Solutions for Introduction to Chemistry
Problem 3QP:
What is a chemical bond?Problem 8QP:
Which of the following compounds are likely to have ionic bonds? (a)CsCl(b)CaCl2(c)OCl2(d)NBr3(e)IF5Problem 15QP:
Predict whether each of the following substances is likely to have a relatively high or low boiling...Problem 17QP:
Describe how electronegativity values change going down a group in the periodic table.Problem 19QP:
What kind of bonds are always nonpolar?Problem 20QP:
Describe how to decide whether a bond is polar.Problem 22QP:
Using periodic trends, arrange the following atoms in order of increasing electronegativity. (a) B,...Problem 26QP:
Arrange the following bonds in order of increasing polarity. (a)HF,FF,HH,HI(b)BF,OF,CF,HFProblem 27QP:
What information can be determine from Lewis symbol?Problem 28QP:
What is the maximum number of valence electrons represented in the Lewis symbols of the main-group...Problem 33QP:
Write a formula for each of the following ionic salts using the Lewis symbols of the ions....Problem 34QP:
Write a formula for each of the following ionic salts using the Lewis symbols of the ions....Problem 40QP:
What holds ions together in a crystal lattice?Problem 41QP:
Describe the sodium chloride structure shown in Figure 8.8. How many chloride ions surround each...Problem 42QP:
Describe the cesium chloride structure shown in Figure 8.9. How many chloride ions surround each...Problem 45QP:
Draw the Lewis structures for O2andF2. (a) How many valence electrons are around each atoms in each...Problem 46QP:
Draw the Lewis structures for I2andN2. (a) How many valence electrons are around each atoms in each...Problem 47QP:
Why does hydrogen exist as a diatomic molecules?Problem 50QP:
How many single bonds are typically formed by the following atoms? (a) B (b) O (c) I (d) CProblem 54QP:
Draw a Lewis structure for each of the following: (a)NH2OH(b)CCl4(c)C2H3Cl(d)C2Br2(e)HOClProblem 62QP:
Indicate whether or not each of the following molecules or ions exhibits resonance....Problem 63QP:
Draw a Lewis structure, include the resonance forms, for each of the following molecules or ions....Problem 65QP:
In HF, the hydrogen atoms shares two electrons with the fluorine atom, but has no unshared electrons...Problem 66QP:
Describe the bonding in S2Cl2. The atom are connected in the order, Cl S S Cl. Why does this...Problem 67QP:
Decide whether the indicated atoms obeys the octet rule. If not, indicate how the octet rule is...Problem 68QP:
Decide whether the indicated atom obeys the octet rule. If not, indicate how octet rule is broken....Problem 69QP:
An atom of the following molecules does not obey the octet rule. Decide which atom violet the rule...Problem 70QP:
An atom of the following molecules does not obey the octet rule. Decide which atom violet the rule...Problem 84QP:
Why are unshared pairs of electrons on a central atom not considered to be part of the molecular...Problem 87QP:
Draw each of the following geometric arrangements. (a)Â tetrahedral (b)Â trigonal planar (c) bent...Problem 88QP:
In which of the following molecular shapes would you expect to find one or more unshared pairs of...Problem 90QP:
Predict the parent structures of the following molecules. (a)OCS(b)FNO(c)FCN(d)HN3(e)PF3(f)SF2(g)NO2Problem 93QP:
Predict the bond angles in the following molecules. (a)NH3(b)H2O(c)HCl(d)HCN(e)BF3(f)H2CO(g)PCl3Problem 94QP:
Predict the bond angles in the following molecules. (a)NF3(b)SO2Cl2(c)CBr4(d)F2CO(e)PH3(f)HOClProblem 99QP:
Is this the shape of NO3 or ClO3?Problem 100QP:
Is this shape of
Problem 101QP:
Which of the following molecules or ions have unshared electron pairs on the central atom?Problem 102QP:
Which of the following molecules or ions have unshared electron pairs on the central atom?Problem 103QP:
Hydrazine, N2H4, is a colorless, oily liquid that fumes in air and has an odor much like that of...Problem 104QP:
Oxalic acid, H2C2O4, a poisonous colorless solid, is found in some vegetable such as spinach and...Problem 105QP:
Chloropicrin, Cl3CNO2, is an insecticide that has been used against insects that attack cereals and...Problem 106QP:
Fuel cell are used in many areas, such as the aerospace industry, where energy efficiency is more...Problem 107QP:
Distinguish between bond polarity and molecular polarity.Problem 108QP:
Why does molecular polarity depend not only on bond polarity but also on the molecule?Problem 109QP:
Explain how carbon tetrachloride can have polar bonds but still be a nonpolar molecule.Problem 112QP:
Are the following molecules polar or nonpolar? aBF3(c)CH2Cl2Problem 113QP:
For each pair of molecules decide which molecule is polar and explain why it is polar while the...Problem 121QP:
Draw Lewis symbols showing the valence electrons of the following atoms. (a) Br (b) Pb (c) S (d) Ca...Problem 126QP:
Draw a Lewis structure for each of the following. (a)HClO2(b)HClO3(c)HClO4(d)BrF3(e)ClO3Problem 128QP:
Draw a Lewis structure, including the resonance forms, for each of the following molecules or ions....Problem 129QP:
Draw the Lewis structure for each of the following. Including any necessary resonance forms....Problem 130QP:
Gaseous aluminium chloride exists as a dimer, Al2Cl6, with two chlorines between the two aluminium...Problem 131QP:
Describe the molecular shape of each of the following....Problem 132QP:
Describe the structure and bonding in sulfuric acid, H2SO4, and in its two ions, HSO4andSO42.Problem 133QP:
Decide which of each pair of gaseous molecules is polar, and explain why that molecule is polar...Problem 135QP:
For each pair of molecules decide which molecule is most polar and explain your answer....Problem 137QP:
Predict whether each of the following substances is likely to have a relatively high or low boiling...Problem 138QP:
Predict whether each of the following substances is likely to have a relatively high or low boiling...Problem 141QP:
There are two different alcohols with the formula C3H7OH. Draw Lewis for the two alcohols.Problem 142QP:
The proteins in our bodies are built from small organic molecules called acids. An amino acid is a...Problem 144QP:
Plastic food storage containers are often made of polypropylene. The compound used to make...Problem 145QP:
Draw the Lewis structure for a ketone containing four carbon atoms and eight hydrogen atoms.Problem 146QP:
Compare the molecular shape around each carbon atom and HCC bond angles in C2H6,C2H4,andC2H2. How...Problem 147QP:
Which compound contains both covalent and ionic bonds? A.NaHSO4B.NaFC.HFD.NaHE.SO2Cl2 Identify the...Problem 148QP:
The bonds in O3 are expected to be A. ionic because of a large difference in electronegativity. B....Problem 149QP:
Which of the following is a true statement about ionic crystal? A. The strong electrostatic forces...Problem 150QP:
Which of the following bonds is most polar? A.CFB.CClC.CSD.CHE.FF For each incorrect answer that is...Problem 151QP:
Which of the following always violets the octet rule? A. a molecule or ion with sulfur as the...Problem 152QP:
Identify the main-group element X that could form this compound: A. C B. O C. N D. F E. B Explain...Problem 153QP:
Which of the following has a Lewis structure most like that of SO32? A.SO42B.NO3C.SO3D.NF3E.CO32 Why...Problem 154QP:
Which of the following has a double bond? A.N2H4B.C2H2C.C2H4D.C2H6E.N2 For each incorrect answer,...Problem 155QP:
Which of the following statements about resonance is true? A. Resonance is needed when a single...Browse All Chapters of This Textbook
Chapter 1 - Matter And EnergyChapter 2 - Atoms, Ions, And The Periodic TableChapter 3 - Chemical CompoundsChapter 4 - Chemical CompositionChapter 5 - Chemical Reactions And EquationsChapter 6 - Quantities In Chemical ReactionsChapter 7 - Electron Structureof The AtomChapter 8 - Chemical BondingChapter 9 - The Gaseous StateChapter 10 - The Liquid And Solid States
Book Details
Introduction to Chemistry, 4e by Bauer/Birk/Marks offers today's student a fresh perspective to the introduction of chemistry. This textbook offers a conceptual approach to chemistry by starting first with macroscopic phenomena, and then presenting the underlying microscopic detail. Each chapter opens with a real-life scenario that helps students connect abstract chemical concepts to their own lives. The math found in
Introduction to Chemistry, 4e is introduced on a need-to-know basis, with "Math Toolboxes" in select chapters to help support the math skills required in that chapter.
Sample Solutions for this Textbook
We offer sample solutions for Introduction to Chemistry homework problems. See examples below:
Chapter 1, Problem 1QCChapter 1, Problem 9PPSignificant figures are the digit numbers in which the answer is described in accuracy. It starts...The calculation can be carried out by simply applying the multiplication method:...Chapter 1, Problem 8QPChapter 1, Problem 19QPChapter 1, Problem 20QPChapter 1, Problem 21QPThe conversion factor for centiometer to feet is as follows. 1 cm=0.0328084 ft1=0.0328084 ft1 cm For...
Chapter 1, Problem 23QPThe relation between Foot ft and in is shown below: 1 ft=12 in The conversion factors used to...Chapter 1, Problem 86QPChapter 1, Problem 113QPChapter 1, Problem 122QPChapter 1, Problem 124QPChapter 1, Problem 142QPChapter 1, Problem 145QPChapter 1, Problem 156QPChapter 1, Problem 157QPChapter 2, Problem 1QCGiven information: The table is provided in the question. In the first row of the table, the mass...The differences between ionic and molecular compounds are explained below: In ionic compounds,...Given Information:Table is provided in the question. Ca2+ cation combines with Cl− to form CaCl2...Given Information:Table is provided in the question. Ba2+ cation combines with Br− to form BaBr3...Chapter 3, Problem 55QPGiven Information: Table is provided in the question. Sodium cation Na+ combines with chloride anion...Ammonia is a combination of nitrogen and hydrogen in which a covalent bond is formed by sharing of...The charges and symbols of elements are analyzed on the basis of their position in the periodic...In a compound, the mass composition of an element is determined by dividing the mass of that element...The given compound is Hg2Cl2 . Molar mass can be determined by adding the masses of the...Chapter 4, Problem 28QPThe given compound is K2SO4 . Number of moles is determined using the molar mass and mass of the...The molar mass of 15 g Na2CO3 is to be converted into an equivalent number of moles. The number of...Chapter 4, Problem 53QPChapter 4, Problem 55QPChapter 4, Problem 56QPChapter 4, Problem 73QPChapter 4, Problem 87QPThe percent composition of any substance is calculated by dividing the mass of the substance in a...The percent composition of any substance is calculated by dividing the mass of substance in a sample...The percent composition of any substance is calculated by dividing the mass of substance in a sample...The molarity of the acetic acid solution is to be determined. The number of moles is calculated from...The number of moles is calculated from the following expression: n=mMm …… (1) Here, m is the...The conversion of volume from milliliters to liters is given as follows: VolumeL=x mL×1 L1000 mL...C3H4 contains three moles of carbon and four moles of hydrogen. The mass of three moles of carbon is...The number of moles of Ca3PO42 can be calculated by using the expression of molarity as follows:...Chemical reaction is defined as a process in which reactant species interact with each other in...The skeleton equation for the chemical equation is shown in (1) where, on the left side, the number...The skeleton equation for the chemical equation is shown below, where on the left side, the number...The chemical equation that is shown below is balanced because the number of atoms on the left side...Sodium chloride NaCl and sodium sulfate Na2SO4 are electrolytes whereas silver sulfate Ag2SO4 and...Except for chromium (III) hydroxide (Cr(OH)3), all other substances in the given reaction are...Chapter 5, Problem 111QPAmmonium nitrate and chromium chloride are electrolytes that react to produce chromium (III)...The given reaction is, C4H10g+O2g→CO2g+H2Og The reactant side contains 4 carbon atoms, 10 hydrogen...The numerical coefficients in a chemical equation show the ratio of the molecules of each of the...Given Information: The given reaction: Na2CO3s+2HClg→2NaClaq+H2Ol+CO2g Moles of Na2CO3 is 11 g and...The balanced equation of the given reaction is: 2C7H5NO23s→7Cs+7COg+3N2g+5H2Og It is apparent from...The balanced equation of the given reaction is: 2NH4NO3s→2N2g+O2g+4H2Og It is apparent from the...The mass of the first reactant is 0.600 g . The relation among the number of moles, molar mass and...The relation among the number of moles, molar mass and mass is, n= mMM Here, n is the number of...Given information: A reaction is given in the question. Initially, 0.269 g of C2H6 is mixed. So, the...Given Information: A reaction is given in the question. Initially, 0.130 g of C4H10 is mixed. So,...Given Information: Mass of pipe and water is 175 g and 100 g , respectively. The temperatures of...Chapter 6, Problem 126QPThe given balanced equation shows that one mole of MgNO32 dissolves and dissociates into Mg2+ and 2...4 moles of C3H3N3O9 decomposes to produce 6 moles of N2 . The number of moles of N2 produced by 1.0...One mole of N2 reacts with three moles of H2 . Thus, N2 is present in excess. So, the number of...The electromagnetic spectrum includes different radiations that are categorized on the basis of...When a metal and a non-metal are present in the formula, then ionic bond is formed. In ionic...Chapter 8, Problem 89QPChapter 8, Problem 131QPThe general properties of gases are discussed below. Compressibility: As the intermolecular spaces...The conversion factor required to convert the value of pressure is: 760 torr=1 atm1=1 atm760 torr...The conversion factor which is used to convert the pressure from atm to torr is as follows: 1...The calculation for determining the final volume of the gas. The conversion of temperature from...: The calculation for determining the final pressure of the gas. The conversion of temperature from...Ideal gas law gives a relation between pressure P , volume V , temperature T , and the number of...Ideal gas law gives a relation between pressure P , volume V , temperature T , and the number of...Ideal gas law gives a relation between pressure P , volume V , temperature T , and the number of...The molar mass of a gas at STP can be determined by using the value of its density. The density ρ of...The ideal gas equation is an equation that determines the relation between the pressure P ,...Given Information: The volume of N2O is 145 L at 2850 torr and 42°C . The reaction is as follows:...Given Information: The volume of argon gas collected over water is 3 L at 27.0°C and 765 torr . The...Given Information: The volume of the tank is 2.00 L . Tank contains 72.0 g N2 and 66.0 g Ar . The...Given Information: The amount of limestone used daily is 1.00×105 kg at 735 torr and 25.0°C . The...The number of moles of a gas n is equal to the ratio of the amount of gas m present in the container...Given Information: Table 9.2 The partial pressure of a gas in a mixture is defined as the force...The ideal gas equation states that pressure P and volume V of a gas is directly proportional to the...The ideal gas equation states that pressure P and volume of a gas V is directly proportional to...The number of moles of a gas n is equal to the ratio of mass of the gas m to the molar mass MM of...Oxygen is produced by the following reaction: 2KClO3s→2KCls+3O2g According to the reaction, 2 mol...Chapter 10, Problem 1QCChapter 10, Problem 37QPGiven Information: Mass of steam is 32.0 g , the temperature of steam is 115.0°C , the specific heat...Chapter 10, Problem 40QPA homogeneous mixture that has a uniform composition is called a solution. Solutions can be mixtures...Given Information: The molarity of lead nitrate solution is 0.105 M and the molarity of potassium...Chapter 11, Problem 69QPGiven Information: The (ppb) concentration of nitrate ions in tap water is 95 ppb . Parts per...Given Information: 100 mL of 0.15 M Pb2+ ion solution and 1.0 M KI solution are given. The given...Given Information: 20.00 mL of 0.1033 M NaOH is neutralized with 0.850 M H2SO4 solution. : The...The balanced chemical equation is, HCl(aq)+NaOH(aq)→NaCl(aq)+H2O(l) The moles of HCl present in...The balanced chemical equation is, HCl(aq)+NaOH(aq)→NaCl(aq)+H2O(l) The moles of NaOH present in...Given Information: Percent by mass concentration of H2SO4 solution is 24% and density of solution is...Given Information: The molarity of Acetic acid solution is 1 M and density of the solution is 1.005...Given Information: The molarity of silver nitrate solution is 0.200 M and of sodium carbonate...Given Information: The molarity of barium chloride solution is 0.100 M and of potassium sulfate...Consider the given statement, “The dissolution process of Mg(NO3)2 in water forms 0.20 M...KCl is an ionic compound and water is a polar solvent. Thus, KCl is easily soluble in water to and...The reaction between silver nitrate and potassium sulphate forms the precipitate of aluminium...A solution that gives the highest number of particles has the lowest freezing point. 1.5 m KBr...A reaction takes place under different conditions at different rates. As the concentration of...Chapter 13, Problem 1QCIonic product of water is defined as the product of concentrations of H+ and OH− ions present in the...pH of a solution gives the concentration of hydrogen ions in that solution. Range of pH values is...From the table 13.1 (from the book), H2SO4 is a strong acid. H2SO4aq dissociates completely into...Citric acid is a weak organic acid and furnishes hydronium ions according to its Ka value. The...The given concentration of OH− is 1×10−3 M . Now, OH−×H3O+=1×10−14 M2H3O+=1×10−14 M2OH− Substitute...The given concentration of H3O+ is 1×10−3 M . Now, OH−×H3O+=1×10−14 M2OH−=1×10−14 M2H3O+ Substitute...The given OH− concentration is 1×10−4 M . The expression that shows the relation between pOH and OH−...The given OH− concentration is 6.4×10−4 M . The expression that shows the relation between pOH and...The given concentration of HNO3 is 0.01 M . HNO3 is a strong acid, the H3O+ concentration is equal...The given concentration of KOH is 0.001 M . KOH is a strong base, the OH− concentration is equal to...Ionic product of water is defined as the product of concentrations of H+ and OH− ions present in the...pH of a solution gives the concentration of hydrogen ions in that solution. Range of pH values is...The given value of pH is 5 . The relation between pH and pOH is as follows: pH+pOH=14 Substitute 5...Given Information: The given concentrations of the solutions are 0.1 M HNO3 , 0.5 M HCl , a solution...The given acids are 0.5 M CH3CO2H and 0.10 M HF and their Ka values are 1.8×10−5 and 6.3×10−4 ,...Chapter 13, Problem 147QPIn a oxidation-reduction reaction, the oxidation state of a substance increases due to loss of...Chapter 14, Problem 18QPChapter 14, Problem 19QPChapter 14, Problem 20QPChapter 14, Problem 27QPThe given ion is H2PO4− . The oxidation number of oxygen and hydrogen is −2 and −1 which is...The skeleton equation chemical equation is shown below: H2Saq+Cr2O72−aq→Ss+Cr3+aq …(1) The...Chapter 14, Problem 56QPChapter 14, Problem 57QPChapter 14, Problem 58QPChapter 14, Problem 59QPThe half-cell reactions for the given chemical equations can be obtained by writing the oxidation...The ionic skeleton chemical equation for the given reaction is shown in equation (1)....The isotopes are the atoms with different number of neutrons. They can be stable or unstable...A nuclear reaction involves changes at the subatomic level such as, the changes in the number of...A nuclear reaction involves changes at the subatomic level such as, the changes in the number of...A nuclear reaction involves changes at the subatomic level such as changes in the number of protons,...If the NZ ratio is too high, nuclide undergoes beta decay to lower the ratio. If the NZ ratio is too...If the NZ ratio is too high, nuclide undergoes beta decay to lower the ratio. If the NZ ratio is too...If the NZ ratio is too high, nuclide undergoes beta decay to lower the ratio. If the NZ ratio is too...In the given nuclear reaction shown below, the mass number is not balanced because the total mass...The nuclear reaction that represents the conversion of U92234 to thorium- 230 is shown below....The half-life of technetium- 99 is 6.0 h . Thus, after 6.0 h , the amount of technetium- 99 gets...Organic molecules can be represented by their molecular formulas, ball and stick models, structural...The isomers of a compound have the same molecular formula with a different arrangement of atoms....Chapter 17, Problem 1QCThe simplest amino acid is alanine after glycine because the side chain in alanine is the methyl...
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