
Concept explainers
(a)
Interpretation:
Comparison of ratio of atoms or ions in 3p states and in ground state of Na atom and Mg+ is to be done when there is a natural gas air flame of temperature 1800 K.
Concept introduction:
Boltzmann equation is used for the calculation of the ratio. This equation tells that how much an atom or ion is populated as a function of temperature. This equation is given as-
And the calculation of energy of atom and ion is done by the following formula-
Where,
h= Planck’s constant
c = light velocity
λ= wavelength
Ej= energy difference of excited state and ground state
(b)
Interpretation:
Comparison of ratio of atoms or ions in 3p states and in ground state of Na atom and Mg+ is to be done when there is a hydrogen - oxygen flame of 2950K.
Concept introduction:
Boltzmann equation is used for the calculation of the ratio. This equation tells that how much an atom or ion is populated as a function of temperature. This equation is given as-
And the calculation of energy of atom and ion is done by the following formula-
Where,
h= Planck’s constant
c = light velocity
λ= wavelength
Ej= energy difference of excited state and ground state.
(c)
Interpretation:
Comparison of ratio of atoms or ions in 3p states and in ground state of Na atom and Mg+ is to be done when there is an inductively −coupled plasma source of 7250 K.
Concept introduction:
Boltzmann equation is used for the calculation of the ratio. This equation tells that how much an atom or ion is populated as a function of temperature. This equation is given as-
And the calculation of energy of atom and ion is done by the following formula-
Where,
h= Planck’s constant
c = light velocity
λ= wavelength
Ej= energy difference of excited state and ground state.

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Chapter 8 Solutions
Principles of Instrumental Analysis
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