(a) Interpretation: The complete IUPAC name of the given molecule is to be written. Concept introduction: Both ketones and aldehydes contain a C = O bond, the carbonyl group. Ketones and aldehydes require adding a suffix to the IUPAC name according to Table E-1. The main chain or ring is the one that contains the highest-priority functional group. The next step is to number the main chain or ring such that the carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order. A locator number is added for the ketone but not for the aldehyde. For a molecule that contains only an aldehyde as a functional group requires dropping the final e and adding the al suffix. For a molecule containing both an aldehyde and a ketone as functional groups, a locator number is added for the ketone but not for the aldehyde. For a molecule containing more than one aldehyde or ketones functional groups, the e in ane is retained. Note that for a cyclic aldehyde, the C = O bond cannot be a part of the ring and is named as cycloalkanecarbaldehyde.

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Question

Chapter E, Problem E.16P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

Both ketones and aldehydes contain a C=O bond, the carbonyl group. Ketones and aldehydes require adding a suffix to the IUPAC name according to Table E-1.

The main chain or ring is the one that contains the highest-priority functional group. The next step is to number the main chain or ring such that the carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order. A locator number is added for the ketone but not for the aldehyde.

For a molecule that contains only an aldehyde as a functional group requires dropping the final e and adding the al suffix.

For a molecule containing both an aldehyde and a ketone as functional groups, a locator number is added for the ketone but not for the aldehyde.

For a molecule containing more than one aldehyde or ketones functional groups, the e in ane is retained.

Note that for a cyclic aldehyde, the C=O bond cannot be a part of the ring and is named as cycloalkanecarbaldehyde.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

Both ketones and aldehydes contain a C=O bond, the carbonyl group. Ketones and aldehydes require adding a suffix to the IUPAC name according to Table E-1.

The main chain or ring is the one that contains the highest-priority functional group. The next step is to number the main chain or ring such that the carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order. A locator number is added for the ketone but not for the aldehyde.

For a molecule that contains only an aldehyde as a functional group requires dropping the final e and adding the al suffix.

For a molecule containing both an aldehyde and a ketone as functional groups, a locator number is added for the ketone but not for the aldehyde.

For a molecule containing more than one aldehyde or ketones functional groups, the e in ane is retained.

Note that for a cyclic aldehyde, the C=O bond cannot be a part of the ring and is named as cycloalkanecarbaldehyde.

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

Both ketones and aldehydes contain a C=O bond, the carbonyl group. Ketones and aldehydes require adding a suffix to the IUPAC name according to Table E-1.

The main chain or ring is the one that contains the highest-priority functional group. The next step is to number the main chain or ring such that the carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order. A locator number is added for the ketone but not for the aldehyde.

For a molecule that contains only an aldehyde as a functional group requires dropping the final e and adding the al suffix.

For a molecule containing both an aldehyde and a ketone as functional groups, a locator number is added for the ketone but not for the aldehyde.

For a molecule containing more than one aldehyde or ketones functional groups, the e in ane is retained.

Note that for a cyclic aldehyde, the C=O bond cannot be a part of the ring and is named as cycloalkanecarbaldehyde.

Interpretation Introduction

(d)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

Both ketones and aldehydes contain a C=O bond, the carbonyl group. Ketones and aldehydes require adding a suffix to the IUPAC name according to Table E-1.

The main chain or ring is the one that contains the highest-priority functional group. The next step is to number the main chain or ring such that the carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order. A locator number is added for the ketone but not for the aldehyde.

For a molecule that contains only an aldehyde as a functional group requires dropping the final e and adding the al suffix.

For a molecule containing both an aldehyde and a ketone as functional groups, a locator number is added for the ketone but not for the aldehyde.

For a molecule containing more than one aldehyde or ketones functional groups, the e in ane is retained.

Note that for a cyclic aldehyde, the C=O bond cannot be a part of the ring and is named as cycloalkanecarbaldehyde.

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Answer 2

Question

Chapter E, Problem E.16P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

Both ketones and aldehydes contain a C=O bond, the carbonyl group. Ketones and aldehydes require adding a suffix to the IUPAC name according to Table E-1.

The main chain or ring is the one that contains the highest-priority functional group. The next step is to number the main chain or ring such that the carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order. A locator number is added for the ketone but not for the aldehyde.

For a molecule that contains only an aldehyde as a functional group requires dropping the final e and adding the al suffix.

For a molecule containing both an aldehyde and a ketone as functional groups, a locator number is added for the ketone but not for the aldehyde.

For a molecule containing more than one aldehyde or ketones functional groups, the e in ane is retained.

Note that for a cyclic aldehyde, the C=O bond cannot be a part of the ring and is named as cycloalkanecarbaldehyde.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

Both ketones and aldehydes contain a C=O bond, the carbonyl group. Ketones and aldehydes require adding a suffix to the IUPAC name according to Table E-1.

The main chain or ring is the one that contains the highest-priority functional group. The next step is to number the main chain or ring such that the carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order. A locator number is added for the ketone but not for the aldehyde.

For a molecule that contains only an aldehyde as a functional group requires dropping the final e and adding the al suffix.

For a molecule containing both an aldehyde and a ketone as functional groups, a locator number is added for the ketone but not for the aldehyde.

For a molecule containing more than one aldehyde or ketones functional groups, the e in ane is retained.

Note that for a cyclic aldehyde, the C=O bond cannot be a part of the ring and is named as cycloalkanecarbaldehyde.

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

Both ketones and aldehydes contain a C=O bond, the carbonyl group. Ketones and aldehydes require adding a suffix to the IUPAC name according to Table E-1.

The main chain or ring is the one that contains the highest-priority functional group. The next step is to number the main chain or ring such that the carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order. A locator number is added for the ketone but not for the aldehyde.

For a molecule that contains only an aldehyde as a functional group requires dropping the final e and adding the al suffix.

For a molecule containing both an aldehyde and a ketone as functional groups, a locator number is added for the ketone but not for the aldehyde.

For a molecule containing more than one aldehyde or ketones functional groups, the e in ane is retained.

Note that for a cyclic aldehyde, the C=O bond cannot be a part of the ring and is named as cycloalkanecarbaldehyde.

Interpretation Introduction

(d)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

Both ketones and aldehydes contain a C=O bond, the carbonyl group. Ketones and aldehydes require adding a suffix to the IUPAC name according to Table E-1.

The main chain or ring is the one that contains the highest-priority functional group. The next step is to number the main chain or ring such that the carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order. A locator number is added for the ketone but not for the aldehyde.

For a molecule that contains only an aldehyde as a functional group requires dropping the final e and adding the al suffix.

For a molecule containing both an aldehyde and a ketone as functional groups, a locator number is added for the ketone but not for the aldehyde.

For a molecule containing more than one aldehyde or ketones functional groups, the e in ane is retained.

Note that for a cyclic aldehyde, the C=O bond cannot be a part of the ring and is named as cycloalkanecarbaldehyde.

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Answer 3

Question

Chapter E, Problem E.16P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

Both ketones and aldehydes contain a C=O bond, the carbonyl group. Ketones and aldehydes require adding a suffix to the IUPAC name according to Table E-1.

The main chain or ring is the one that contains the highest-priority functional group. The next step is to number the main chain or ring such that the carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order. A locator number is added for the ketone but not for the aldehyde.

For a molecule that contains only an aldehyde as a functional group requires dropping the final e and adding the al suffix.

For a molecule containing both an aldehyde and a ketone as functional groups, a locator number is added for the ketone but not for the aldehyde.

For a molecule containing more than one aldehyde or ketones functional groups, the e in ane is retained.

Note that for a cyclic aldehyde, the C=O bond cannot be a part of the ring and is named as cycloalkanecarbaldehyde.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

Both ketones and aldehydes contain a C=O bond, the carbonyl group. Ketones and aldehydes require adding a suffix to the IUPAC name according to Table E-1.

The main chain or ring is the one that contains the highest-priority functional group. The next step is to number the main chain or ring such that the carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order. A locator number is added for the ketone but not for the aldehyde.

For a molecule that contains only an aldehyde as a functional group requires dropping the final e and adding the al suffix.

For a molecule containing both an aldehyde and a ketone as functional groups, a locator number is added for the ketone but not for the aldehyde.

For a molecule containing more than one aldehyde or ketones functional groups, the e in ane is retained.

Note that for a cyclic aldehyde, the C=O bond cannot be a part of the ring and is named as cycloalkanecarbaldehyde.

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

Both ketones and aldehydes contain a C=O bond, the carbonyl group. Ketones and aldehydes require adding a suffix to the IUPAC name according to Table E-1.

The main chain or ring is the one that contains the highest-priority functional group. The next step is to number the main chain or ring such that the carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order. A locator number is added for the ketone but not for the aldehyde.

For a molecule that contains only an aldehyde as a functional group requires dropping the final e and adding the al suffix.

For a molecule containing both an aldehyde and a ketone as functional groups, a locator number is added for the ketone but not for the aldehyde.

For a molecule containing more than one aldehyde or ketones functional groups, the e in ane is retained.

Note that for a cyclic aldehyde, the C=O bond cannot be a part of the ring and is named as cycloalkanecarbaldehyde.

Interpretation Introduction

(d)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

Both ketones and aldehydes contain a C=O bond, the carbonyl group. Ketones and aldehydes require adding a suffix to the IUPAC name according to Table E-1.

The main chain or ring is the one that contains the highest-priority functional group. The next step is to number the main chain or ring such that the carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order. A locator number is added for the ketone but not for the aldehyde.

For a molecule that contains only an aldehyde as a functional group requires dropping the final e and adding the al suffix.

For a molecule containing both an aldehyde and a ketone as functional groups, a locator number is added for the ketone but not for the aldehyde.

For a molecule containing more than one aldehyde or ketones functional groups, the e in ane is retained.

Note that for a cyclic aldehyde, the C=O bond cannot be a part of the ring and is named as cycloalkanecarbaldehyde.

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Answer 4

Question

Chapter E, Problem E.16P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

Both ketones and aldehydes contain a C=O bond, the carbonyl group. Ketones and aldehydes require adding a suffix to the IUPAC name according to Table E-1.

The main chain or ring is the one that contains the highest-priority functional group. The next step is to number the main chain or ring such that the carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order. A locator number is added for the ketone but not for the aldehyde.

For a molecule that contains only an aldehyde as a functional group requires dropping the final e and adding the al suffix.

For a molecule containing both an aldehyde and a ketone as functional groups, a locator number is added for the ketone but not for the aldehyde.

For a molecule containing more than one aldehyde or ketones functional groups, the e in ane is retained.

Note that for a cyclic aldehyde, the C=O bond cannot be a part of the ring and is named as cycloalkanecarbaldehyde.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

Both ketones and aldehydes contain a C=O bond, the carbonyl group. Ketones and aldehydes require adding a suffix to the IUPAC name according to Table E-1.

The main chain or ring is the one that contains the highest-priority functional group. The next step is to number the main chain or ring such that the carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order. A locator number is added for the ketone but not for the aldehyde.

For a molecule that contains only an aldehyde as a functional group requires dropping the final e and adding the al suffix.

For a molecule containing both an aldehyde and a ketone as functional groups, a locator number is added for the ketone but not for the aldehyde.

For a molecule containing more than one aldehyde or ketones functional groups, the e in ane is retained.

Note that for a cyclic aldehyde, the C=O bond cannot be a part of the ring and is named as cycloalkanecarbaldehyde.

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

Both ketones and aldehydes contain a C=O bond, the carbonyl group. Ketones and aldehydes require adding a suffix to the IUPAC name according to Table E-1.

The main chain or ring is the one that contains the highest-priority functional group. The next step is to number the main chain or ring such that the carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order. A locator number is added for the ketone but not for the aldehyde.

For a molecule that contains only an aldehyde as a functional group requires dropping the final e and adding the al suffix.

For a molecule containing both an aldehyde and a ketone as functional groups, a locator number is added for the ketone but not for the aldehyde.

For a molecule containing more than one aldehyde or ketones functional groups, the e in ane is retained.

Note that for a cyclic aldehyde, the C=O bond cannot be a part of the ring and is named as cycloalkanecarbaldehyde.

Interpretation Introduction

(d)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

Both ketones and aldehydes contain a C=O bond, the carbonyl group. Ketones and aldehydes require adding a suffix to the IUPAC name according to Table E-1.

The main chain or ring is the one that contains the highest-priority functional group. The next step is to number the main chain or ring such that the carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order. A locator number is added for the ketone but not for the aldehyde.

For a molecule that contains only an aldehyde as a functional group requires dropping the final e and adding the al suffix.

For a molecule containing both an aldehyde and a ketone as functional groups, a locator number is added for the ketone but not for the aldehyde.

For a molecule containing more than one aldehyde or ketones functional groups, the e in ane is retained.

Note that for a cyclic aldehyde, the C=O bond cannot be a part of the ring and is named as cycloalkanecarbaldehyde.

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Answer 5

Chapter E, Problem E.16P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

Both ketones and aldehydes contain a C=O bond, the carbonyl group. Ketones and aldehydes require adding a suffix to the IUPAC name according to Table E-1.

The main chain or ring is the one that contains the highest-priority functional group. The next step is to number the main chain or ring such that the carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order. A locator number is added for the ketone but not for the aldehyde.

For a molecule that contains only an aldehyde as a functional group requires dropping the final e and adding the al suffix.

For a molecule containing both an aldehyde and a ketone as functional groups, a locator number is added for the ketone but not for the aldehyde.

For a molecule containing more than one aldehyde or ketones functional groups, the e in ane is retained.

Note that for a cyclic aldehyde, the C=O bond cannot be a part of the ring and is named as cycloalkanecarbaldehyde.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

Both ketones and aldehydes contain a C=O bond, the carbonyl group. Ketones and aldehydes require adding a suffix to the IUPAC name according to Table E-1.

The main chain or ring is the one that contains the highest-priority functional group. The next step is to number the main chain or ring such that the carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order. A locator number is added for the ketone but not for the aldehyde.

For a molecule that contains only an aldehyde as a functional group requires dropping the final e and adding the al suffix.

For a molecule containing both an aldehyde and a ketone as functional groups, a locator number is added for the ketone but not for the aldehyde.

For a molecule containing more than one aldehyde or ketones functional groups, the e in ane is retained.

Note that for a cyclic aldehyde, the C=O bond cannot be a part of the ring and is named as cycloalkanecarbaldehyde.

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

Both ketones and aldehydes contain a C=O bond, the carbonyl group. Ketones and aldehydes require adding a suffix to the IUPAC name according to Table E-1.

The main chain or ring is the one that contains the highest-priority functional group. The next step is to number the main chain or ring such that the carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order. A locator number is added for the ketone but not for the aldehyde.

For a molecule that contains only an aldehyde as a functional group requires dropping the final e and adding the al suffix.

For a molecule containing both an aldehyde and a ketone as functional groups, a locator number is added for the ketone but not for the aldehyde.

For a molecule containing more than one aldehyde or ketones functional groups, the e in ane is retained.

Note that for a cyclic aldehyde, the C=O bond cannot be a part of the ring and is named as cycloalkanecarbaldehyde.

Interpretation Introduction

(d)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

Both ketones and aldehydes contain a C=O bond, the carbonyl group. Ketones and aldehydes require adding a suffix to the IUPAC name according to Table E-1.

The main chain or ring is the one that contains the highest-priority functional group. The next step is to number the main chain or ring such that the carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order. A locator number is added for the ketone but not for the aldehyde.

For a molecule that contains only an aldehyde as a functional group requires dropping the final e and adding the al suffix.

For a molecule containing both an aldehyde and a ketone as functional groups, a locator number is added for the ketone but not for the aldehyde.

For a molecule containing more than one aldehyde or ketones functional groups, the e in ane is retained.

Note that for a cyclic aldehyde, the C=O bond cannot be a part of the ring and is named as cycloalkanecarbaldehyde.

Answer 6

Chapter E, Problem E.16P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

Both ketones and aldehydes contain a C=O bond, the carbonyl group. Ketones and aldehydes require adding a suffix to the IUPAC name according to Table E-1.

The main chain or ring is the one that contains the highest-priority functional group. The next step is to number the main chain or ring such that the carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order. A locator number is added for the ketone but not for the aldehyde.

For a molecule that contains only an aldehyde as a functional group requires dropping the final e and adding the al suffix.

For a molecule containing both an aldehyde and a ketone as functional groups, a locator number is added for the ketone but not for the aldehyde.

For a molecule containing more than one aldehyde or ketones functional groups, the e in ane is retained.

Note that for a cyclic aldehyde, the C=O bond cannot be a part of the ring and is named as cycloalkanecarbaldehyde.

Answer 7

Chapter E, Problem E.16P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

Both ketones and aldehydes contain a C=O bond, the carbonyl group. Ketones and aldehydes require adding a suffix to the IUPAC name according to Table E-1.

The main chain or ring is the one that contains the highest-priority functional group. The next step is to number the main chain or ring such that the carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order. A locator number is added for the ketone but not for the aldehyde.

For a molecule that contains only an aldehyde as a functional group requires dropping the final e and adding the al suffix.

For a molecule containing both an aldehyde and a ketone as functional groups, a locator number is added for the ketone but not for the aldehyde.

For a molecule containing more than one aldehyde or ketones functional groups, the e in ane is retained.

Note that for a cyclic aldehyde, the C=O bond cannot be a part of the ring and is named as cycloalkanecarbaldehyde.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

Both ketones and aldehydes contain a C=O bond, the carbonyl group. Ketones and aldehydes require adding a suffix to the IUPAC name according to Table E-1.

The main chain or ring is the one that contains the highest-priority functional group. The next step is to number the main chain or ring such that the carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order. A locator number is added for the ketone but not for the aldehyde.

For a molecule that contains only an aldehyde as a functional group requires dropping the final e and adding the al suffix.

For a molecule containing both an aldehyde and a ketone as functional groups, a locator number is added for the ketone but not for the aldehyde.

For a molecule containing more than one aldehyde or ketones functional groups, the e in ane is retained.

Note that for a cyclic aldehyde, the C=O bond cannot be a part of the ring and is named as cycloalkanecarbaldehyde.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

Both ketones and aldehydes contain a C=O bond, the carbonyl group. Ketones and aldehydes require adding a suffix to the IUPAC name according to Table E-1.

The main chain or ring is the one that contains the highest-priority functional group. The next step is to number the main chain or ring such that the carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order. A locator number is added for the ketone but not for the aldehyde.

For a molecule that contains only an aldehyde as a functional group requires dropping the final e and adding the al suffix.

For a molecule containing both an aldehyde and a ketone as functional groups, a locator number is added for the ketone but not for the aldehyde.

For a molecule containing more than one aldehyde or ketones functional groups, the e in ane is retained.

Note that for a cyclic aldehyde, the C=O bond cannot be a part of the ring and is named as cycloalkanecarbaldehyde.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

Both ketones and aldehydes contain a C=O bond, the carbonyl group. Ketones and aldehydes require adding a suffix to the IUPAC name according to Table E-1.

The main chain or ring is the one that contains the highest-priority functional group. The next step is to number the main chain or ring such that the carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order. A locator number is added for the ketone but not for the aldehyde.

For a molecule that contains only an aldehyde as a functional group requires dropping the final e and adding the al suffix.

For a molecule containing both an aldehyde and a ketone as functional groups, a locator number is added for the ketone but not for the aldehyde.

For a molecule containing more than one aldehyde or ketones functional groups, the e in ane is retained.

Note that for a cyclic aldehyde, the C=O bond cannot be a part of the ring and is named as cycloalkanecarbaldehyde.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

Both ketones and aldehydes contain a C=O bond, the carbonyl group. Ketones and aldehydes require adding a suffix to the IUPAC name according to Table E-1.

The main chain or ring is the one that contains the highest-priority functional group. The next step is to number the main chain or ring such that the carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order. A locator number is added for the ketone but not for the aldehyde.

For a molecule that contains only an aldehyde as a functional group requires dropping the final e and adding the al suffix.

For a molecule containing both an aldehyde and a ketone as functional groups, a locator number is added for the ketone but not for the aldehyde.

For a molecule containing more than one aldehyde or ketones functional groups, the e in ane is retained.

Note that for a cyclic aldehyde, the C=O bond cannot be a part of the ring and is named as cycloalkanecarbaldehyde.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

Both ketones and aldehydes contain a C=O bond, the carbonyl group. Ketones and aldehydes require adding a suffix to the IUPAC name according to Table E-1.

The main chain or ring is the one that contains the highest-priority functional group. The next step is to number the main chain or ring such that the carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order. A locator number is added for the ketone but not for the aldehyde.

For a molecule that contains only an aldehyde as a functional group requires dropping the final e and adding the al suffix.

For a molecule containing both an aldehyde and a ketone as functional groups, a locator number is added for the ketone but not for the aldehyde.

For a molecule containing more than one aldehyde or ketones functional groups, the e in ane is retained.

Note that for a cyclic aldehyde, the C=O bond cannot be a part of the ring and is named as cycloalkanecarbaldehyde.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

Both ketones and aldehydes contain a C=O bond, the carbonyl group. Ketones and aldehydes require adding a suffix to the IUPAC name according to Table E-1.

The main chain or ring is the one that contains the highest-priority functional group. The next step is to number the main chain or ring such that the carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless needed. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order. A locator number is added for the ketone but not for the aldehyde.

For a molecule that contains only an aldehyde as a functional group requires dropping the final e and adding the al suffix.

For a molecule containing both an aldehyde and a ketone as functional groups, a locator number is added for the ketone but not for the aldehyde.

For a molecule containing more than one aldehyde or ketones functional groups, the e in ane is retained.

Note that for a cyclic aldehyde, the C=O bond cannot be a part of the ring and is named as cycloalkanecarbaldehyde.

Answer 14

Expert Solution & Answer

Answer 15

Expert Solution & Answer

Answer 16

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Answer 17

Ch. E - Prob. E.1P Ch. E - Prob. E.2P Ch. E - Prob. E.3P Ch. E - Prob. E.4P Ch. E - Prob. E.5P Ch. E - Prob. E.6P Ch. E - Prob. E.7P Ch. E - Prob. E.8P Ch. E - Prob. E.9P Ch. E - Prob. E.10P

Solution Summary: The author explains that the complete IUPAC name of the given molecule is 4-oxoheptanal.

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Chapter E Solutions