Introduction to Chemistry, Special Edition
6th Edition
ISBN: 9781337035934
Author: Cracolice/Peters
Publisher: Cengage Learning
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Chapter 9, Problem 11PE
Interpretation Introduction
Interpretation:
The ionic equation for the reaction, when solutions of nickel
Concept Introduction:
An ion-combination reaction is a reaction in which cation from one reactant combines with the anion from another reactant and form a particular kind of product. The product is an insoluble ionic compound that settles at the bottom of mixed solution.
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You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you
manipulated and exploited the acid-base chemistry of one or more of the compounds in your
mixture to facilitate their separation into different phases. The key to understanding how liquid-
liquid extractions work is by knowing which layer a compound is in, and in what protonation state.
The following liquid-liquid extraction is different from the one you performed in Experiment
4, but it uses the same type of logic. Your task is to show how to separate apart Compound
A and Compound B.
. Complete the following flowchart of a liquid-liquid extraction. Handwritten work is
encouraged.
•
Draw by hand (neatly) only the appropriate organic compound(s) in the boxes.
.
Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4
and 5.
•
Box 7a requires the solvent (name is fine).
•
Box 7b requires one inorganic compound.
• You can neatly complete this assignment by hand and…
b) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;'
The compound has the ff electronic transitions: 0%o* and no a*
1H NMR Spectrum
(CDCl3, 400 MHz)
3.5
3.0
2.5
2.0
1.5
1.0
0.5 ppm
13C{H} NMR Spectrum
(CDCl3, 100 MHz)
Solvent
80
70
60
50
40
30
20
10
0 ppm
ppm
¹H-13C me-HSQC Spectrum
ppm
(CDCl3, 400 MHz)
5
¹H-¹H COSY Spectrum
(CDCl3, 400 MHz)
0.5
10
3.5
3.0
2.5
2.0
1.5 1.0
10
15
20
20
25
30
30
-35
-1.0
1.5
-2.0
-2.5
3.0
-3.5
0.5
ppm
3.5
3.0
2.5
2.0
1.5
1.0
0.5
ppm
Show work with explanation. don't give Ai generated solution
Chapter 9 Solutions
Introduction to Chemistry, Special Edition
Ch. 9 - Prob. 1ECh. 9 - Prob. 2ECh. 9 - Prob. 3ECh. 9 - Prob. 4ECh. 9 - Questions 5 through 12: Write the major species in...Ch. 9 - Prob. 6ECh. 9 - Questions 5 through 12: Write the major species in...Ch. 9 - Prob. 8ECh. 9 - Questions 5 through 12: Write the major species in...Ch. 9 - Question 5 through 12: Write the major species in...
Ch. 9 - Question 5 through 12: Write the major species in...Ch. 9 - Question 5 through 12: Write the major species in...Ch. 9 - Questions 13 through 18: For each reaction...Ch. 9 - Questions 13 through 18: For each reaction...Ch. 9 - Prob. 15ECh. 9 - Prob. 16ECh. 9 - Prob. 17ECh. 9 - Questions 13 through 18: For each reaction...Ch. 9 - Questions 19 through 24: For each pair of...Ch. 9 - Prob. 20ECh. 9 - Questions 19 through 24: For each pair of...Ch. 9 - Questions 19 through 24: For each pair of...Ch. 9 - Questions 19 through 24: For each pair of...Ch. 9 - Prob. 24ECh. 9 - Questions 25 through 28: Write the equation for...Ch. 9 - Prob. 26ECh. 9 - Prob. 27ECh. 9 - Prob. 28ECh. 9 - Questions 29 through 36: For each pair of...Ch. 9 - Prob. 30ECh. 9 - Questions 29 through 36: For each pair of...Ch. 9 - Prob. 32ECh. 9 - Questions 29 through36: For each pair of reactants...Ch. 9 - Questions 29 through36: For each pair of reactants...Ch. 9 - Questions 29 through36: For each pair of reactants...Ch. 9 - Questions 29 through 36: For each pair of...Ch. 9 - Write the net ionic equations for the...Ch. 9 - Prob. 38ECh. 9 - Questions 39 through 44: For each pair of...Ch. 9 - Prob. 40ECh. 9 - Questions 39 through 44: For each pair of...Ch. 9 - Prob. 42ECh. 9 - Questions 39 through 44: For each pair of...Ch. 9 - Prob. 44ECh. 9 - Questions 45 through 48: For each pair of...Ch. 9 - Prob. 46ECh. 9 - Questions 45 through 48: For each pair of...Ch. 9 - Prob. 48ECh. 9 - Prob. 49ECh. 9 - Prob. 50ECh. 9 - Prob. 51ECh. 9 - The remaining questions include all types of...Ch. 9 - Prob. 53ECh. 9 - Prob. 54ECh. 9 - Prob. 55ECh. 9 - Prob. 56ECh. 9 - Prob. 57ECh. 9 - Prob. 58ECh. 9 - Prob. 59ECh. 9 - The remaining questions include all types of...Ch. 9 - Prob. 61ECh. 9 - Prob. 62ECh. 9 - Prob. 63ECh. 9 - Prob. 64ECh. 9 - Prob. 65ECh. 9 - Prob. 66ECh. 9 - Prob. 67ECh. 9 - Prob. 68ECh. 9 - Prob. 69ECh. 9 - The remaining questions include all types of...Ch. 9 - Prob. 71ECh. 9 - Prob. 72ECh. 9 - The remaining questions include all types of...Ch. 9 - Prob. 74ECh. 9 - The remaining questions include all types of...Ch. 9 - Prob. 76ECh. 9 - Prob. 77ECh. 9 - Prob. 78ECh. 9 - Prob. 79ECh. 9 - Prob. 80ECh. 9 - Prob. 9.1TCCh. 9 - Write a brief description of the relationships...Ch. 9 - Write a brief description of the relationships...Ch. 9 - Prob. 3CLECh. 9 - Prob. 1PECh. 9 - Prob. 2PECh. 9 - Prob. 3PECh. 9 - Aluminum nitrate and sodium hydroxide solutions...Ch. 9 - A piece of solid zinc is dropped into hydrochloric...Ch. 9 - Chlorine gas is bubbled through a sodium bromide...Ch. 9 - Write the conventional, total ionic, and net ionic...Ch. 9 - Prob. 8PECh. 9 - Prob. 9PECh. 9 - Prob. 10PECh. 9 - Prob. 11PECh. 9 - Prob. 12PECh. 9 - Solutions of hydrobromic acid and barium hydroxide...Ch. 9 - Solutions of hydroiodic acid and sodium fluoride...Ch. 9 - Prob. 15PECh. 9 - Prob. 16PECh. 9 - A nitric acid solution is poured onto solid nickel...Ch. 9 - Prob. 18PECh. 9 - A skill you need for writing net ionic equations...Ch. 9 - Prob. 2ECECh. 9 - Prob. 3ECECh. 9 - Prob. 4ECECh. 9 - Prob. 5ECECh. 9 - Prob. 6ECECh. 9 - A skill you need for writing net ionic equations...Ch. 9 - A skill you need for writing net ionic equations...Ch. 9 - Prob. 9ECECh. 9 - Prob. 10ECECh. 9 - Prob. 11ECECh. 9 - A skill you need for writing net ionic equations...
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- Redraw the flowchartarrow_forwardredraw the flowchart with boxes and molecules written in themarrow_forwardPart I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400arrow_forward
- • Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peakarrow_forwardCould you redraw these and also explain how to solve them for me pleasarrow_forwardNonearrow_forward
- Draw the curved-arrow mechanism with the drawings of the molecules, not just abbreviations. -NO₂ Sn, HCl (aq) E D H (CH3CO)₂O -NH2 CH3arrow_forwardWhat is/are the product(s) of the following reaction? Select all that apply. * HI A B C OD OH A B OH D Carrow_forwardIn the image, the light blue sphere represents a mole of hydrogen atoms, the purple or teal spheres represent a mole of a conjugate base. A light blue sphere by itself is H+. Assuming there is 2.00 L of solution, answer the following: The Ka of the left & right solution is? The pH of the left & right solution is? The acid on the left & right is what kind of acid?arrow_forward
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