The synthesis for the given products is to be outlined by using benzene, toluene or aniline and any other required. Concept introduction: Bromination of aromatic rings is possible with Friedel–Craft’s reagent bromine/chlorine in ferric chloride or ferric bromide using N -bromosuccinimide. Grignard reagents are nucleophiles which are highly reactive, they can be obtained by reacting magnesium in diethyl ether with an alkyl or aryl bromide. Swern oxidation of alcohols allows conversion of primary or secondary alcohols to an aldehyde or ketone , the reagents involved are oxalyl chloride and an organic base in dimethyl sulfoxide. Synthesis of β-hydroxyketone is possible by reacting an enolate with a carbonyl compound. Thus, various reagents can be used to convert a functional group to another such that desired molecular structures are obtained.

Question

Want to see the full answer?

Answer 1

Question

Chapter SRP, Problem 7P

Interpretation Introduction

Interpretation:

The synthesis for the given products is to be outlined by using benzene, toluene or aniline and any other required.

Concept introduction:

Bromination of aromatic rings is possible with Friedel–Craft’s reagent bromine/chlorine in ferric chloride or ferric bromide using N-bromosuccinimide.

Grignard reagents are nucleophiles which are highly reactive, they can be obtained by reacting magnesium in diethyl ether with an alkyl or aryl bromide.

Swern oxidation of alcohols allows conversion of primary or secondary alcohols to an aldehyde or ketone, the reagents involved are oxalyl chloride and an organic base in dimethyl sulfoxide.

Synthesis of β-hydroxyketone is possible by reacting an enolate with a carbonyl compound. Thus, various reagents can be used to convert a functional group to another such that desired molecular structures are obtained.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

You are trying to decide if there is a single reagent you can add that will make the following synthesis possible without any other major side products: xi 1. ☑ 2. H₂O хе i Draw the missing reagent X you think will make this synthesis work in the drawing area below. If there is no reagent that will make your desired product in good yield or without complications, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. There is no reagent that will make this synthesis work without complications. : ☐ S ☐

Predict the major products of this organic reaction: H OH 1. LiAlH4 2. H₂O ? Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry. Click and drag to start drawing a structure. G C टे

For each reaction below, decide if the first stable organic product that forms in solution will create a new C-C bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. NH2 CI MgCl ? Will the first product that forms in this reaction create a new CC bond? Yes No MgBr ? Will the first product that forms in this reaction create a new CC bond? Yes No G टे