(a) Interpretation: The complete IUPAC name of the given molecule is to be written. Concept introduction: The IUPAC name of a compound consists of three parts, prefix, root and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other, low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

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Answer 1

Question

Chapter E, Problem E.27P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other, low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root, and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root, and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

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(a 4 shows scanning electron microscope (SEM) images of extruded actions of packing bed for two capillary columns of different diameters, al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the same stationary phase, spherical particles with 1-um diameter. A) When the columns were prepared, the figure shows that the column with the larger diameter has more packing irregularities. Explain this observation. B) Predict what affect this should have on band broadening and discuss your prediction using the van Deemter terms. C) Does this figure support your explanations in application question 33? Explain why or why not and make any changes in your answers in light of this figure. Figure 4 SEM images of sections of packed columns for a) 750 and b) 30-um-i.d. capillary columns.³

fcrip = ↓ bandwidth Il temp 32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual components of the van Deemter equation and consequently, band broadening? Increase temperature Longer column Using a gas mobile phase instead of liquid Smaller particle stationary phase Multiple Paths Diffusion Mass Transfer

34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.). A) Predict whether decreasing the column inner diameters increase or decrease bandwidth. B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or decreasing bandwidth as a function of i.d. and justify your answer. Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles. 35 20 H(um) 큰 20 15 90 0+ 1500 100 75 550 01 02 594 05 μ(cm/sec) 30 15 10

Answer 2

Question

Chapter E, Problem E.27P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other, low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root, and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root, and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

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Answer 3

Question

Chapter E, Problem E.27P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other, low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root, and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root, and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

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Answer 4

Question

Chapter E, Problem E.27P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other, low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root, and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root, and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

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Answer 5

Chapter E, Problem E.27P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other, low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root, and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root, and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

Answer 6

Chapter E, Problem E.27P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other, low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

Answer 7

Chapter E, Problem E.27P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other, low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root, and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root, and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root, and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name of the given molecule is to be written.

Concept introduction:

The IUPAC name of a compound consists of three parts, prefix, root, and suffix. The root is the longest continuous carbon chain or the largest ring that bears the highest priority functional group. The suffix refers to the highest priority functional group. The functional group name suffix replaces the last ‘e’ in the root alkyl/aryl name. The root chain or ring carbons are numbered so that the highest priority group gets the lowest possible location numbers. The number is inserted between the root and the suffix unless redundant. Any other low priority functional groups are listed alphabetically in the prefix, along with their location numbers. If the root is a ring compound, the ring is numbered in the direction that gives the lowest possible numbers to other substituents if present. A prefix di, tri, etc. is used in case two or more instances of the functional group are present.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. E - Prob. E.1P Ch. E - Prob. E.2P Ch. E - Prob. E.3P Ch. E - Prob. E.4P Ch. E - Prob. E.5P Ch. E - Prob. E.6P Ch. E - Prob. E.7P Ch. E - Prob. E.8P Ch. E - Prob. E.9P Ch. E - Prob. E.10P

Solution Summary: The author explains that the IUPAC name of a compound consists of three parts, prefix, root and suffix.

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