Chemistry: Principles and Reactions
8th Edition
ISBN: 9781305079373
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
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Question
Chapter 9, Problem 10QAP
Interpretation Introduction
Interpretation:
The temperature at which water boils in Glacier national park is to be calculated.
Concept introduction:
Clausius-Clapeyron equation is an expression that relates the vapor pressure of a liquid at two different temperatures with the enthalpy of vaporization of the liquid. The expression is given as:
P1 = vapor pressure at temperature T1
P2 = vapor pressure at temperature T2
R = Ideal gas constant = 8.314 J/Kmol
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f) The unusual molecule [2.2.2] propellane is pictured.
1) Given the bond length and bond angles in the image, what hybridization scheme
best describes the carbons marked by the askerisks?
2) What types of orbitals are used in the bond between the two carbons marked by
the askerisks?
3) How does this bond compare to an ordinary carbon-carbon bond (which is usually
1.54 Å long)?
CH2 1.60Å
H₂C *
H₂C
CH2
C
H2C
*
C
Of
H₂
120°
e) Determine the hybridization and geometry around the indicated carbon atoms.
H3C
CH3
B
HC
CH2
A
C
C
C
CH3
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Chapter 9 Solutions
Chemistry: Principles and Reactions
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