Exploring Chemical Analysis
Exploring Chemical Analysis
5th Edition
ISBN: 9781429275033
Author: Daniel C. Harris
Publisher: Macmillan Higher Education
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Chapter 12, Problem 12.24P
Interpretation Introduction

Interpretation:

Charge balance equation of solution of arsenic acid has to be written and structure of HAsO42 has to be drawn.

Concept Introduction:

Prior to representation of a systematic equilibrium, two equations namely charge balance and mass balance equation are written. Net amount of charges or mas inflow or outflow are depicted with the aid of charge balance while mass balance is a reflection of law of conservation observed for mass.

Charge balance equation indicates sum of charges on one side of an equation has to be balanced by sum of charges on opposite size. This is essentially the principle of electro neutrality.

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Using reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NO2 (g) = N2O4(g) AGº = -5.4 kJ Now suppose a reaction vessel is filled with 4.53 atm of dinitrogen tetroxide (N2O4) at 279. °C. Answer the following questions about this system: Under these conditions, will the pressure of N2O4 tend to rise or fall? Is it possible to reverse this tendency by adding NO2? In other words, if you said the pressure of N2O4 will tend to rise, can that be changed to a tendency to fall by adding NO2? Similarly, if you said the pressure of N2O4 will tend to fall, can that be changed to a tendency to '2' rise by adding NO2? If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO 2 needed to reverse it. Round your answer to 2 significant digits. 00 rise ☐ x10 fall yes no ☐ atm G Ar 1
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