GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES
4th Edition
ISBN: 9781265982959
Author: SMITH
Publisher: MCG
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Chapter 8, Problem 96P
A patient receives 750 ml, of a 10.% (w/v) aqueous glucose solution. (a) How manygrams of glucose does the patient receive? (b) How many moles of glucose (molar mass 180.2 g/mol) does the patient receive?
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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 8 Solutions
GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES
Ch. 8.1 - Classify each substance as a heterogeneous...Ch. 8.1 - Use the appearance of each product to classify it...Ch. 8.2 - Consider the following diagrams for an aqueous...Ch. 8.2 - Classify each solution as an electrolyte or...Ch. 8.2 - Using the given number of moles, determine how...Ch. 8.2 - Prob. 8.2PPCh. 8.2 - A solution contains the following ions:...Ch. 8.2 - If a solution contains 125 mEq of Na+ per liter,...Ch. 8.3 - Which compounds are water soluble? a. NaNO3 b. CH4...Ch. 8.3 - Prob. 8.7P
Ch. 8.3 - Use the solubility rules to predict whether the...Ch. 8.3 - Use the solubility rules for ionic compounds to...Ch. 8.4 - Why does a soft drink become "flat" faster when it...Ch. 8.4 - Predict the effect each change has on the...Ch. 8.5 - A commercial mouthwash contains 4.3 g of ethanol...Ch. 8.5 - What is the weight/volume percent concentration of...Ch. 8.5 - Prob. 8.6PPCh. 8.5 - Prob. 8.7PPCh. 8.5 - A drink sold in a health food store contains 0.50%...Ch. 8.5 - Prob. 8.12PCh. 8.5 - What is the concentration in parts per million of...Ch. 8.6 - Prob. 8.10PPCh. 8.6 - Prob. 8.13PCh. 8.6 - Prob. 8.11PPCh. 8.6 - Prob. 8.12PPCh. 8.6 - How many grams of NaCl are contained in each of...Ch. 8.6 - How many milliliters of a 0.25 M sucrose solution...Ch. 8.7 - What is the concentration of a solution formed by...Ch. 8.7 - If the solution of A+B- in X is diluted, which...Ch. 8.7 - Prob. 8.15PPCh. 8.7 - Prob. 8.16PCh. 8.8 - What is the boiling point of a solution prepared...Ch. 8.8 - Representations A, B, and C each show an aqueous...Ch. 8.8 - Prob. 8.18PPCh. 8.8 - What is the melting point of a solution that is...Ch. 8.9 - Which solution in each pair exerts the greater...Ch. 8.9 - Prob. 8.19PCh. 8.9 - Consider the two aqueous solutions separated by a...Ch. 8.9 - What happens to a red blood cell when it is placed...Ch. 8 - Prob. 21PCh. 8 - Prob. 22PCh. 8 - Prob. 23PCh. 8 - Which representation of molecular art better shows...Ch. 8 - Classify each of the following as a solution,...Ch. 8 - Classify each of the following as a solution,...Ch. 8 - Prob. 27PCh. 8 - Label each diagram as a strong electrolyte, weak...Ch. 8 - Prob. 29PCh. 8 - Prob. 30PCh. 8 - Prob. 31PCh. 8 - Prob. 32PCh. 8 - Consider a mixture of two substances shown in blue...Ch. 8 - Which diagram (C or D) best represents what occurs...Ch. 8 - If the solubilityofKClin 100 mL of H2O is 34 g at...Ch. 8 - If the solubilityofsucrosein 100 mL of H2O is 204...Ch. 8 - Prob. 37PCh. 8 - Prob. 38PCh. 8 - Using the ball-and-stick model for methanol...Ch. 8 - Prob. 40PCh. 8 - Prob. 41PCh. 8 - Prob. 42PCh. 8 - Prob. 43PCh. 8 - Prob. 44PCh. 8 - Prob. 45PCh. 8 - Prob. 46PCh. 8 - Prob. 47PCh. 8 - How is the solubility of helium gas in water...Ch. 8 - Use the solubility rules listed in Section 8.3B to...Ch. 8 - Use the solubility rules listed in Section 8.3B to...Ch. 8 - Prob. 51PCh. 8 - Prob. 52PCh. 8 - Prob. 53PCh. 8 - Prob. 54PCh. 8 - Prob. 55PCh. 8 - Prob. 56PCh. 8 - Prob. 57PCh. 8 - Prob. 58PCh. 8 - How would you use a 250-mL volumetric flask to...Ch. 8 - How would you use a 250-mLvolumetric flask to...Ch. 8 - Prob. 61PCh. 8 - Prob. 62PCh. 8 - Prob. 63PCh. 8 - Prob. 64PCh. 8 - Prob. 65PCh. 8 - What is the molarity of a 20.0% (v/v) aqueous...Ch. 8 - Prob. 67PCh. 8 - Prob. 68PCh. 8 - Prob. 69PCh. 8 - Prob. 70PCh. 8 - Prob. 71PCh. 8 - Prob. 72PCh. 8 - Prob. 73PCh. 8 - Prob. 74PCh. 8 - Prob. 75PCh. 8 - Prob. 76PCh. 8 - Prob. 77PCh. 8 - Representations A (containing 1.0 mol ofNaCl) and...Ch. 8 - What is the boiling point of a solution that...Ch. 8 - Prob. 80PCh. 8 - If 150 g of ethylene glycol (C2H6O2) is added to...Ch. 8 - Prob. 82PCh. 8 - Prob. 83PCh. 8 - Prob. 84PCh. 8 - Which solution in each pair has the higher melting...Ch. 8 - Prob. 86PCh. 8 - A flask contains two compartments (A and B) with...Ch. 8 - A flask contains two compartments (A and B) with...Ch. 8 - The molecular art illustrates a red blood cell in...Ch. 8 - Prob. 90PCh. 8 - Prob. 91PCh. 8 - Explain why more sugar dissolves in a cup of hot...Ch. 8 - If the concentration of glucose in the blood is...Ch. 8 - Prob. 94PCh. 8 - Mannitol, a carbohydrate, is supplied as a 25%...Ch. 8 - A patient receives 750 ml, of a 10.% (w/v) aqueous...Ch. 8 - Explain why a cucumber placed in a concentrated...Ch. 8 - Explain why a cucumber placed in a concentrated...Ch. 8 - Prob. 99PCh. 8 - Prob. 100PCh. 8 - Prob. 101PCh. 8 - Prob. 102PCh. 8 - The therapeutic concentration—the concentration...Ch. 8 - Prob. 104CP
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY