Browse All Chapters of This Textbook
Chapter 0 - The Analytical ProcessChapter 1 - Chemical MeasurementsChapter 2 - Tools Of The TradeChapter 3 - Math ToolkitChapter 4 - StatisticsChapter 5 - Quality Assurance And Calibration MethodsChapter 6 - Good TitrationsChapter 7 - Gravimetric And Combustion AnalysisChapter 8 - Introducing Acids And BasesChapter 9 - Buffers
Chapter 10 - Acid-base TitrationsChapter 11 - Polyprotic Acids And BasesChapter 12 - A Deeper Look At Chemical EquilibriumChapter 13 - Edta TitrationsChapter 14 - Electrode PotentialsChapter 15 - Electrode MeasurementsChapter 16 - Redox TitrationsChapter 17 - Intrumental Methods In ElectrochemistryChapter 18 - Let There Be LightChapter 19 - Spectrophotometry: Instruments And ApplicationsChapter 20 - Atomic SpectroscopyChapter 21 - Principles Of Chromatography And Mass SpectrometryChapter 22 - Gas And Liquid ChromatographyChapter 23 - Chromatographic Methods And Capillary Electrophoresis
Book Details
Chapter 0 The Analytical Process Cocaine Use? Ask the River 0-1 The Analytical Chemist's Job 0-2 General Steps in a Chemical Analysis Box 0-1 Constructing a Representative Sample
Sample Solutions for this Textbook
We offer sample solutions for Exploring Chemical Analysis homework problems. See examples below:
Qualitative analysis determines the chemical composition of the sample like what are the elements or...SI units of length, mass, time, electric current, temperature and amount of substance are listed and...The quantity 10−13 joules can be expressed as 100 fJ. fJ is femtoJoule and the prefix femto is...Applying the dilution formula volume of 18.0M98 wt%H2SO4 that has to be withdrawn to make 1.00 L of...The force of gravity differs from place to place and at different elevations above Earth's surface....Given data: The given number is 1.2367 Rounding off: The next digit after the rounding place is...Given data: [12.41(±0.09)÷4.16(±0.01)] × 7.0682(±0.0004)=? Calculation of absolute and percent...Given data: [9.23(±0.03)+4.21(±0.02)] − 3.26(±0.06)=? Calculation of absolute and percent relative...The relationship between precision and standard deviation is that greater the standard deviation,...
The mean values for method 1 and method 2 are first calculated as follows, Enzyme activity(5...The raw data resemble individual measurements. They are directly measured like measuring volume from...The standard deviation value for the 9 given samples is calculated as follows, Mean, x¯ =...Equivalence point is achieved when the exact amount of titrant (known concentration) is added to...Given data is, Reaction : 5Oxalic acid + 2MnO4 + 6H+ → 10CO2 + 2Mn2+ + 8H2O The moles of oxalic acid...Given, 25.42mg of sample. 29.03mg of silver iodide. Let n be the number of CH3CH2O- groups in the...Since formic acid is a Bronsted-Lowry acid, it donates proton when it reacts with cyanide ion. The...As known, Ka of HCN is 6.2 × 10−10. The value of Kb of HCN is calculated as, Kb = KwKa = 1 ×...The equation as follows, OCl−(aq) + H2O(l) ⇌ HOCl(aq) + OH−(aq) As known, Kb = [HOCl][OH−][OCl−]...The given compound Cr(ClO4)3 is dissociates into Cr3+ and ClO4-. Cr3+ ion is acidic in nature and...Addition of acid to a buffer solution does not bring any change in pH of solution. It is due to...The formula to calculate concentration of glycine amide (B) is as follows: [B]=(mass of Bmolar mass...The equilibrium reaction for imidazole with equilibrium constant Kb is as follows:...Before the equivalence point is reached any volume of H+ consumes the corresponding stoichiometric...The dilution formula is given as follows: M1V1=M2V2 (1) Substitute 0.05 M for M1, 0.500 M for M2 ,...Dilution formula is given as follows: M1V1=M2V2 (1) Substitute 1.00 M for M1, 0.1 M for M2 , 100 mL...Initial point at A corresponds to weak acid H2A. Thus formal concentration of weak acid H2A is used...First equilibrium reaction for malonic acid that is designated as Ka1 is as follows: H2M⇌Ka1HM−+H+...The compound B is a dibasic compound thus, it requires two protons. Acceptance of one proton...In accordance to Henderson Hasselbach equation pH is calculated as follows: pH=pK1+log[HA−][H2A] (1)...Anion is surrounded by more number of cation than anions, similarly cation are surrounded by more...Equilibrium for PbF2 written as follows: PbF2⇌Pb2++2F− Assume [Pb2+] is same as [F−] equal to x....Equilibrium for CaSO4 written as follows: CaSO4⇌Ca2++SO42− Assume [Ca2+] is same as [SO42−] equal to...Formula to calculate [H+] is given as follows: [H+]=10−pH (1) Substitute 10.50 for pH in equation...Rearrange equation (1) for moles of solute. Moles of solute=[(Molarity of solution(M))(Volume (L) of...Expression for Kf' is as follows: Kf'=(αY4−)(Kf) (1) Here, Kf' is conditional rate constant. Kf is...Expression for Kf' is as follows: Kf'=(αY4−)(Kf) (1) Here, Kf' is conditional rate constant. Kf is...Electric charge is defined as physical property of matter due to that it experiences a force when...The half cell reaction at cathode is as follows: AgCl+2e−→2Ag+2Cl− Expression of Nernst equation for...Reduction half cell reaction in anodic half cell is as follows: Br2(l)+2e−⇌2Br− Reduction half cell...Since Cu electrode is attached to postive terminal of potentiometer it serves as cathode and...Titration reaction is written as follows: Hg22++2Cl−⇌Hg2Cl2(s) (1) Dilution formula is given as...Expression to compute potential of ion selective electrode is given as follows:...Given titration reaction is as follows: Ce4++Fe2+→Ce3++Fe3+ Reduction half-cell reaction of...In this reaction, Ce4+, acts as an oxidizing agent. It oxidizes Cu+ to Cu2+ and itself reduced to...The basic idea of electrogravimetric analysis is if energy is supplied from external source to...Formula to calculate moles is as follows: n=PVRT (1) Substitute 303 K for T, 0.996 bar for P, 0.082...Equilibrium for dissociation of is given as follows: H2SO3⇌HSO3−+H+ Value of pH is calculated by...Planck’s hypothesis states energy associated with photon in terms of frequency is as follows: E=hv...Conversion factor to convert nm to m is as follows: 1 nm=10−9 m Thus, 250 nm is converted to m as...Since 1 mol NH3 has 1 mol N, and mass of 1 mol N is 14.007 g/mol, thus mass of N in 28.6 % NH3 is...Single beam spectrophotometer has a separate mount for blank cuvette before the test run. In double...Relation between path length and dimension is as follows: D=b(ε'Xε"Y−ε'Yε"X) (1) Substitute 420...Expression to compute concentration as per Beer’s law is as follows: c=Aε⋅b (1) Substitute 0.463 for...Advantages of flame atomic absorption spectroscopy over furnace are listed as follows: 1. Relatively...Conversion factor to convert nm to m is as follows: 1 nm=10−9 m Thus, 422.7 nm is converted to m as...Phenomenon that allows analyte injected within a chromatographic column to get separated when the...Assume most abundant isotope are used for each atom in 12C9H17N5Cl+, mass of this ion is calculated...Odd nominal mass of 79 suggests there are odd numbers of N atoms. So it can be 1, 3 or any odd...In wall-coated open tubular column, liquid stationary phase is bonded to the wall of column. In...Particle size has a significant impact on the analyte band. For smaller sized particles at very low...Expression to compute number of theoretical plate is as follows: N=5.55 tr2w1/22 (1) Substitute 50...pKa of hexanoic acid is 5.09 and pKa of 1-aminohexane is 10.21, hence at pH 12.0, the reaction...pH of cloud water is calculated as follows: pH=−log10[H+]=−log10(131×10−6)=3.883 Hence, pH of cloud...The relative standard deviation of 14.4 % of 0.2 μg L−1 is calculated as follows: (0.2 μg...
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Exploring Chemical Analysis
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