General Chemistry - Standalone book (MindTap Course List)
11th Edition
ISBN: 9781305580343
Author: Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher: Cengage Learning
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Textbook Question
Chapter 9.5, Problem 9.8E
Using electronegativities, decide which of the following bonds is most polar: C─O, C─S, H─Br.
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Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass
spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained.
Draw the structures of these fragments.
For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.
Chapter 9 Solutions
General Chemistry - Standalone book (MindTap Course List)
Ch. 9.1 - Represent the transfer of electrons from magnesium...Ch. 9.2 - Prob. 9.2ECh. 9.2 - Prob. 9.3ECh. 9.2 - Prob. 9.4ECh. 9.2 - The following are electron configurations for some...Ch. 9.3 - Which has the larger radius, S or S2? Explain.Ch. 9.3 - Without looking at Table 9.3, arrange the...Ch. 9.3 - Prob. 9.7ECh. 9.5 - Using electronegativities, decide which of the...Ch. 9.6 - Dichlorodifluoromethane, CCl2F2, is a gas used as...
Ch. 9.6 - Prob. 9.10ECh. 9.6 - Prob. 9.11ECh. 9.6 - Prob. 9.2CCCh. 9.7 - Prob. 9.12ECh. 9.8 - Prob. 9.13ECh. 9.8 - Prob. 9.14ECh. 9.9 - Prob. 9.15ECh. 9.9 - Prob. 9.3CCCh. 9.10 - Estimate the OH bond length in H2O from the...Ch. 9.10 - Formic acid, isolated in 1670, is the irritant in...Ch. 9.11 - Use bond enthalpies to estimate the enthalpy...Ch. 9 - Describe the formation of a sodium chloride...Ch. 9 - Prob. 9.2QPCh. 9 - Prob. 9.3QPCh. 9 - Define lattice energy for potassium bromide.Ch. 9 - Why do most monatomic cations of the main-group...Ch. 9 - Prob. 9.6QPCh. 9 - Prob. 9.7QPCh. 9 - Prob. 9.8QPCh. 9 - Prob. 9.9QPCh. 9 - Draw a potential-energy diagram for a molecule...Ch. 9 - Prob. 9.11QPCh. 9 - Prob. 9.12QPCh. 9 - Prob. 9.13QPCh. 9 - Prob. 9.14QPCh. 9 - Prob. 9.15QPCh. 9 - Prob. 9.16QPCh. 9 - Prob. 9.17QPCh. 9 - Prob. 9.18QPCh. 9 - Which of the following contains both ionic and...Ch. 9 - The radii of the species S, S+, and S decrease in...Ch. 9 - Prob. 9.21QPCh. 9 - Prob. 9.22QPCh. 9 - Prob. 9.23QPCh. 9 - Bond Enthalpy When atoms of the hypothetical...Ch. 9 - You land on a distant planet in another universe...Ch. 9 - Which of the following represent configurations of...Ch. 9 - Prob. 9.27QPCh. 9 - Prob. 9.28QPCh. 9 - Prob. 9.29QPCh. 9 - For each of the following molecular models, write...Ch. 9 - For each of the following molecular formulas, draw...Ch. 9 - Below are three resonance formulas for N2O...Ch. 9 - Lithium, Li, reacts with element X to form an...Ch. 9 - Prob. 9.34QPCh. 9 - Prob. 9.35QPCh. 9 - Prob. 9.36QPCh. 9 - Use Lewis symbols to represent the transfer of...Ch. 9 - Use Lewis symbols to represent the electron...Ch. 9 - Prob. 9.39QPCh. 9 - Prob. 9.40QPCh. 9 - Prob. 9.41QPCh. 9 - Prob. 9.42QPCh. 9 - Prob. 9.43QPCh. 9 - Prob. 9.44QPCh. 9 - Prob. 9.45QPCh. 9 - Prob. 9.46QPCh. 9 - Prob. 9.47QPCh. 9 - Which has the larger radius, N3 or P3? Explain....Ch. 9 - Arrange the following in order of increasing ionic...Ch. 9 - Arrange the following in order of increasing ionic...Ch. 9 - Use Lewis symbols to show the reaction of atoms to...Ch. 9 - Prob. 9.52QPCh. 9 - Assuming that the atoms form the normal number of...Ch. 9 - Assuming that the atoms form the normal number of...Ch. 9 - Prob. 9.55QPCh. 9 - Prob. 9.56QPCh. 9 - Arrange the following bonds in order of increasing...Ch. 9 - Decide which of the following bonds is least polar...Ch. 9 - Prob. 9.59QPCh. 9 - Prob. 9.60QPCh. 9 - Prob. 9.61QPCh. 9 - Write Lewis formulas for the following molecules:...Ch. 9 - Write Lewis formulas for the following molecules:...Ch. 9 - Write Lewis formulas for the following molecules:...Ch. 9 - Write Lewis formulas for the following ions: a ClO...Ch. 9 - Write Lewis formulas for the following ions: a...Ch. 9 - Write resonance descriptions for the following: a...Ch. 9 - Prob. 9.68QPCh. 9 - Prob. 9.69QPCh. 9 - Prob. 9.70QPCh. 9 - Write Lewis formulas for the following: a XeF2 b...Ch. 9 - Write Lewis formulas for the following: a I3 b...Ch. 9 - Write Lewis formulas for the following: a BCl3 b...Ch. 9 - Write Lewis formulas for the following: a BeF2 b...Ch. 9 - Write a Lewis formula for each of the following,...Ch. 9 - Write a Lewis formula for each of the following,...Ch. 9 - Prob. 9.77QPCh. 9 - For each of the following, use formal charges to...Ch. 9 - Prob. 9.79QPCh. 9 - Prob. 9.80QPCh. 9 - Calculate the bond length for each of the...Ch. 9 - Prob. 9.82QPCh. 9 - One of the following compounds has a...Ch. 9 - Prob. 9.84QPCh. 9 - Use bond enthalpies (Table 9.5) to estimate H for...Ch. 9 - A commercial process for preparing ethanol (ethyl...Ch. 9 - For each of the following pairs of elements, state...Ch. 9 - For each of the following pairs of elements, state...Ch. 9 - Prob. 9.89QPCh. 9 - Prob. 9.90QPCh. 9 - Iodic acid, HIO3, is a colorless, crystalline...Ch. 9 - Prob. 9.92QPCh. 9 - Sodium amide, known commercially as sodamide, is...Ch. 9 - Prob. 9.94QPCh. 9 - Nitronium perchlorate, NO2ClO4, is a reactive salt...Ch. 9 - Solid phosphorus pentabromide, PBr5, has been...Ch. 9 - Write electron-dot formulas for the following: a...Ch. 9 - Prob. 9.98QPCh. 9 - Prob. 9.99QPCh. 9 - Write Lewis formulas for the following: a AlCl4 b...Ch. 9 - Prob. 9.101QPCh. 9 - Prob. 9.102QPCh. 9 - Prob. 9.103QPCh. 9 - Acetic acid has the structure CH3CO(OH), in which...Ch. 9 - Prob. 9.105QPCh. 9 - Methyl nitrite has the structure No attempt has...Ch. 9 - Prob. 9.107QPCh. 9 - Prob. 9.108QPCh. 9 - Use bond enthalpies to estimate H for the reaction...Ch. 9 - Prob. 9.110QPCh. 9 - Compare the properties of an ionic material such...Ch. 9 - Prob. 9.112QPCh. 9 - Explain the decomposition of nitroglycerin in...Ch. 9 - How did the Swedish chemist Alfred Nobel manage to...Ch. 9 - What property of a chemical bond gives rise to the...Ch. 9 - Prob. 9.116QPCh. 9 - Prob. 9.117QPCh. 9 - Calculate the lattice energy of potassium...Ch. 9 - Prob. 9.119QPCh. 9 - Prob. 9.120QPCh. 9 - Prob. 9.121QPCh. 9 - An ion M2+ has the configuration [Ar]3d2, and an...Ch. 9 - Prob. 9.123QPCh. 9 - Prob. 9.124QPCh. 9 - Prob. 9.125QPCh. 9 - Prob. 9.126QPCh. 9 - Which of the following molecules contains only...Ch. 9 - Prob. 9.128QPCh. 9 - Two fourth-period atoms, one of a transition...Ch. 9 - Prob. 9.130QPCh. 9 - Draw resonance formulas of the phosphoric acid...Ch. 9 - Prob. 9.132QPCh. 9 - Prob. 9.133QPCh. 9 - Prob. 9.134QPCh. 9 - Prob. 9.135QPCh. 9 - Prob. 9.136QPCh. 9 - Phosphorous acid. H3PO3, has the structure...Ch. 9 - Hypophosphorous acid, H3PO2, has the structure...Ch. 9 - An ionic compound has the following composition...Ch. 9 - An ionic compound has the following composition...Ch. 9 - A gaseous compound has the following composition...Ch. 9 - A liquid compound used in dry cleaning contains...Ch. 9 - A compound of tin and chlorine is a colorless...Ch. 9 - Prob. 9.144QPCh. 9 - Calculate the enthalpy of reaction for...Ch. 9 - Prob. 9.146QPCh. 9 - Prob. 9.147QPCh. 9 - Prob. 9.148QPCh. 9 - Prob. 9.149QPCh. 9 - Prob. 9.150QP
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