(a) Interpretation: Comparison of ratio of atoms or ions in 3p states and in ground state of Na atom and Mg + is to be done when there is a natural gas air flame of temperature 1800 K. Concept introduction: Boltzmann equation is used for the calculation of the ratio. This equation tells that how much an atom or ion is populated as a function of temperature. This equation is given as- N j N o = g j g o exp ( − E j k T ) ......... (1) And the calculation of energy of atom and ion is done by the following formula- E j = h c λ ......... (2) Where, h= Planck’s constant c = light velocity λ= wavelength Ej= energy difference of excited state and ground state

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bre The reaction sequence shown in Scheme 5 demonstrates the synthesis of a substituted benzene derivative Q. wolsd works 2 NH2 NaNO2, HCI (apexe) 13× (1 HNO3, H2SO4 C6H5CIN2 0°C HOTE CHINO₂ N O *O₂H ( PO Q Я Scheme 5 2 bag abouoqmics to sounde odi WEIC (i) Draw the structure of intermediate O. [2 marks] to noitsmot od: tot meinedogm, noit so oft listsb ni zaupaib bas wa (ii) Draw the mechanism for the transformation of aniline N to intermediate O. Spoilage (b) [6 marks] (iii) Identify the reagent X used to convert compound O to the iodinated compound [tom E P. vueimado oilovonsa ni moitos nolisbnolov ayd toes ai tedw nisiqx (iv) Identify the possible structures of compound Q. [2 marks] [2 marks] [shom 2] (v) bus noires goiribbeolovo xnivollot adj to subora sidab Draw the mechanism for the transformation of intermediate P to compound Q. [5 marks] vi (vi) Account for the regiochemical outcome observed in the reaction forming compound Q. [3 marks]

Answer 1

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Chapter 8, Problem 8.9QAP

Interpretation Introduction

(a)

Interpretation:

Comparison of ratio of atoms or ions in 3p states and in ground state of Na atom and Mg⁺ is to be done when there is a natural gas air flame of temperature 1800 K.

Concept introduction:

Boltzmann equation is used for the calculation of the ratio. This equation tells that how much an atom or ion is populated as a function of temperature. This equation is given as-

NjNo=gjgoexp(−EjkT) ......... (1)

And the calculation of energy of atom and ion is done by the following formula-

Ej=hcλ ......... (2)

Where,

h= Planck’s constant

c = light velocity

λ= wavelength

Ej= energy difference of excited state and ground state

Interpretation Introduction

(b)

Interpretation:

Comparison of ratio of atoms or ions in 3p states and in ground state of Na atom and Mg⁺ is to be done when there is a hydrogen - oxygen flame of 2950K.

Concept introduction:

Boltzmann equation is used for the calculation of the ratio. This equation tells that how much an atom or ion is populated as a function of temperature. This equation is given as-

NjNo=gjgoexp(−EjkT) ......... (1)

And the calculation of energy of atom and ion is done by the following formula-

Ej=hcλ ......... (2)

Where,

h= Planck’s constant

c = light velocity

λ= wavelength

Ej= energy difference of excited state and ground state.

Interpretation Introduction

(c)

Interpretation:

Comparison of ratio of atoms or ions in 3p states and in ground state of Na atom and Mg⁺ is to be done when there is an inductively −coupled plasma source of 7250 K.

Concept introduction:

Boltzmann equation is used for the calculation of the ratio. This equation tells that how much an atom or ion is populated as a function of temperature. This equation is given as-

NjNo=gjgoexp(−EjkT) ......... (1)

And the calculation of energy of atom and ion is done by the following formula-

Ej=hcλ ......... (2)

Where,

h= Planck’s constant

c = light velocity

λ= wavelength

Ej= energy difference of excited state and ground state.

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bre The reaction sequence shown in Scheme 5 demonstrates the synthesis of a substituted benzene derivative Q. wolsd works 2 NH2 NaNO2, HCI (apexe) 13× (1 HNO3, H2SO4 C6H5CIN2 0°C HOTE CHINO₂ N O *O₂H ( PO Q Я Scheme 5 2 bag abouoqmics to sounde odi WEIC (i) Draw the structure of intermediate O. [2 marks] to noitsmot od: tot meinedogm, noit so oft listsb ni zaupaib bas wa (ii) Draw the mechanism for the transformation of aniline N to intermediate O. Spoilage (b) [6 marks] (iii) Identify the reagent X used to convert compound O to the iodinated compound [tom E P. vueimado oilovonsa ni moitos nolisbnolov ayd toes ai tedw nisiqx (iv) Identify the possible structures of compound Q. [2 marks] [2 marks] [shom 2] (v) bus noires goiribbeolovo xnivollot adj to subora sidab Draw the mechanism for the transformation of intermediate P to compound Q. [5 marks] vi (vi) Account for the regiochemical outcome observed in the reaction forming compound Q. [3 marks]

PROBLEM 4 Solved Show how 1-butanol can be converted into the following compounds: a. PROBLEM 5+ b. d. -C= N

Which alkene is the major product of this dehydration? OH H2SO4 heat

Answer 2

Question

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Chapter 8, Problem 8.9QAP

Interpretation Introduction

(a)

Interpretation:

Comparison of ratio of atoms or ions in 3p states and in ground state of Na atom and Mg⁺ is to be done when there is a natural gas air flame of temperature 1800 K.

Concept introduction:

Boltzmann equation is used for the calculation of the ratio. This equation tells that how much an atom or ion is populated as a function of temperature. This equation is given as-

NjNo=gjgoexp(−EjkT) ......... (1)

And the calculation of energy of atom and ion is done by the following formula-

Ej=hcλ ......... (2)

Where,

h= Planck’s constant

c = light velocity

λ= wavelength

Ej= energy difference of excited state and ground state

Interpretation Introduction

(b)

Interpretation:

Comparison of ratio of atoms or ions in 3p states and in ground state of Na atom and Mg⁺ is to be done when there is a hydrogen - oxygen flame of 2950K.

Concept introduction:

Boltzmann equation is used for the calculation of the ratio. This equation tells that how much an atom or ion is populated as a function of temperature. This equation is given as-

NjNo=gjgoexp(−EjkT) ......... (1)

And the calculation of energy of atom and ion is done by the following formula-

Ej=hcλ ......... (2)

Where,

h= Planck’s constant

c = light velocity

λ= wavelength

Ej= energy difference of excited state and ground state.

Interpretation Introduction

(c)

Interpretation:

Comparison of ratio of atoms or ions in 3p states and in ground state of Na atom and Mg⁺ is to be done when there is an inductively −coupled plasma source of 7250 K.

Concept introduction:

Boltzmann equation is used for the calculation of the ratio. This equation tells that how much an atom or ion is populated as a function of temperature. This equation is given as-

NjNo=gjgoexp(−EjkT) ......... (1)

And the calculation of energy of atom and ion is done by the following formula-

Ej=hcλ ......... (2)

Where,

h= Planck’s constant

c = light velocity

λ= wavelength

Ej= energy difference of excited state and ground state.

Expert Solution & Answer

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Answer 3

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Chapter 8, Problem 8.9QAP

Interpretation Introduction

(a)

Interpretation:

Comparison of ratio of atoms or ions in 3p states and in ground state of Na atom and Mg⁺ is to be done when there is a natural gas air flame of temperature 1800 K.

Concept introduction:

Boltzmann equation is used for the calculation of the ratio. This equation tells that how much an atom or ion is populated as a function of temperature. This equation is given as-

NjNo=gjgoexp(−EjkT) ......... (1)

And the calculation of energy of atom and ion is done by the following formula-

Ej=hcλ ......... (2)

Where,

h= Planck’s constant

c = light velocity

λ= wavelength

Ej= energy difference of excited state and ground state

Interpretation Introduction

(b)

Interpretation:

Comparison of ratio of atoms or ions in 3p states and in ground state of Na atom and Mg⁺ is to be done when there is a hydrogen - oxygen flame of 2950K.

Concept introduction:

Boltzmann equation is used for the calculation of the ratio. This equation tells that how much an atom or ion is populated as a function of temperature. This equation is given as-

NjNo=gjgoexp(−EjkT) ......... (1)

And the calculation of energy of atom and ion is done by the following formula-

Ej=hcλ ......... (2)

Where,

h= Planck’s constant

c = light velocity

λ= wavelength

Ej= energy difference of excited state and ground state.

Interpretation Introduction

(c)

Interpretation:

Comparison of ratio of atoms or ions in 3p states and in ground state of Na atom and Mg⁺ is to be done when there is an inductively −coupled plasma source of 7250 K.

Concept introduction:

Boltzmann equation is used for the calculation of the ratio. This equation tells that how much an atom or ion is populated as a function of temperature. This equation is given as-

NjNo=gjgoexp(−EjkT) ......... (1)

And the calculation of energy of atom and ion is done by the following formula-

Ej=hcλ ......... (2)

Where,

h= Planck’s constant

c = light velocity

λ= wavelength

Ej= energy difference of excited state and ground state.

Expert Solution & Answer

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Answer 4

Question

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Chapter 8, Problem 8.9QAP

Interpretation Introduction

(a)

Interpretation:

Comparison of ratio of atoms or ions in 3p states and in ground state of Na atom and Mg⁺ is to be done when there is a natural gas air flame of temperature 1800 K.

Concept introduction:

Boltzmann equation is used for the calculation of the ratio. This equation tells that how much an atom or ion is populated as a function of temperature. This equation is given as-

NjNo=gjgoexp(−EjkT) ......... (1)

And the calculation of energy of atom and ion is done by the following formula-

Ej=hcλ ......... (2)

Where,

h= Planck’s constant

c = light velocity

λ= wavelength

Ej= energy difference of excited state and ground state

Interpretation Introduction

(b)

Interpretation:

Comparison of ratio of atoms or ions in 3p states and in ground state of Na atom and Mg⁺ is to be done when there is a hydrogen - oxygen flame of 2950K.

Concept introduction:

Boltzmann equation is used for the calculation of the ratio. This equation tells that how much an atom or ion is populated as a function of temperature. This equation is given as-

NjNo=gjgoexp(−EjkT) ......... (1)

And the calculation of energy of atom and ion is done by the following formula-

Ej=hcλ ......... (2)

Where,

h= Planck’s constant

c = light velocity

λ= wavelength

Ej= energy difference of excited state and ground state.

Interpretation Introduction

(c)

Interpretation:

Comparison of ratio of atoms or ions in 3p states and in ground state of Na atom and Mg⁺ is to be done when there is an inductively −coupled plasma source of 7250 K.

Concept introduction:

Boltzmann equation is used for the calculation of the ratio. This equation tells that how much an atom or ion is populated as a function of temperature. This equation is given as-

NjNo=gjgoexp(−EjkT) ......... (1)

And the calculation of energy of atom and ion is done by the following formula-

Ej=hcλ ......... (2)

Where,

h= Planck’s constant

c = light velocity

λ= wavelength

Ej= energy difference of excited state and ground state.

Expert Solution & Answer

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Answer 5

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Answer 6

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Answer 7

Chapter 8, Problem 8.9QAP

Interpretation Introduction

(a)

Interpretation:

Comparison of ratio of atoms or ions in 3p states and in ground state of Na atom and Mg⁺ is to be done when there is a natural gas air flame of temperature 1800 K.

Concept introduction:

Boltzmann equation is used for the calculation of the ratio. This equation tells that how much an atom or ion is populated as a function of temperature. This equation is given as-

NjNo=gjgoexp(−EjkT) ......... (1)

And the calculation of energy of atom and ion is done by the following formula-

Ej=hcλ ......... (2)

Where,

h= Planck’s constant

c = light velocity

λ= wavelength

Ej= energy difference of excited state and ground state

Interpretation Introduction

(b)

Interpretation:

Comparison of ratio of atoms or ions in 3p states and in ground state of Na atom and Mg⁺ is to be done when there is a hydrogen - oxygen flame of 2950K.

Concept introduction:

Boltzmann equation is used for the calculation of the ratio. This equation tells that how much an atom or ion is populated as a function of temperature. This equation is given as-

NjNo=gjgoexp(−EjkT) ......... (1)

And the calculation of energy of atom and ion is done by the following formula-

Ej=hcλ ......... (2)

Where,

h= Planck’s constant

c = light velocity

λ= wavelength

Ej= energy difference of excited state and ground state.

Interpretation Introduction

(c)

Interpretation:

Comparison of ratio of atoms or ions in 3p states and in ground state of Na atom and Mg⁺ is to be done when there is an inductively −coupled plasma source of 7250 K.

Concept introduction:

Boltzmann equation is used for the calculation of the ratio. This equation tells that how much an atom or ion is populated as a function of temperature. This equation is given as-

NjNo=gjgoexp(−EjkT) ......... (1)

And the calculation of energy of atom and ion is done by the following formula-

Ej=hcλ ......... (2)

Where,

h= Planck’s constant

c = light velocity

λ= wavelength

Ej= energy difference of excited state and ground state.

Answer 8

Chapter 8, Problem 8.9QAP

Interpretation Introduction

(a)

Interpretation:

Comparison of ratio of atoms or ions in 3p states and in ground state of Na atom and Mg⁺ is to be done when there is a natural gas air flame of temperature 1800 K.

Concept introduction:

Boltzmann equation is used for the calculation of the ratio. This equation tells that how much an atom or ion is populated as a function of temperature. This equation is given as-

NjNo=gjgoexp(−EjkT) ......... (1)

And the calculation of energy of atom and ion is done by the following formula-

Ej=hcλ ......... (2)

Where,

h= Planck’s constant

c = light velocity

λ= wavelength

Ej= energy difference of excited state and ground state

Answer 9

Chapter 8, Problem 8.9QAP

Interpretation Introduction

(a)

Interpretation:

Comparison of ratio of atoms or ions in 3p states and in ground state of Na atom and Mg⁺ is to be done when there is a natural gas air flame of temperature 1800 K.

Concept introduction:

Boltzmann equation is used for the calculation of the ratio. This equation tells that how much an atom or ion is populated as a function of temperature. This equation is given as-

NjNo=gjgoexp(−EjkT) ......... (1)

And the calculation of energy of atom and ion is done by the following formula-

Ej=hcλ ......... (2)

Where,

h= Planck’s constant

c = light velocity

λ= wavelength

Ej= energy difference of excited state and ground state

Answer 10

Interpretation Introduction

(b)

Interpretation:

Comparison of ratio of atoms or ions in 3p states and in ground state of Na atom and Mg⁺ is to be done when there is a hydrogen - oxygen flame of 2950K.

Concept introduction:

Boltzmann equation is used for the calculation of the ratio. This equation tells that how much an atom or ion is populated as a function of temperature. This equation is given as-

NjNo=gjgoexp(−EjkT) ......... (1)

And the calculation of energy of atom and ion is done by the following formula-

Ej=hcλ ......... (2)

Where,

h= Planck’s constant

c = light velocity

λ= wavelength

Ej= energy difference of excited state and ground state.

Answer 11

Interpretation Introduction

(b)

Interpretation:

Comparison of ratio of atoms or ions in 3p states and in ground state of Na atom and Mg⁺ is to be done when there is a hydrogen - oxygen flame of 2950K.

Concept introduction:

Boltzmann equation is used for the calculation of the ratio. This equation tells that how much an atom or ion is populated as a function of temperature. This equation is given as-

NjNo=gjgoexp(−EjkT) ......... (1)

And the calculation of energy of atom and ion is done by the following formula-

Ej=hcλ ......... (2)

Where,

h= Planck’s constant

c = light velocity

λ= wavelength

Ej= energy difference of excited state and ground state.

Answer 12

Interpretation Introduction

(c)

Interpretation:

Comparison of ratio of atoms or ions in 3p states and in ground state of Na atom and Mg⁺ is to be done when there is an inductively −coupled plasma source of 7250 K.

Concept introduction:

Boltzmann equation is used for the calculation of the ratio. This equation tells that how much an atom or ion is populated as a function of temperature. This equation is given as-

NjNo=gjgoexp(−EjkT) ......... (1)

And the calculation of energy of atom and ion is done by the following formula-

Ej=hcλ ......... (2)

Where,

h= Planck’s constant

c = light velocity

λ= wavelength

Ej= energy difference of excited state and ground state.

Answer 13

Interpretation Introduction

(c)

Interpretation:

Comparison of ratio of atoms or ions in 3p states and in ground state of Na atom and Mg⁺ is to be done when there is an inductively −coupled plasma source of 7250 K.

Concept introduction:

Boltzmann equation is used for the calculation of the ratio. This equation tells that how much an atom or ion is populated as a function of temperature. This equation is given as-

NjNo=gjgoexp(−EjkT) ......... (1)

And the calculation of energy of atom and ion is done by the following formula-

Ej=hcλ ......... (2)

Where,

h= Planck’s constant

c = light velocity

λ= wavelength

Ej= energy difference of excited state and ground state.

Answer 14

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Ch. 8 - Prob. 8.1QAP Ch. 8 - Prob. 8.2QAP Ch. 8 - Prob. 8.3QAP Ch. 8 - Prob. 8.4QAP Ch. 8 - Prob. 8.5QAP Ch. 8 - Prob. 8.6QAP Ch. 8 - Prob. 8.7QAP Ch. 8 - The Doppler effect is one of the sources of the...Ch. 8 - Prob. 8.9QAP Ch. 8 - In high-temperature sources, sodium atoms emit a...

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