(a) Interpretation: For the given molecule, the complete IUPAC name is to be written. Concept introduction: In the nomenclature of amines , if the Nitrogen atom of an amine is bonded to more than one alkyl group, the root is established by the alkyl group that makes the longest chain or largest carbon ring. Any other alkyl group, attached to the nitrogen atom in amine, is treated as substituent, and each of them is given an italic N as a locator instead of a number. The substituents attached to the nitrogen atom in amine are named in an alphabetical order.

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Answer 1

Question

Chapter E, Problem E.31P

Interpretation Introduction

(a)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

In the nomenclature of amines, if the Nitrogen atom of an amine is bonded to more than one alkyl group, the root is established by the alkyl group that makes the longest chain or largest carbon ring. Any other alkyl group, attached to the nitrogen atom in amine, is treated as substituent, and each of them is given an italic N as a locator instead of a number. The substituents attached to the nitrogen atom in amine are named in an alphabetical order.

Interpretation Introduction

(b)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

In the nomenclature of amines, if the Nitrogen atom of an amine is bonded to more than one alkyl group, the root is established by the alkyl group that makes the longest chain or largest carbon ring. Any other alkyl group, attached to the nitrogen atom in amine is treated as substituent, and each of them is given an italic N as a locator instead of a number. The substituents attached to the nitrogen atom in amine are named in an alphabetical order.

Interpretation Introduction

(c)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

In the nomenclature of amines, if the Nitrogen atom of an amine is bonded to more than one alkyl group, then the root is established by the alkyl group that makes up the longest chain or largest carbon ring. Any other alkyl groups attached to the nitrogen atom in amine are treated as substituents and each of them is given an italic N as a locator instead of a number. The substituents attached to the nitrogen atom in amine are named in an alphabetical order.

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Use the Henderson-Hasselbalch equation to calculate pH of a buffer containing 0.050M benzoic acidand 0.150M sodium benzoate. The Ka of benzoic acid is 6.5 x 10-5

Answer 2

Question

Chapter E, Problem E.31P

Interpretation Introduction

(a)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

In the nomenclature of amines, if the Nitrogen atom of an amine is bonded to more than one alkyl group, the root is established by the alkyl group that makes the longest chain or largest carbon ring. Any other alkyl group, attached to the nitrogen atom in amine, is treated as substituent, and each of them is given an italic N as a locator instead of a number. The substituents attached to the nitrogen atom in amine are named in an alphabetical order.

Interpretation Introduction

(b)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

In the nomenclature of amines, if the Nitrogen atom of an amine is bonded to more than one alkyl group, the root is established by the alkyl group that makes the longest chain or largest carbon ring. Any other alkyl group, attached to the nitrogen atom in amine is treated as substituent, and each of them is given an italic N as a locator instead of a number. The substituents attached to the nitrogen atom in amine are named in an alphabetical order.

Interpretation Introduction

(c)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

In the nomenclature of amines, if the Nitrogen atom of an amine is bonded to more than one alkyl group, then the root is established by the alkyl group that makes up the longest chain or largest carbon ring. Any other alkyl groups attached to the nitrogen atom in amine are treated as substituents and each of them is given an italic N as a locator instead of a number. The substituents attached to the nitrogen atom in amine are named in an alphabetical order.

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Answer 3

Question

Chapter E, Problem E.31P

Interpretation Introduction

(a)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

In the nomenclature of amines, if the Nitrogen atom of an amine is bonded to more than one alkyl group, the root is established by the alkyl group that makes the longest chain or largest carbon ring. Any other alkyl group, attached to the nitrogen atom in amine, is treated as substituent, and each of them is given an italic N as a locator instead of a number. The substituents attached to the nitrogen atom in amine are named in an alphabetical order.

Interpretation Introduction

(b)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

In the nomenclature of amines, if the Nitrogen atom of an amine is bonded to more than one alkyl group, the root is established by the alkyl group that makes the longest chain or largest carbon ring. Any other alkyl group, attached to the nitrogen atom in amine is treated as substituent, and each of them is given an italic N as a locator instead of a number. The substituents attached to the nitrogen atom in amine are named in an alphabetical order.

Interpretation Introduction

(c)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

In the nomenclature of amines, if the Nitrogen atom of an amine is bonded to more than one alkyl group, then the root is established by the alkyl group that makes up the longest chain or largest carbon ring. Any other alkyl groups attached to the nitrogen atom in amine are treated as substituents and each of them is given an italic N as a locator instead of a number. The substituents attached to the nitrogen atom in amine are named in an alphabetical order.

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Answer 4

Question

Chapter E, Problem E.31P

Interpretation Introduction

(a)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

In the nomenclature of amines, if the Nitrogen atom of an amine is bonded to more than one alkyl group, the root is established by the alkyl group that makes the longest chain or largest carbon ring. Any other alkyl group, attached to the nitrogen atom in amine, is treated as substituent, and each of them is given an italic N as a locator instead of a number. The substituents attached to the nitrogen atom in amine are named in an alphabetical order.

Interpretation Introduction

(b)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

In the nomenclature of amines, if the Nitrogen atom of an amine is bonded to more than one alkyl group, the root is established by the alkyl group that makes the longest chain or largest carbon ring. Any other alkyl group, attached to the nitrogen atom in amine is treated as substituent, and each of them is given an italic N as a locator instead of a number. The substituents attached to the nitrogen atom in amine are named in an alphabetical order.

Interpretation Introduction

(c)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

In the nomenclature of amines, if the Nitrogen atom of an amine is bonded to more than one alkyl group, then the root is established by the alkyl group that makes up the longest chain or largest carbon ring. Any other alkyl groups attached to the nitrogen atom in amine are treated as substituents and each of them is given an italic N as a locator instead of a number. The substituents attached to the nitrogen atom in amine are named in an alphabetical order.

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Answer 5

Chapter E, Problem E.31P

Interpretation Introduction

(a)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

In the nomenclature of amines, if the Nitrogen atom of an amine is bonded to more than one alkyl group, the root is established by the alkyl group that makes the longest chain or largest carbon ring. Any other alkyl group, attached to the nitrogen atom in amine, is treated as substituent, and each of them is given an italic N as a locator instead of a number. The substituents attached to the nitrogen atom in amine are named in an alphabetical order.

Interpretation Introduction

(b)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

In the nomenclature of amines, if the Nitrogen atom of an amine is bonded to more than one alkyl group, the root is established by the alkyl group that makes the longest chain or largest carbon ring. Any other alkyl group, attached to the nitrogen atom in amine is treated as substituent, and each of them is given an italic N as a locator instead of a number. The substituents attached to the nitrogen atom in amine are named in an alphabetical order.

Interpretation Introduction

(c)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

In the nomenclature of amines, if the Nitrogen atom of an amine is bonded to more than one alkyl group, then the root is established by the alkyl group that makes up the longest chain or largest carbon ring. Any other alkyl groups attached to the nitrogen atom in amine are treated as substituents and each of them is given an italic N as a locator instead of a number. The substituents attached to the nitrogen atom in amine are named in an alphabetical order.

Answer 6

Chapter E, Problem E.31P

Interpretation Introduction

(a)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

In the nomenclature of amines, if the Nitrogen atom of an amine is bonded to more than one alkyl group, the root is established by the alkyl group that makes the longest chain or largest carbon ring. Any other alkyl group, attached to the nitrogen atom in amine, is treated as substituent, and each of them is given an italic N as a locator instead of a number. The substituents attached to the nitrogen atom in amine are named in an alphabetical order.

Answer 7

Chapter E, Problem E.31P

Interpretation Introduction

(a)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

In the nomenclature of amines, if the Nitrogen atom of an amine is bonded to more than one alkyl group, the root is established by the alkyl group that makes the longest chain or largest carbon ring. Any other alkyl group, attached to the nitrogen atom in amine, is treated as substituent, and each of them is given an italic N as a locator instead of a number. The substituents attached to the nitrogen atom in amine are named in an alphabetical order.

Answer 8

Interpretation Introduction

(b)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

In the nomenclature of amines, if the Nitrogen atom of an amine is bonded to more than one alkyl group, the root is established by the alkyl group that makes the longest chain or largest carbon ring. Any other alkyl group, attached to the nitrogen atom in amine is treated as substituent, and each of them is given an italic N as a locator instead of a number. The substituents attached to the nitrogen atom in amine are named in an alphabetical order.

Answer 9

Interpretation Introduction

(b)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

In the nomenclature of amines, if the Nitrogen atom of an amine is bonded to more than one alkyl group, the root is established by the alkyl group that makes the longest chain or largest carbon ring. Any other alkyl group, attached to the nitrogen atom in amine is treated as substituent, and each of them is given an italic N as a locator instead of a number. The substituents attached to the nitrogen atom in amine are named in an alphabetical order.

Answer 10

Interpretation Introduction

(c)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

In the nomenclature of amines, if the Nitrogen atom of an amine is bonded to more than one alkyl group, then the root is established by the alkyl group that makes up the longest chain or largest carbon ring. Any other alkyl groups attached to the nitrogen atom in amine are treated as substituents and each of them is given an italic N as a locator instead of a number. The substituents attached to the nitrogen atom in amine are named in an alphabetical order.

Answer 11

Interpretation Introduction

(c)

Interpretation:

For the given molecule, the complete IUPAC name is to be written.

Concept introduction:

In the nomenclature of amines, if the Nitrogen atom of an amine is bonded to more than one alkyl group, then the root is established by the alkyl group that makes up the longest chain or largest carbon ring. Any other alkyl groups attached to the nitrogen atom in amine are treated as substituents and each of them is given an italic N as a locator instead of a number. The substituents attached to the nitrogen atom in amine are named in an alphabetical order.

Answer 12

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Answer 13

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Answer 15

Ch. E - Prob. E.1P Ch. E - Prob. E.2P Ch. E - Prob. E.3P Ch. E - Prob. E.4P Ch. E - Prob. E.5P Ch. E - Prob. E.6P Ch. E - Prob. E.7P Ch. E - Prob. E.8P Ch. E - Prob. E.9P Ch. E - Prob. E.10P

Solution Summary: The complete IUPAC name for the given molecule is N-ethylpentan-1-amine.

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