Organic Chemistry
Organic Chemistry
12th Edition
ISBN: 9781118875766
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Chapter SRP, Problem 30P

Consider this reaction involving peracetic acid:

Chapter SRP, Problem 30P, Consider this reaction involving peracetic acid: These are spectral data for the product, B:

These are spectral data for the product, B:

M S ( m / z ) :   150 ( M + ) ,   132 I R ( cm 1 ) :   3400   ( broad ) ,   750   ( no absorption in the range of  690 710 )   1 H NMR  ( δ ) :   6.7 7.0   ( m ,   4 H ) ,   4.2   ( m, 1H ) ,   3.9   ( d, 2H ) ,   2.9   ( d, 2H ) ,  and  1.8   ( 1 H ;  disappears after treatment with D 2 O ) 13 C NMR  ( δ ) :   159   ( C ) , 129  ( CH ) , 126  ( CH ) , 124  ( C ) , 120  ( CH ) , 114  ( CH ) , 78  ( CH ) , 70  ( CH 2 ) ,  and 35  ( CH 2 ) (a) What is the structure of B?

(b) Propose a mechanism for formation of B.

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3. Propose a synthesis for the following transformation. Do not draw an arrow-pushing mechanism below, but make sure to draw the product of each proposed step (3 points). CN + En CN
3) Propagation of uncertainty. Every measurement has uncertainty. In this problem, we'll evaluate the uncertainty in every step of a titration of potassium hydrogen phthalate (a common acid used in titrations, abbreviated KHP, formula CsH5KO4) with NaOH of an unknown concentration. The calculation that ultimately needs to be carried out is: concentration NaOH 1000 x mass KHP × purity KHP molar mass KHP x volume NaOH Measurements: a) You use a balance to weigh 0.3992 g of KHP. The uncertainty is ±0.15 mg (0.00015 g). b) You use a buret to slowly add NaOH to the KHP until it reaches the endpoint. It takes 18.73 mL of NaOH. The uncertainty of the burst is 0.03 mL.. c) The manufacturer states the purity of KHP is 100%±0.05%. d) Even though we don't think much about them, molar masses have uncertainty as well. The uncertainty comes from the distribution of isotopes, rather than random measurement error. The uncertainty in the elements composing KHP are: a. Carbon: b. Hydrogen: ±0.0008…
Don't used hand raiting and don't used Ai solution

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