Chemistry & Chemical Reactivity
9th Edition
ISBN: 9781133949640
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Chapter 9, Problem 67SCQ
Borax has the molecular formula Na2B4O5(OH)4. The structure of the anion in this compound is shown below. What is the electron pair geometry and molecular geometry surrounding each of the boron atoms in this anion? What hybridization can be assigned to each of the boron atoms? What is the formal charge of each boron atom?
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Chapter 9 Solutions
Chemistry & Chemical Reactivity
Ch. 9.2 - Use valence bond theory to describe the bonding in...Ch. 9.2 - Identify the hybridization of each underlined atom...Ch. 9.2 - Use valence bond theory to describe the bonding in...Ch. 9.2 - What is the hybridization of the S atom (the...Ch. 9.2 - 2. Which of the following is incorrect?
The...Ch. 9.2 - Prob. 3RCCh. 9.2 - Prob. 4RCCh. 9.3 - What is the electron configuration of the H2+ ion?...Ch. 9.3 - Could the anion Li2 exist? What is the ions bond...Ch. 9.3 - The cations O2+ and N2+ are formed when molecules...
Ch. 9.3 - What is the NO bond order in nitrogen monoxide,...Ch. 9.3 - Prob. 2RCCh. 9.3 - Prob. 3RCCh. 9.3 - 4. Among the known dioxygen species (O2+, O2, O2−...Ch. 9.3 - What is the empirical formula of Tynan purple?Ch. 9.3 - Butter yellow absorbs light with a wavelength of...Ch. 9.3 - Prob. 3CSCh. 9.A - Photoelectron spectroscopy is s1milar to the...Ch. 9.A - What is the energy of a photon with a wavelength...Ch. 9.A - Using the accompanying figure, state which...Ch. 9.A - The kinetic energy of an electron ejected from the...Ch. 9.A - The N2+ ions that are formed when electrons with...Ch. 9 - Draw the Lewis structure for chloroform, CHCl3....Ch. 9 - Draw the Lewis structure for NF3. What are its...Ch. 9 - Draw the Lewis structure for hydroxylamine, H2NOH....Ch. 9 - Draw the Lewis structure for 1,...Ch. 9 - Draw the Lewis structure for carbonyl fluoride,...Ch. 9 - Draw the Lewis structure for acetamide, CH3CONH2....Ch. 9 - Specify the electron-pair and molecular geometry...Ch. 9 - Specify the electron-pair and molecular geometry...Ch. 9 - Prob. 9PSCh. 9 - What is the hybrid orbital set used by each of the...Ch. 9 - Draw the Lewis structures of the acid HPO2F2 and...Ch. 9 - Draw the Lewis structures of the arid HSO3F and...Ch. 9 - What is the hybridization of the carbon atom in...Ch. 9 - What is the hybridization of the carbon atoms in...Ch. 9 - What is the electron-pair and molecular geometry...Ch. 9 - Prob. 17PSCh. 9 - For each compound below, decide whether cis and...Ch. 9 - Molecular Orbital Theory (See Examples 9.49.6.)...Ch. 9 - Give the electron configurations for the ions Li2+...Ch. 9 - Platinum hexafluoride is an extremely strong...Ch. 9 - When potassium and oxygen react, one of the...Ch. 9 - Among the following, which has the shortest bond...Ch. 9 - Consider the following list of small molecules and...Ch. 9 - Prob. 27PSCh. 9 - The nitrosyl ion. NO+, has an interesting...Ch. 9 - These questions are not designated as to type or...Ch. 9 - What is the OSO angle and the hybrid orbital set...Ch. 9 - Sketch the resonance structures for the nitrite...Ch. 9 - Sketch the resonance structures for the nitrate...Ch. 9 - Sketch the resonance structures for the N2O...Ch. 9 - Compare the structure and bonding in CO2 and CO32...Ch. 9 - Numerous molecules are detected in deep space....Ch. 9 - Acrolein, a component of photochemical smog, has a...Ch. 9 - The organic compound below is a member of a class...Ch. 9 - The compound sketched below is acetylsalicylic...Ch. 9 - Phosphoserine is a less-common amino acid. (a)...Ch. 9 - Lactic acid is a natural compound found in sour...Ch. 9 - Cinnamaldehyde ocaus naturally in cinnamon oil....Ch. 9 - The ion Si2 was reported in a laboratory...Ch. 9 - The simple valence bond picture of O2 does not...Ch. 9 - Nitrogen, N2, can ionize to form N2+ or add an...Ch. 9 - Which of the homonuclear, diatomic molecules of...Ch. 9 - Which of the following molecules or ions are...Ch. 9 - Prob. 47GQCh. 9 - The structure of amphetamine, a stimulant, is...Ch. 9 - Menthol is used in soaps, perfumes, and foods. It...Ch. 9 - Prob. 50GQCh. 9 - Suppose you carry out the following reaction of...Ch. 9 - Ethylene oxide is an intermediate in the...Ch. 9 - The sulfamate ion, H2NSO3, can be thought of as...Ch. 9 - The compound whose structure is shown here is...Ch. 9 - Prob. 55ILCh. 9 - Carbon dioxide (CO2), dinitrogen monoxide (N2O),...Ch. 9 - Draw the two resonance structures that describe...Ch. 9 - Draw a Lewis structure for diimide, HNNH. Then,...Ch. 9 - Prob. 59SCQCh. 9 - Consider the three fluorides BF4, SiF4, and SF4....Ch. 9 - When two amino acids react with each other, they...Ch. 9 - What is the connection between bond order, bond...Ch. 9 - When is it desirable to use MO theory rather than...Ch. 9 - Show how valence bond theory and molecular orbital...Ch. 9 - Three of the four molecular orbitals for...Ch. 9 - Lets look more closely at the process of...Ch. 9 - Borax has the molecular formula Na2B4O5(OH)4. The...Ch. 9 - A model of the organic compound allene is shown...Ch. 9 - Prob. 69SCQCh. 9 - Prob. 70SCQCh. 9 - Bromine forms a number of oxides of varying...Ch. 9 - Prob. 72SCQCh. 9 - Urea reacts with malonic acid to produce...
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- The complex anion in Ba₂[Cr(CN)6] is a tetragonally distorted octahedral complex (Dan). Baz[Cr(CN)6] is paramagnetic at room temperature with S = 1. Assume that the complex is a low-spin complex. a) Identify if the [Cr(CN)6] anionic complex has 4 long and 2 short bonds (left side of figure) or if the complex has 4 short and 2 long bonds (right side of figure) with respect to Oh symmetry. Use crystal field theory to answer this question. Explain/rationalize your decision. Can the provided information decide on the order of orbital energies? Dah Tetragonal Distortion ய Dab z-compression z-elongation x and y elongation O symmetry x and y compression E eg d² dx²-y² t2g dxy dxz dyz Question 4 a) continued: Provide your explanations in the space below. b) At low temperatures Ba₂[Cr(CN)6] is ferromagnetically ordered with a phase transition to a paramagnetic phase at Tc = 150K. Sketch the magnetic susceptibility vs. temperature in the diagram below. Indicate Tc as well as the paramagnetic and…arrow_forwarda) Draw the octahedral mer-[FeCl3(CN)3] complex and determine its point group. Use proper wedges and dashes in order to illustrate 3 dimensional details. Use the point group to determine if the complex has a resulting net dipole moment and describe its allowed direction with respect to its symmetry elements (if applicable). ード M 4- b) Substitute one chlorido ligand in mer-[FeCl3(CN)3] 4 with one fluorido ligand. Determine all possible isomers and their corresponding point groups. Use the point groups to determine if the complexes have resulting net dipole moments and describe their allowed direction with respect to its symmetry elements (if applicable). The number of complex sketches below is not necessarily indicative of the number of isomers. 4- 4- ☐☐☐ c) Substitute two chlorido ligands in mer-[FeCl3 (CN)3] 4 with two fluorido ligands. Determine all possible isomers and their corresponding point groups.. Use the point groups to determine if the complexes have resulting net dipole…arrow_forwardShow work. don't give Ai generated solutionarrow_forward
- Differentiate electron spin and electron spin moment.arrow_forwardDifferentiate between nuclear spin and electron spin.arrow_forwardDraw the trigonal prismatic MH6 molecular compound, where M is a 3d transition metal. a) Draw the trigonal prismatic MH6 molecular compound and determine its point group. b) i. What is the symmetry species for the 4s orbital on the central metal? ii. What is the symmetry species for the 3dx²-y² orbital on the central metal? Note: The z-axis is the principal axis. iii. Suggest a crystal field energy diagram for a d² electron configuration in a trigonal prismatic coordination environment. Label the metal d-orbital with their corresponding symmetry species label. Use the appropriate character table in the resource section.arrow_forward
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