Whether the reaction that occurs when aluminum shavings are dropped into a solution of copper ( II ) nitrate is an example of redox reaction or precipitation reaction is to be predicted based on the activity series and solubility guidelines. The net ionic equation is to be stated. Concept introduction: Metals are tabulated in decreasing order of their reducing power or increasing order of their oxidizing power. The table is termed as activity series. Any element in the activity series will replace the ions of the elements from a solution written below it. If the product formed is an insoluble compound, the reaction is termed as precipitation reaction. If the elements in the reactants undergo oxidation and reduction, the reaction is termed as redox reaction.

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Using reaction free energy to predict equilibrium composition Consider the following equilibrium: N2O4 (g) 2NO2 (g) AG⁰ = 5.4 kJ Now suppose a reaction vessel is filled with 1.68 atm of dinitrogen tetroxide (N204) at 148. °C. Answer the following questions about this system: rise Under these conditions, will the pressure of N2O4 tend to rise or fall? x10 fall Is it possible to reverse this tendency by adding NO2? In other words, if you said the pressure of N2O4 will tend to rise, can that be changed to a tendency to fall by adding NO2? Similarly, if you said the pressure of N2O4 will tend to fall, can that be changed to a tendency to rise by adding NO2? If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO 2 needed to reverse it. Round your answer to 2 significant digits. yes no 0.42 atm ☑ 5 0/5 ? مله Ar

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Chapter 9, Problem 77E

Interpretation Introduction

Interpretation:

Whether the reaction that occurs when aluminum shavings are dropped into a solution of copper (II) nitrate is an example of redox reaction or precipitation reaction is to be predicted based on the activity series and solubility guidelines. The net ionic equation is to be stated.

Concept introduction:

Metals are tabulated in decreasing order of their reducing power or increasing order of their oxidizing power. The table is termed as activity series. Any element in the activity series will replace the ions of the elements from a solution written below it. If the product formed is an insoluble compound, the reaction is termed as precipitation reaction. If the elements in the reactants undergo oxidation and reduction, the reaction is termed as redox reaction.

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Using reaction free energy to predict equilibrium composition Consider the following equilibrium: N2O4 (g) 2NO2 (g) AG⁰ = 5.4 kJ Now suppose a reaction vessel is filled with 1.68 atm of dinitrogen tetroxide (N204) at 148. °C. Answer the following questions about this system: rise Under these conditions, will the pressure of N2O4 tend to rise or fall? x10 fall Is it possible to reverse this tendency by adding NO2? In other words, if you said the pressure of N2O4 will tend to rise, can that be changed to a tendency to fall by adding NO2? Similarly, if you said the pressure of N2O4 will tend to fall, can that be changed to a tendency to rise by adding NO2? If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO 2 needed to reverse it. Round your answer to 2 significant digits. yes no 0.42 atm ☑ 5 0/5 ? مله Ar

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