the sample into a clean test tube. To the hot liquid, add 2
drops of K2CrO4. Record any observations and dispose of any supernatant and precipitates.
Clean the test tube for the next step. Indicate what ions are in the sample and provide the
reasoning for those conclusions. Add 20 drops of test solutions to the clean test tube and 4 drops of 6 M NaOH with a
dropper. Mix and centrifugate the sample if precipitate forms. Record any visual changes. After
the centrifuge, discard any supernatants and save precipitates for the next experiment. Add 20 drops of 15 M NH3 to the test tube of left over precipitant from the previous test,
mix and centrifugate the samples. Record any observations in Data Table 2. After recording data,
add 3 mL of DMG (dimethylglyoxime). Stir the solutions and record any observations.
Safety precautions Since possibly hazardous chemicals will be handled (unknown sample) while loading and
unloading the samples into the centrifuge, the personal protective equipment (PPE) must be used
thorough the duration of this lab. These consists of safety goggles, lab coat, long pants, close toe
shoes, and gloves. In the case of any chemical reaching exposed skin, it must be rinsed off and
washed. If a chemical is introduced in the eyes, these must be flushed constantly with water for
about 15 minutes. If any of these chemicals are ingested a medical doctor must be contacted. To
avoid accidents the centrifuge machine must be balanced every time is about to be used, failure
to do so might result in the damage of the machine, the samples, and/or the person operating the
machine.
What is it in tobacco that makes it so dangerous? There are more than 4,000 chemical compounds in every cigarette that are hazardous to your health. Nicotine, for example, acts as a high-powered stimulant that raises blood pressure and
heart rate. It is one of the most addictive drugs in the market. Its addiction is comparable to heroine or morphine. Nicotine causes irritation to the lining of the blood vessels. This may cause the "bad" LDL cholesterol to adhere to the vessel walls and speed hardening of the arteries (arteriosclerosis). Hardening of the arteries can
eventually lead to a heart attack or stroke. At least 40 of these chemicals in cigarettes are known
to cause cancer in humans. When a cigarette is smoked, nicotine first enters the lungs and bloodstream. Within seven seconds, about 15 percent of the nicotine travels directly to the brain. Each puff provides the smoker with a dose of nicotine. Not all the smoke from a cigarette goes into the lungs of the smoker; a large part is exhaling into the air. This creates an atmosphere of smoke for other people to breath. This is known as second-hand smoke. How dangerous is second-hand smoke? Second-hand smoke is more dangerous because it is not filtered out and goes straight into the air.
More than 5000 toxins spread through the air into other people’s lungs. Seven out of the top 20 more toxic chemicals are found in cigarettes. An estimate of 3000 deaths per year is attributed to second-hand smoke. Second-hand smoke is classified as a human class A carcinogen by the Environmental Protection Agency (EPA), a fact not a probability. In this experiment we will determine the effect of direct (1st hand) and indirect (2nd hand) smoke by collecting the solids released while simulating the process of smoking.
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IN QUALITATIVE ANALYSIS OF GROUP 3 CATIONS , COMPLETE THIS TABLE AND WRITE THE CHEMICAL REACTIONS FOR THE IONS THAT OCCURED.
COMPLETE THIS TABLE:
Group IIICations
ConfirmatoryReagent
Result/Observation
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O Color change
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PART ONE: Preparation of FECNS* Solution
Prepare the two solutions in table 1 by accurately measuring the required volumes of distilled
water and CNS into two labeled test tubes. The absorbance of the solutions must be measured
soon after adding the Fe" solution from a buret.
TABLE 1
Fe
5 ml
5S mL
Solution
Distilled Water
CNS
2 mL
Total Volume
3 ml
2 ml
10 ml
3 mL
10 ml
In this part of the experiment you are to explore what the above quote means. As a
PRELIMINARY Exercise, formulate a hypothesis as to what would happen under each of the
following circumstances:
1. 1ml of 0.0020 M CNS' solution is added to the unused portion of
solution 1 in the test tube
2. One drop of 0.20 M CNS solution is added to the unused portion of
solution 2 in the test tube.
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The spectroscopic data in the table is generated with five solutions of known concentration.
Concentration (M)
0.0133
m=
0.0266
0.0532
0.106
0.213
Absorbance
0.1271
What is the intercept of the linear regression line?
0.08531
0.5388
1.069
Use a spreadsheet program, such as Microsoft Excel, to graph the data points and determine the equation of the best-fit line.
1.954
What is the slope of the linear regression line formed by these points?
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Case #5
Case #6
Jeepers! Someone snuck into
the Movie Madness studio and
Someone stole the net from the
High Wire act at the Crazy Circus!
Without it, the show can't go on!
stole the reels for the new film!
The CSI team found a liquid at
At this crime scene, there were
traces of a liquid, 9 drops (at ,059
drop) were found to contain
279C, 119790, and ,06039H, What
was the empirical formula of the
compound? Who committed the
heinous act?
this crime scene, When the
,77009 sample was analyzed, it
was found to contain ,04679H
and ,724390, What was the
empirical formula? Who should
the police question?
a
Case #7
Case #8
Old Man Higgins had his
favorite cane taken from him
when he was out for a walk
through Sinister Park, The CSI
team found traces of a uhite
powder at this crime scene, To
be 61,67%CL, A flame test
yielded a yellow flame,
indicating the remaining
portion was sodium, What was
the empirical formula of the
compound? What kind of
person would steal an antique
cane?
The original…
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72.
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W. College Physic
mical App
AN Careers
eagleonline.hccs.edu/courses/188795/assignments/3601808
valnabie diler reD 4 dl 10.1Tam
Constants | Periodic Table
Part O
Complete the fourth row.
Complete the following table by calculating the
missing entries and indicating whether the solution
is acidic or basic.
Express your answer using two decimal
places.
Acidic or
[H+]
[OH-]
pH pOH
basic?
7.4x10-3
ΑΣφ
3.3x10-10
M
pH
8.25
5.73
Is
to
fa
ho
II
10
insert
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Absorbance
1.40
Beer's Law Plot
1.20
1.00
0.80
0.60
0.40
0.20
0.00
0
10
20
30
40
50
Concentration (M x 105)
D
The slope for the line is 80.23. Use the Beer's Law plot provided to determine the
concentration for a solution with absorbance = 0.5786.
M
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Document1 - Word
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References
Mailings
Review
View
Help
Write the corresponding letters to the following descriptions. Each proposal can be associated with 0 or
1 match and each letter is not necessarily associated with a proposal.
a. [Ar] 4s?
b. 1s 2s2p63s23p3
c. 1s2s2p2
d. [Ne] 3s23ps
e. [Ar] 4s23d10
f. 1s22s!
g. None of those answers
1. I am a halogen
2. I am a transition metal
3. I am alkaline
4. I have exactly 2 single electrons
5. I am the smallest of the atoms presented here
6. I have exactly 3 valence electrons
7.I am the most paramagnetic of the atoms presented here
8. I am the copper
9.I am isoelectronic with Ti2+
IF
cessibility: Good to go
IA
16
SIS
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The lab will analyze large samples for Cu. What instrument would you recommend purchasing to support this work, Atomic absorption spectrophotometer or an inductively coupled plasma atomic spectrophotometer? Explain the basis for your decision.
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Suspect #1: George Norman
Suspect #2: Becky Baker
George Norman recently
Becky Baker is a world famous
chef. She had just finished
baking a cake at the time of
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for baking soda. The formula
for baking soda
(sodium
bicarbonate) is
had an accident
where he cut
himself with a
Alaia
knife. He cleaned
the wound with
rubbing alcohol.
The formula for
rubbing alcohol
Bak ing
Seda
NaHCOз.
(isopropanol) is C3H80.
Suspect # 3: Liz Lemon
Suspect #4: Ben Linus
Liz Lemon just had her nails
Ben Linus had been walking
done, and she still has
traces of nail polish remover
on her hands. Nail
around in the rain
for about an hour
before the crime
polish remover
he was suspected
contains acetone.
Acetone
of occurred. He
The formula for
Polish
was dripping wet with water
acetone is C3H60.
renover
at the time. The formula for
water is H2o.
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Dangerous Paint Stripper Jessica has a summer job working for the
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remove graffiti from the bathrooms. She has to take a lot of breaks, because
the chemical makes her throat burn. It also makes her feel dizzy sometimes,
especially when the bathrooms don’t have very many windows. On the label, she
sees that the cleaner has methylene chloride in it. She feels like she’s
managing to get the work done, but she is worried about feeling dizzy. She
wants to find out more about this chemical, what harm it can cause, and
whether there are safer ways to do this work.
Questions for following story.
1. What went right in this situation?
2. What went wrong in this situation?
3. What steps should be taken in this workplace to make sure employees are
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Number 2,3,and 4
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The spectroscopic data in the table is generated with five solutions of known concentration.
Concentration (M)
0.0179
0.0358
0.0716
0.143
0.286
Absorbance
0.1425
0.1896
0.5722
1.126
2.110
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please highlight the correct answer
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[References]
Use the References to access important values if needed for this question.
Taking logarithms and antilogarithms is necessary to solve many chemistry problems. For practice, complete the following table, where N is a number.
log N
7.92
1.867
-1.402
Submit Answer
Retry Entire Group
4 more group attempts remaining
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Next
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Use the References to access important values if needed for this question.
18
16
14
12
10
8
6
4.
Choose the correct relationship for the plot shown above.
O a direct proportion
O an inverse proportion
O linear with a positive slope and nonzero y-intercept
O linear with a negative slope and nonzero y-intercept
Submit
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Select one:
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O d. 2.82 mg/mL
e. 0.0365 mg/mL
Next page
Law Tutorial Part 2
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Exp #9 - Laboratory Practical►
Worksheet
étv A
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The following Absorbance vs concentration of nitrite graph is obtained for a set of data:
Absorbance Vs Concentration y = 1.6628x+0.0373
R? = 0.9893
1.8
1.6
1.4
1.2
1
0.8
0.6
0.4
0.2
0.2
0.4
0.6
0.8
1
Concentration of nitrite (mg/L)
Determine the concentration of unknown solution for which the absorbance is determined
as 0.69
A. More data is required
В. 0.69
С. 0.65
D. 0.39
Absorbance
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