1 Matter And Measurements 2 Atoms, Molecules, And Ions 3 Mass Relations In Chemistry; Stoichiometry 4 Reactions In Aqueous Solution 5 Gases 6 Electronic Structure And The Periodic Table 7 Covalent Bonding 8 Thermochemistry 9 Liquids And Solids 10 Solutions 11 Rate Of Reaction 12 Gaseous Chemical Equilibrium 13 Acids And Bases 14 Equilibria In Acid-base Solutions 15 Complex Ion And Precipitation Equilibria 16 Spontaneity Of Reaction 17 Electrochemistry 18 Nuclear Reactions 19 Complex Ions 20 Chemistry Of The Metals 21 Chemistry Of The Nonmetals 22 Organic Chemistry 23 Organic Polymers, Natural And Synthetic expand_more
Chapter Questions expand_more
Problem 1QAP Problem 2QAP Problem 3QAP: The vapor pressure of I2(s) at 30C is 0.466 mm Hg. (a) How many milligrams of iodine will sublime... Problem 4QAP Problem 5QAP: Trichloroethane, C2H3Cl3 is used as a degreaser (solvent for waxes and oils). Its density is 1.435... Problem 6QAP: p-Dichlorobenzene, C6H4Cl2, can be one of the ingredients in mothballs. Its vapor pressure at 20C is... Problem 7QAP Problem 8QAP: Dichloromethane, CH2Cl2,is widely used as a degreaser and paint stripper. Its vapor pressure is... Problem 9QAP Problem 10QAP Problem 11QAP: At a resort in Sante Fe, New Mexico, the barometric pressure is 625 mm Hg. Water boils in an open... Problem 12QAP Problem 13QAP Problem 14QAP: Consider the following data for the vapor pressure of diethyl ether, a widely used anesthetic in the... Problem 15QAP: Referring to Figure 9.7, state what phase(s) is/are present at (a) 1 atm, 100C. (b) 0.5 atm,... Problem 16QAP: Referring to Figure 9.7, state what phase(s) is (are) present at (a) 1 atm, 10C. (b) 3 mm Hg, 20C.... Problem 17QAP Problem 18QAP: Consider the phase diagram of the compound in Problem 17 to answer the following questions. (a) What... Problem 19QAP Problem 20QAP Problem 21QAP: Given the following data about xenon,... Problem 22QAP: Given the following data about CO2: • triple point: -57C, 5.11 atm • critical point: 31C, 73 atm... Problem 23QAP: A pure substance X has the following properties: Mp=90C, increasing slightly as pressure increases;... Problem 24QAP Problem 25QAP Problem 26QAP: Arrange the following compounds in order of increasing boiling point. (a) Ar (b) He (c) Ne (d) Xe Problem 27QAP: Which of the following would you expect to show dispersion forces? dipole forces? (a) GeBr4(b) C2H2... Problem 28QAP: Which of the following compounds would you expect to show dispersion forces? Dipole forces? (a)... Problem 29QAP Problem 30QAP Problem 31QAP: Explain in terms of forces between structural units why (a) HI has a higher boiling point than HBr.... Problem 32QAP Problem 33QAP Problem 34QAP: In which of the following processes is it necessary to break covalent bonds as opposed to simply... Problem 35QAP: For each of the following pairs, choose the member with the lower boiling point. Explain your reason... Problem 36QAP: Follow the directions for Question 35 for the following substances. (a) LiCl or CCl4 (b) CH3OH or... Problem 37QAP: What are the strongest attractive forces that must be overcome to (a) boil silicon hydride, SiH4?... Problem 38QAP: What are the strongest attractive forces that must be overcome to (a) melt ice? (b) sublime bromine?... Problem 39QAP Problem 40QAP Problem 41QAP: Of the four general types of solids, which one(s) (a) are generally low-boiling? (b) are ductile and... Problem 42QAP: Of the four general types of solids, which one(s) (a) are generally insoluble in water? (b) have... Problem 43QAP Problem 44QAP Problem 45QAP: Give the formula of a solid containing Si that is (a) molecular (b) ionic (c) network covalent Problem 46QAP Problem 47QAP Problem 48QAP: Describe the structural units in (a) C (graphite) (b) SiC (c) FeCl2 (d) C2H2 Problem 49QAP: Molybdenum has an atomic radius of 0.145 nm. The volume of its cubic unit cell is 0.0375 nm3. What... Problem 50QAP: Nickel has an atomic radius of 0.162 nm. The edge of its cubic unit cell is 0.458 nm. What is the... Problem 51QAP: Lead (atomicradius=0.181nm) crystallizes with a face-centered cubic unit cell. What is the length of... Problem 52QAP: Iridium crystallizes in a face-centered unit cell. The side of the cell is 0.3833 nm. Calculate the... Problem 53QAP: In the LiCl structure shown in Figure 9.21, the chloride ions form a face-centered cubic unit cell... Problem 54QAP: Potassium iodide has a unit cell similar to that of sodium chloride (Figure 9.21). The ionic radii... Problem 55QAP Problem 56QAP: Consider the CsCl cell (Figure 9.21). The ionic radii of Cs+ and Cl- are 0.169 and 0.181 nm,... Problem 57QAP: Consider the sodium chloride unit cell shown in Figure 9.21. Looking only at the front face (five... Problem 58QAP: Consider the CsCl unit shown in Figure 9.21. How many Cs+ ions are there per unit cell? How many Cl-... Problem 59QAP: A 1.25-L clean and dry flask is sealed. The air in the flask is at 27C and 38% relative humidity.... Problem 60QAP: Aluminum metal crystallizes with a face-centered cubic unit cell. The volume of the cell is 0.0662... Problem 61QAP: Consider a sealed flask with a movable piston that contains 5.25 L of O2 saturated with water vapor... Problem 62QAP Problem 63QAP Problem 64QAP Problem 65QAP: Chloroform, CHCl3, has a normal boiling point of 61C. Its vapor pressure at 43C is 0.526 atm. What... Problem 66QAP Problem 67QAP Problem 68QAP: In the blanks provided, answer the questions below, using LT (for is less than), GT (for is greater... Problem 69QAP: Answer the questions below, by filling in the blanks with LT for is less than, GT for is greater... Problem 70QAP Problem 71QAP Problem 72QAP: What is the difference between (a) a covalent bond and an ionic bond? (b) boiling point and critical... Problem 73QAP: Four shiny solids are labeled A, B, C, and D. Given the following information about the solids,... Problem 74QAP Problem 75QAP: The following data are given for CC14:... Problem 76QAP: Iron crystallizes in a body-centered unit cell. Its atomic radius is 0.124 nm. Its density is 7.86... Problem 77QAP Problem 78QAP: Trichloroethane, C2H3Cl3, is the active ingredient in aerosols that claim to stain-proof men's ties.... Problem 79QAP Problem 80QAP Problem 81QAP format_list_bulleted