Chemistry: Principles and Reactions
8th Edition
ISBN: 9781305079373
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
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Textbook Question
Chapter 9, Problem 37QAP
What are the strongest attractive forces that must be overcome to
(a) boil silicon hydride, SiH4?
(b) vaporize calcium chloride?
(c) dissolve Cl2 in carbon tetrachloride, CCl4?
(d) melt iodine?
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The structure of the bicarbonate (hydrogen carbonate) ion, HCO3-, HCO3
best described as a hybrid of several contributing resonance forms, two of which
are shown here.
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Bicarbonate is crucial for the control of body pH (for example, blood pH:
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source of CO2 CO₂ 2 gas, which gives bread and pastry their fluffy
constituency.
(i) Draw at least one additional resonance form.
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(ii) Using curved "electron-pushing" arrows, show how these Lewis structures may
be interconverted by movement of electron pairs. (iii) Determine which form or
forms will be the major contributor(s) to the real structure of bicarbonate,
explaining your answer on the basis of the criteria in Section 1-5.
Chapter 9 Solutions
Chemistry: Principles and Reactions
Ch. 9 - Prob. 1QAPCh. 9 - Prob. 2QAPCh. 9 - The vapor pressure of I2(s) at 30C is 0.466 mm Hg....Ch. 9 - Prob. 4QAPCh. 9 - Trichloroethane, C2H3Cl3 is used as a degreaser...Ch. 9 - p-Dichlorobenzene, C6H4Cl2, can be one of the...Ch. 9 - Prob. 7QAPCh. 9 - Dichloromethane, CH2Cl2,is widely used as a...Ch. 9 - Prob. 9QAPCh. 9 - Prob. 10QAP
Ch. 9 - At a resort in Sante Fe, New Mexico, the...Ch. 9 - Prob. 12QAPCh. 9 - Prob. 13QAPCh. 9 - Consider the following data for the vapor pressure...Ch. 9 - Referring to Figure 9.7, state what phase(s)...Ch. 9 - Referring to Figure 9.7, state what phase(s) is...Ch. 9 - Prob. 17QAPCh. 9 - Consider the phase diagram of the compound in...Ch. 9 - Prob. 19QAPCh. 9 - Prob. 20QAPCh. 9 - Given the following data about xenon,...Ch. 9 - Given the following data about CO2: • triple...Ch. 9 - A pure substance X has the following properties:...Ch. 9 - Prob. 24QAPCh. 9 - Prob. 25QAPCh. 9 - Arrange the following compounds in order of...Ch. 9 - Which of the following would you expect to show...Ch. 9 - Which of the following compounds would you expect...Ch. 9 - Prob. 29QAPCh. 9 - Prob. 30QAPCh. 9 - Explain in terms of forces between structural...Ch. 9 - Prob. 32QAPCh. 9 - Prob. 33QAPCh. 9 - In which of the following processes is it...Ch. 9 - For each of the following pairs, choose the member...Ch. 9 - Follow the directions for Question 35 for the...Ch. 9 - What are the strongest attractive forces that must...Ch. 9 - What are the strongest attractive forces that must...Ch. 9 - Prob. 39QAPCh. 9 - Prob. 40QAPCh. 9 - Of the four general types of solids, which one(s)...Ch. 9 - Of the four general types of solids, which one(s)...Ch. 9 - Prob. 43QAPCh. 9 - Prob. 44QAPCh. 9 - Give the formula of a solid containing Si that is...Ch. 9 - Prob. 46QAPCh. 9 - Prob. 47QAPCh. 9 - Describe the structural units in (a) C (graphite)...Ch. 9 - Molybdenum has an atomic radius of 0.145 nm. The...Ch. 9 - Nickel has an atomic radius of 0.162 nm. The edge...Ch. 9 - Lead (atomicradius=0.181nm) crystallizes with a...Ch. 9 - Iridium crystallizes in a face-centered unit cell....Ch. 9 - In the LiCl structure shown in Figure 9.21, the...Ch. 9 - Potassium iodide has a unit cell similar to that...Ch. 9 - Prob. 55QAPCh. 9 - Consider the CsCl cell (Figure 9.21). The ionic...Ch. 9 - Consider the sodium chloride unit cell shown in...Ch. 9 - Consider the CsCl unit shown in Figure 9.21. How...Ch. 9 - A 1.25-L clean and dry flask is sealed. The air in...Ch. 9 - Aluminum metal crystallizes with a face-centered...Ch. 9 - Consider a sealed flask with a movable piston that...Ch. 9 - Prob. 62QAPCh. 9 - Prob. 63QAPCh. 9 - Prob. 64QAPCh. 9 - Chloroform, CHCl3, has a normal boiling point of...Ch. 9 - Prob. 66QAPCh. 9 - Prob. 67QAPCh. 9 - In the blanks provided, answer the questions...Ch. 9 - Answer the questions below, by filling in the...Ch. 9 - Prob. 70QAPCh. 9 - Prob. 71QAPCh. 9 - What is the difference between (a) a covalent bond...Ch. 9 - Four shiny solids are labeled A, B, C, and D....Ch. 9 - Prob. 74QAPCh. 9 - The following data are given for CC14:...Ch. 9 - Iron crystallizes in a body-centered unit cell....Ch. 9 - Prob. 77QAPCh. 9 - Trichloroethane, C2H3Cl3, is the active ingredient...Ch. 9 - Prob. 79QAPCh. 9 - Prob. 80QAPCh. 9 - Prob. 81QAP
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