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(a)
Interpretation:
Whether a decrease in activity coefficient observed due to increase in ionic strength is true statement or not has to be identified.
Concept Introduction:
For equilibrium as indicated below,
Law of mass action states that for such equilibrium that involves solutions and gases expression of equilibrium constant in principle is written in accordance with law of mass action as follows:
Here,
To account for changed ionic atmosphere of various species concentration terms are include concept of activities. Activity is defined as product of concentration times the activity coefficient. Thus expression of equilibrium constant is then written as follows:
(b)
Interpretation:
Whether a decrease in activity coefficient observed due to increase in ionic charge is true statement or not has to be identified.
Concept Introduction:
Refer to part (a).
(c)
Interpretation:
Whether a decrease in activity coefficient observed due to decrease in hydrated size is true statement or not has to be identified.
Concept Introduction:
Refer to part (a).
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Chapter 12 Solutions
Exploring Chemical Analysis
- What would be the best choices for the missing reagents 1 and 3 in this synthesis? 1. PPh3 3 2. n-BuLi • Draw the missing reagents in the drawing area below. You can draw them in any arrangement you like. • Do not draw the missing reagent 2. If you draw 1 correctly, we'll know what it is. • Note: if one of your reagents needs to contain a halogen, use bromine. Click and drag to start drawing a structure.arrow_forwardIdentify the missing organic reactants in the following reaction: X + Y H+ two steps Note: This chemical equation only focuses on the important organic molecules in the reaction. Additional inorganic or small-molecule reactants or products (like H2O) are not shown. In the drawing area below, draw the skeletal ("line") structures of the missing organic reactants X and Y. You may draw the structures in any arrangement that you like, so long as they aren't touching. Click and drag to start drawing a structure. Х :arrow_forwardDraw the mechanism of friedel-crafts acylation using acetyl chloride of m-Xylenearrow_forward
- Don't used hand raiting and don't used Ai solution and correct answerarrow_forwardH R Part: 1/2 :CI: is a/an electrophile Part 2 of 2 Draw the skeletal structure of the product(s) for the Lewis acid-base reaction. Include lone pairs and formal charges (if applicable) on the structures. 4-7: H ö- H Skip Part Check X :C1: $ % L Fi Click and drag to start drawing a structure. MacBook Pro & ㅁ x G 0: P Add or increase positive formal cha Save For Later Submit ©2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Centearrow_forwardDraw the friedel-crafts acylation mechanism of m-Xylenearrow_forward
- Don't used hand raiting and don't used Ai solutionarrow_forward1. Base on this experimental results, how do you know that the product which you are turning in is methyl 3-nitrobenzoate(meta substituted product ) rather than either of the other two products? 2. What observation suggests that at least a small amount of one or both of the other two isomers are in the mother liquor?arrow_forwardExplain Huckel's rule.arrow_forward
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