Given reaction of 2-metylpropene with CH3OH in the presence of H2SO4 catalyst yields methyl tert- butylether, CH3OC(CH3)3, by a mechanism analogous to that of acid catalyzed alkene hydration. The mechanism for each step of the reaction is to be given using curved arrows. Concept introduction: In the presence of strong acids the double bond in alkene is protonated by the nucleophilic attack of the Ï€ electrons in double bond on the hydrogen of the acid. The carbonium ion obtained during the process is then attacked by the unshared pair of the electrons on oxygen in methanol to yield an intermediate which loses a proton to give the final ether as product. To give: The mechanism for each step of the reaction in which 2-metylpropene reacts with CH3OH in the presence of H2SO4 catalyst to yield methyl tert- butylether, CH3OC(CH3)3.

Question

Which of the given reactions would form meso product? H₂O, H2SO4 III m CH3 CH₂ONa CH3OH || H₂O, H2SO4 CH3 1. LiAlH4, THF 2. H₂O CH3 IV

Answer 1

Question

Chapter 8.SE, Problem 33MP

Interpretation Introduction

Interpretation:

Given reaction of 2-metylpropene with CH3OH in the presence of H2SO4 catalyst yields methyl tert-butylether, CH3OC(CH3)3, by a mechanism analogous to that of acid catalyzed alkene hydration. The mechanism for each step of the reaction is to be given using curved arrows.

Concept introduction:

In the presence of strong acids the double bond in alkene is protonated by the nucleophilic attack of the Ï€ electrons in double bond on the hydrogen of the acid. The carbonium ion obtained during the process is then attacked by the unshared pair of the electrons on oxygen in methanol to yield an intermediate which loses a proton to give the final ether as product.

To give:

The mechanism for each step of the reaction in which 2-metylpropene reacts with CH3OH in the presence of H2SO4 catalyst to yield methyl tert-butylether, CH3OC(CH3)3.

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Which of the given reactions would form meso product? H₂O, H2SO4 III m CH3 CH₂ONa CH3OH || H₂O, H2SO4 CH3 1. LiAlH4, THF 2. H₂O CH3 IV

What is the major product of the following reaction? O IV III HCI D = III ა IV

The reaction of what nucleophile and substrate is represented by the following transition state? CH3 CH3O -Br อ δ CH3 Methanol with 2-bromopropane Methanol with 1-bromopropane Methoxide with 1-bromopropane Methoxide with 2-bromopropane

Answer 2

Question

Chapter 8.SE, Problem 33MP

Interpretation Introduction

Interpretation:

Given reaction of 2-metylpropene with CH3OH in the presence of H2SO4 catalyst yields methyl tert-butylether, CH3OC(CH3)3, by a mechanism analogous to that of acid catalyzed alkene hydration. The mechanism for each step of the reaction is to be given using curved arrows.

Concept introduction:

In the presence of strong acids the double bond in alkene is protonated by the nucleophilic attack of the Ï€ electrons in double bond on the hydrogen of the acid. The carbonium ion obtained during the process is then attacked by the unshared pair of the electrons on oxygen in methanol to yield an intermediate which loses a proton to give the final ether as product.

To give:

The mechanism for each step of the reaction in which 2-metylpropene reacts with CH3OH in the presence of H2SO4 catalyst to yield methyl tert-butylether, CH3OC(CH3)3.

Expert Solution & Answer

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Answer 3

Question

Chapter 8.SE, Problem 33MP

Interpretation Introduction

Interpretation:

Given reaction of 2-metylpropene with CH3OH in the presence of H2SO4 catalyst yields methyl tert-butylether, CH3OC(CH3)3, by a mechanism analogous to that of acid catalyzed alkene hydration. The mechanism for each step of the reaction is to be given using curved arrows.

Concept introduction:

In the presence of strong acids the double bond in alkene is protonated by the nucleophilic attack of the Ï€ electrons in double bond on the hydrogen of the acid. The carbonium ion obtained during the process is then attacked by the unshared pair of the electrons on oxygen in methanol to yield an intermediate which loses a proton to give the final ether as product.

To give:

The mechanism for each step of the reaction in which 2-metylpropene reacts with CH3OH in the presence of H2SO4 catalyst to yield methyl tert-butylether, CH3OC(CH3)3.

Expert Solution & Answer

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Answer 4

Question

Chapter 8.SE, Problem 33MP

Interpretation Introduction

Interpretation:

Given reaction of 2-metylpropene with CH3OH in the presence of H2SO4 catalyst yields methyl tert-butylether, CH3OC(CH3)3, by a mechanism analogous to that of acid catalyzed alkene hydration. The mechanism for each step of the reaction is to be given using curved arrows.

Concept introduction:

In the presence of strong acids the double bond in alkene is protonated by the nucleophilic attack of the Ï€ electrons in double bond on the hydrogen of the acid. The carbonium ion obtained during the process is then attacked by the unshared pair of the electrons on oxygen in methanol to yield an intermediate which loses a proton to give the final ether as product.

To give:

The mechanism for each step of the reaction in which 2-metylpropene reacts with CH3OH in the presence of H2SO4 catalyst to yield methyl tert-butylether, CH3OC(CH3)3.

Expert Solution & Answer

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Answer 5

Chapter 8.SE, Problem 33MP

Interpretation Introduction

Interpretation:

Given reaction of 2-metylpropene with CH3OH in the presence of H2SO4 catalyst yields methyl tert-butylether, CH3OC(CH3)3, by a mechanism analogous to that of acid catalyzed alkene hydration. The mechanism for each step of the reaction is to be given using curved arrows.

Concept introduction:

In the presence of strong acids the double bond in alkene is protonated by the nucleophilic attack of the Ï€ electrons in double bond on the hydrogen of the acid. The carbonium ion obtained during the process is then attacked by the unshared pair of the electrons on oxygen in methanol to yield an intermediate which loses a proton to give the final ether as product.

To give:

The mechanism for each step of the reaction in which 2-metylpropene reacts with CH3OH in the presence of H2SO4 catalyst to yield methyl tert-butylether, CH3OC(CH3)3.

Answer 6

Chapter 8.SE, Problem 33MP

Interpretation Introduction

Interpretation:

Given reaction of 2-metylpropene with CH3OH in the presence of H2SO4 catalyst yields methyl tert-butylether, CH3OC(CH3)3, by a mechanism analogous to that of acid catalyzed alkene hydration. The mechanism for each step of the reaction is to be given using curved arrows.

Concept introduction:

In the presence of strong acids the double bond in alkene is protonated by the nucleophilic attack of the Ï€ electrons in double bond on the hydrogen of the acid. The carbonium ion obtained during the process is then attacked by the unshared pair of the electrons on oxygen in methanol to yield an intermediate which loses a proton to give the final ether as product.

To give:

The mechanism for each step of the reaction in which 2-metylpropene reacts with CH3OH in the presence of H2SO4 catalyst to yield methyl tert-butylether, CH3OC(CH3)3.

Answer 7

Chapter 8.SE, Problem 33MP

Interpretation Introduction

Interpretation:

Given reaction of 2-metylpropene with CH3OH in the presence of H2SO4 catalyst yields methyl tert-butylether, CH3OC(CH3)3, by a mechanism analogous to that of acid catalyzed alkene hydration. The mechanism for each step of the reaction is to be given using curved arrows.

Concept introduction:

In the presence of strong acids the double bond in alkene is protonated by the nucleophilic attack of the Ï€ electrons in double bond on the hydrogen of the acid. The carbonium ion obtained during the process is then attacked by the unshared pair of the electrons on oxygen in methanol to yield an intermediate which loses a proton to give the final ether as product.

To give:

The mechanism for each step of the reaction in which 2-metylpropene reacts with CH3OH in the presence of H2SO4 catalyst to yield methyl tert-butylether, CH3OC(CH3)3.

Answer 8

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Answer 19

Ch. 8.1 - Prob. 1P Ch. 8.1 - How many alkene products, including E,Z isomers,...Ch. 8.2 - Prob. 3P Ch. 8.2 - Addition of HCl to 1, 2-dimethylcyclohexene yields...Ch. 8.3 - Prob. 5P Ch. 8.3 - Prob. 6P Ch. 8.4 - Prob. 7P Ch. 8.4 - From what alkenes might the following alcohols...Ch. 8.5 - Prob. 9P Ch. 8.5 - What alkenes might be used to prepare the...

Solution Summary: The author explains how 2-metylpropene reacts with CH3OH in the presence of H2SO4 catalyst to yield methyl tert- buty

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