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Interpretation:
Iterations have to be carried to find
Concept Introduction:
Expression to compute ionic strength is as follows:
Here
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Explanation of Solution
Equilibrium for
Assume
Corresponding
Substitute
Thus when ionic strength is assumed as zero, the value for
Formula to compute ionic strength is as follows:
Substitute
Expression for linear interpolation is given as follows:
Substitute
Thus activity coefficient of
Substitute
Thus activity coefficient of
Corresponding
Substitute 0.723 for
Thus, value of
For the next iteration,
Substitute
For
Substitute
Thus activity coefficient of
Substitute
Thus activity coefficient of
Substitute 0.705 for
Thus, value of
For the next iteration,
Substitute
For
Substitute
Thus activity coefficient of
Substitute
Thus activity coefficient of
Substitute 0.704 for
At this stage no more iteration is required as concentration has not changed.
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Chapter 12 Solutions
Exploring Chemical Analysis
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