a) Interpretation: The product of the reaction shown if the reaction was conducted in DMSO with water is to be given. The complete mechanism of the reaction including appropriate regiochemistry and stereochemistry is also to be given. Concept introduction: The addition of halogens to alkenes in the presence of aqueous DMSO results in the anti addition of the halohydrin, HOX to the double bond. In the first step a cyclic halonium ion is formed by the attack of the double bond on the halogen. In the second step water attacks the halonium ion from the least shielded side, followed by the loss of a proton to give an anti addition product. The addition to unsymmetrical alkenes follows Markovnikov regiochemistry. The negative part (OH) adds to the doubly bonded carbon atom which has more number of substituents. To give: The product of the reaction shown if the reaction was conducted in DMSO with water and to give the complete mechanism of the reaction including appropriate regiochemistry and stereochemistry.

Question

Consider the structure of 1-bromo-2-fluoroethane. Part 1 of 2 Draw the Newman projection for the anti conformation of 1-bromo-2-fluoroethane, viewed down the C1-C2 bond. ✡ ぬ Part 2 of 2 H H F Br H H ☑ Draw the Newman projection for the gauche conformation of 1-bromo-2-fluoroethane, viewed down the C1-C2 bond. H F Br H H

Answer 1

Question

Chapter 8.SE, Problem 27MP

Interpretation Introduction

a)

Interpretation:

The product of the reaction shown if the reaction was conducted in DMSO with water is to be given. The complete mechanism of the reaction including appropriate regiochemistry and stereochemistry is also to be given.

Concept introduction:

The addition of halogens to alkenes in the presence of aqueous DMSO results in the anti addition of the halohydrin, HOX to the double bond. In the first step a cyclic halonium ion is formed by the attack of the double bond on the halogen. In the second step water attacks the halonium ion from the least shielded side, followed by the loss of a proton to give an anti addition product. The addition to unsymmetrical alkenes follows Markovnikov regiochemistry. The negative part (OH) adds to the doubly bonded carbon atom which has more number of substituents.

To give:

The product of the reaction shown if the reaction was conducted in DMSO with water and to give the complete mechanism of the reaction including appropriate regiochemistry and stereochemistry.

Interpretation Introduction

b)

Interpretation:

The product of the reaction shown if the reaction was conducted in DMSO with water is to be given. The complete mechanism of the reaction including appropriate regiochemistry and stereochemistry is also to be given.

Concept introduction:

The addition of halogens to alkenes in the presence of aqueous DMSO results in the anti addition of the halohydrin, HOX, to the double bond. In the first step a cyclic halonium ion is formed by the attack of the double bond on the halogen. In the second step water attacks the halonium ion from the least shielded side to give an anti addition product. The addition obeys Markovnikov orientation. The negative part (OH) adds to the doubly bonded carbon atom which has more number of substituents.

To give:

The product of the reaction shown if the reaction was conducted in DMSO with water and to give the complete mechanism of the reaction including appropriate regiochemistry and stereochemistry.

Interpretation Introduction

c)

Interpretation:

The product of the reaction shown if the reaction was conducted in DMSO with water is to be given. The complete mechanism of the reaction including appropriate regiochemistry and stereochemistry is also to be given.

Concept introduction:

The addition of halogens to alkenes in the presence of aqueous DMSO results in the anti addition of the halohydrin, HOX, to the double bond. In the first step a cyclic halonium ion is formed by the attack of the double bond on halogen. In the second step water attacks the halonium ion from the least shielded side to give an anti addition product. The addition obeys Markovnokov orientation. The negative part (OH) adds to the doubly bonded carbon atom which has more number of substituents.

To give:

The product of the reaction shown if the reaction was conducted in DMSO with water and to give the complete mechanism of the reaction including appropriate regiochemistry and stereochemistry.

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Consider the structure of 1-bromo-2-fluoroethane. Part 1 of 2 Draw the Newman projection for the anti conformation of 1-bromo-2-fluoroethane, viewed down the C1-C2 bond. ✡ ぬ Part 2 of 2 H H F Br H H ☑ Draw the Newman projection for the gauche conformation of 1-bromo-2-fluoroethane, viewed down the C1-C2 bond. H F Br H H

Please help me answer this question. I don't understand how or where the different reagents will attach and it's mostly due to the wedge bond because I haven't seen a problem like this before. Please provide a detailed explanation and a drawing showing how it can happen and what the final product will look like.

Which of the following compounds is the most acidic in the gas phase? Group of answer choices H2O SiH4 HBr H2S

Answer 2

Question

Chapter 8.SE, Problem 27MP

Interpretation Introduction

a)

Interpretation:

The product of the reaction shown if the reaction was conducted in DMSO with water is to be given. The complete mechanism of the reaction including appropriate regiochemistry and stereochemistry is also to be given.

Concept introduction:

The addition of halogens to alkenes in the presence of aqueous DMSO results in the anti addition of the halohydrin, HOX to the double bond. In the first step a cyclic halonium ion is formed by the attack of the double bond on the halogen. In the second step water attacks the halonium ion from the least shielded side, followed by the loss of a proton to give an anti addition product. The addition to unsymmetrical alkenes follows Markovnikov regiochemistry. The negative part (OH) adds to the doubly bonded carbon atom which has more number of substituents.

To give:

The product of the reaction shown if the reaction was conducted in DMSO with water and to give the complete mechanism of the reaction including appropriate regiochemistry and stereochemistry.

Interpretation Introduction

b)

Interpretation:

The product of the reaction shown if the reaction was conducted in DMSO with water is to be given. The complete mechanism of the reaction including appropriate regiochemistry and stereochemistry is also to be given.

Concept introduction:

The addition of halogens to alkenes in the presence of aqueous DMSO results in the anti addition of the halohydrin, HOX, to the double bond. In the first step a cyclic halonium ion is formed by the attack of the double bond on the halogen. In the second step water attacks the halonium ion from the least shielded side to give an anti addition product. The addition obeys Markovnikov orientation. The negative part (OH) adds to the doubly bonded carbon atom which has more number of substituents.

To give:

The product of the reaction shown if the reaction was conducted in DMSO with water and to give the complete mechanism of the reaction including appropriate regiochemistry and stereochemistry.

Interpretation Introduction

c)

Interpretation:

The product of the reaction shown if the reaction was conducted in DMSO with water is to be given. The complete mechanism of the reaction including appropriate regiochemistry and stereochemistry is also to be given.

Concept introduction:

The addition of halogens to alkenes in the presence of aqueous DMSO results in the anti addition of the halohydrin, HOX, to the double bond. In the first step a cyclic halonium ion is formed by the attack of the double bond on halogen. In the second step water attacks the halonium ion from the least shielded side to give an anti addition product. The addition obeys Markovnokov orientation. The negative part (OH) adds to the doubly bonded carbon atom which has more number of substituents.

To give:

The product of the reaction shown if the reaction was conducted in DMSO with water and to give the complete mechanism of the reaction including appropriate regiochemistry and stereochemistry.

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Answer 3

Question

Chapter 8.SE, Problem 27MP

Interpretation Introduction

a)

Interpretation:

The product of the reaction shown if the reaction was conducted in DMSO with water is to be given. The complete mechanism of the reaction including appropriate regiochemistry and stereochemistry is also to be given.

Concept introduction:

The addition of halogens to alkenes in the presence of aqueous DMSO results in the anti addition of the halohydrin, HOX to the double bond. In the first step a cyclic halonium ion is formed by the attack of the double bond on the halogen. In the second step water attacks the halonium ion from the least shielded side, followed by the loss of a proton to give an anti addition product. The addition to unsymmetrical alkenes follows Markovnikov regiochemistry. The negative part (OH) adds to the doubly bonded carbon atom which has more number of substituents.

To give:

The product of the reaction shown if the reaction was conducted in DMSO with water and to give the complete mechanism of the reaction including appropriate regiochemistry and stereochemistry.

Interpretation Introduction

b)

Interpretation:

The product of the reaction shown if the reaction was conducted in DMSO with water is to be given. The complete mechanism of the reaction including appropriate regiochemistry and stereochemistry is also to be given.

Concept introduction:

The addition of halogens to alkenes in the presence of aqueous DMSO results in the anti addition of the halohydrin, HOX, to the double bond. In the first step a cyclic halonium ion is formed by the attack of the double bond on the halogen. In the second step water attacks the halonium ion from the least shielded side to give an anti addition product. The addition obeys Markovnikov orientation. The negative part (OH) adds to the doubly bonded carbon atom which has more number of substituents.

To give:

The product of the reaction shown if the reaction was conducted in DMSO with water and to give the complete mechanism of the reaction including appropriate regiochemistry and stereochemistry.

Interpretation Introduction

c)

Interpretation:

The product of the reaction shown if the reaction was conducted in DMSO with water is to be given. The complete mechanism of the reaction including appropriate regiochemistry and stereochemistry is also to be given.

Concept introduction:

The addition of halogens to alkenes in the presence of aqueous DMSO results in the anti addition of the halohydrin, HOX, to the double bond. In the first step a cyclic halonium ion is formed by the attack of the double bond on halogen. In the second step water attacks the halonium ion from the least shielded side to give an anti addition product. The addition obeys Markovnokov orientation. The negative part (OH) adds to the doubly bonded carbon atom which has more number of substituents.

To give:

The product of the reaction shown if the reaction was conducted in DMSO with water and to give the complete mechanism of the reaction including appropriate regiochemistry and stereochemistry.

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Answer 4

Question

Chapter 8.SE, Problem 27MP

Interpretation Introduction

a)

Interpretation:

The product of the reaction shown if the reaction was conducted in DMSO with water is to be given. The complete mechanism of the reaction including appropriate regiochemistry and stereochemistry is also to be given.

Concept introduction:

The addition of halogens to alkenes in the presence of aqueous DMSO results in the anti addition of the halohydrin, HOX to the double bond. In the first step a cyclic halonium ion is formed by the attack of the double bond on the halogen. In the second step water attacks the halonium ion from the least shielded side, followed by the loss of a proton to give an anti addition product. The addition to unsymmetrical alkenes follows Markovnikov regiochemistry. The negative part (OH) adds to the doubly bonded carbon atom which has more number of substituents.

To give:

The product of the reaction shown if the reaction was conducted in DMSO with water and to give the complete mechanism of the reaction including appropriate regiochemistry and stereochemistry.

Interpretation Introduction

b)

Interpretation:

The product of the reaction shown if the reaction was conducted in DMSO with water is to be given. The complete mechanism of the reaction including appropriate regiochemistry and stereochemistry is also to be given.

Concept introduction:

The addition of halogens to alkenes in the presence of aqueous DMSO results in the anti addition of the halohydrin, HOX, to the double bond. In the first step a cyclic halonium ion is formed by the attack of the double bond on the halogen. In the second step water attacks the halonium ion from the least shielded side to give an anti addition product. The addition obeys Markovnikov orientation. The negative part (OH) adds to the doubly bonded carbon atom which has more number of substituents.

To give:

The product of the reaction shown if the reaction was conducted in DMSO with water and to give the complete mechanism of the reaction including appropriate regiochemistry and stereochemistry.

Interpretation Introduction

c)

Interpretation:

The product of the reaction shown if the reaction was conducted in DMSO with water is to be given. The complete mechanism of the reaction including appropriate regiochemistry and stereochemistry is also to be given.

Concept introduction:

The addition of halogens to alkenes in the presence of aqueous DMSO results in the anti addition of the halohydrin, HOX, to the double bond. In the first step a cyclic halonium ion is formed by the attack of the double bond on halogen. In the second step water attacks the halonium ion from the least shielded side to give an anti addition product. The addition obeys Markovnokov orientation. The negative part (OH) adds to the doubly bonded carbon atom which has more number of substituents.

To give:

The product of the reaction shown if the reaction was conducted in DMSO with water and to give the complete mechanism of the reaction including appropriate regiochemistry and stereochemistry.

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Answer 5

Chapter 8.SE, Problem 27MP

Interpretation Introduction

a)

Interpretation:

The product of the reaction shown if the reaction was conducted in DMSO with water is to be given. The complete mechanism of the reaction including appropriate regiochemistry and stereochemistry is also to be given.

Concept introduction:

The addition of halogens to alkenes in the presence of aqueous DMSO results in the anti addition of the halohydrin, HOX to the double bond. In the first step a cyclic halonium ion is formed by the attack of the double bond on the halogen. In the second step water attacks the halonium ion from the least shielded side, followed by the loss of a proton to give an anti addition product. The addition to unsymmetrical alkenes follows Markovnikov regiochemistry. The negative part (OH) adds to the doubly bonded carbon atom which has more number of substituents.

To give:

The product of the reaction shown if the reaction was conducted in DMSO with water and to give the complete mechanism of the reaction including appropriate regiochemistry and stereochemistry.

Interpretation Introduction

b)

Interpretation:

The product of the reaction shown if the reaction was conducted in DMSO with water is to be given. The complete mechanism of the reaction including appropriate regiochemistry and stereochemistry is also to be given.

Concept introduction:

The addition of halogens to alkenes in the presence of aqueous DMSO results in the anti addition of the halohydrin, HOX, to the double bond. In the first step a cyclic halonium ion is formed by the attack of the double bond on the halogen. In the second step water attacks the halonium ion from the least shielded side to give an anti addition product. The addition obeys Markovnikov orientation. The negative part (OH) adds to the doubly bonded carbon atom which has more number of substituents.

To give:

The product of the reaction shown if the reaction was conducted in DMSO with water and to give the complete mechanism of the reaction including appropriate regiochemistry and stereochemistry.

Interpretation Introduction

c)

Interpretation:

The product of the reaction shown if the reaction was conducted in DMSO with water is to be given. The complete mechanism of the reaction including appropriate regiochemistry and stereochemistry is also to be given.

Concept introduction:

The addition of halogens to alkenes in the presence of aqueous DMSO results in the anti addition of the halohydrin, HOX, to the double bond. In the first step a cyclic halonium ion is formed by the attack of the double bond on halogen. In the second step water attacks the halonium ion from the least shielded side to give an anti addition product. The addition obeys Markovnokov orientation. The negative part (OH) adds to the doubly bonded carbon atom which has more number of substituents.

To give:

The product of the reaction shown if the reaction was conducted in DMSO with water and to give the complete mechanism of the reaction including appropriate regiochemistry and stereochemistry.

Answer 6

Chapter 8.SE, Problem 27MP

Interpretation Introduction

a)

Interpretation:

The product of the reaction shown if the reaction was conducted in DMSO with water is to be given. The complete mechanism of the reaction including appropriate regiochemistry and stereochemistry is also to be given.

Concept introduction:

The addition of halogens to alkenes in the presence of aqueous DMSO results in the anti addition of the halohydrin, HOX to the double bond. In the first step a cyclic halonium ion is formed by the attack of the double bond on the halogen. In the second step water attacks the halonium ion from the least shielded side, followed by the loss of a proton to give an anti addition product. The addition to unsymmetrical alkenes follows Markovnikov regiochemistry. The negative part (OH) adds to the doubly bonded carbon atom which has more number of substituents.

To give:

The product of the reaction shown if the reaction was conducted in DMSO with water and to give the complete mechanism of the reaction including appropriate regiochemistry and stereochemistry.

Answer 7

Chapter 8.SE, Problem 27MP

Interpretation Introduction

a)

Interpretation:

The product of the reaction shown if the reaction was conducted in DMSO with water is to be given. The complete mechanism of the reaction including appropriate regiochemistry and stereochemistry is also to be given.

Concept introduction:

The addition of halogens to alkenes in the presence of aqueous DMSO results in the anti addition of the halohydrin, HOX to the double bond. In the first step a cyclic halonium ion is formed by the attack of the double bond on the halogen. In the second step water attacks the halonium ion from the least shielded side, followed by the loss of a proton to give an anti addition product. The addition to unsymmetrical alkenes follows Markovnikov regiochemistry. The negative part (OH) adds to the doubly bonded carbon atom which has more number of substituents.

To give:

The product of the reaction shown if the reaction was conducted in DMSO with water and to give the complete mechanism of the reaction including appropriate regiochemistry and stereochemistry.

Answer 8

Interpretation Introduction

b)

Interpretation:

The product of the reaction shown if the reaction was conducted in DMSO with water is to be given. The complete mechanism of the reaction including appropriate regiochemistry and stereochemistry is also to be given.

Concept introduction:

The addition of halogens to alkenes in the presence of aqueous DMSO results in the anti addition of the halohydrin, HOX, to the double bond. In the first step a cyclic halonium ion is formed by the attack of the double bond on the halogen. In the second step water attacks the halonium ion from the least shielded side to give an anti addition product. The addition obeys Markovnikov orientation. The negative part (OH) adds to the doubly bonded carbon atom which has more number of substituents.

To give:

The product of the reaction shown if the reaction was conducted in DMSO with water and to give the complete mechanism of the reaction including appropriate regiochemistry and stereochemistry.

Answer 9

Interpretation Introduction

b)

Interpretation:

The product of the reaction shown if the reaction was conducted in DMSO with water is to be given. The complete mechanism of the reaction including appropriate regiochemistry and stereochemistry is also to be given.

Concept introduction:

The addition of halogens to alkenes in the presence of aqueous DMSO results in the anti addition of the halohydrin, HOX, to the double bond. In the first step a cyclic halonium ion is formed by the attack of the double bond on the halogen. In the second step water attacks the halonium ion from the least shielded side to give an anti addition product. The addition obeys Markovnikov orientation. The negative part (OH) adds to the doubly bonded carbon atom which has more number of substituents.

To give:

The product of the reaction shown if the reaction was conducted in DMSO with water and to give the complete mechanism of the reaction including appropriate regiochemistry and stereochemistry.

Answer 10

Interpretation Introduction

c)

Interpretation:

The product of the reaction shown if the reaction was conducted in DMSO with water is to be given. The complete mechanism of the reaction including appropriate regiochemistry and stereochemistry is also to be given.

Concept introduction:

The addition of halogens to alkenes in the presence of aqueous DMSO results in the anti addition of the halohydrin, HOX, to the double bond. In the first step a cyclic halonium ion is formed by the attack of the double bond on halogen. In the second step water attacks the halonium ion from the least shielded side to give an anti addition product. The addition obeys Markovnokov orientation. The negative part (OH) adds to the doubly bonded carbon atom which has more number of substituents.

To give:

The product of the reaction shown if the reaction was conducted in DMSO with water and to give the complete mechanism of the reaction including appropriate regiochemistry and stereochemistry.

Answer 11

Interpretation Introduction

c)

Interpretation:

The product of the reaction shown if the reaction was conducted in DMSO with water is to be given. The complete mechanism of the reaction including appropriate regiochemistry and stereochemistry is also to be given.

Concept introduction:

The addition of halogens to alkenes in the presence of aqueous DMSO results in the anti addition of the halohydrin, HOX, to the double bond. In the first step a cyclic halonium ion is formed by the attack of the double bond on halogen. In the second step water attacks the halonium ion from the least shielded side to give an anti addition product. The addition obeys Markovnokov orientation. The negative part (OH) adds to the doubly bonded carbon atom which has more number of substituents.

To give:

The product of the reaction shown if the reaction was conducted in DMSO with water and to give the complete mechanism of the reaction including appropriate regiochemistry and stereochemistry.

Answer 12

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Answer 23

Ch. 8.1 - Prob. 1P Ch. 8.1 - How many alkene products, including E,Z isomers,...Ch. 8.2 - Prob. 3P Ch. 8.2 - Addition of HCl to 1, 2-dimethylcyclohexene yields...Ch. 8.3 - Prob. 5P Ch. 8.3 - Prob. 6P Ch. 8.4 - Prob. 7P Ch. 8.4 - From what alkenes might the following alcohols...Ch. 8.5 - Prob. 9P Ch. 8.5 - What alkenes might be used to prepare the...

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