Principles of Instrumental Analysis
7th Edition
ISBN: 9781305577213
Author: Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher: Cengage Learning
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Chapter 8, Problem 8.2QAP
Interpretation Introduction
Interpretation:
The meaning of resonance fluorescence should be defined.
Concept introduction:
Fluorescence is the emission of
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bre
The reaction sequence shown in Scheme 5 demonstrates the synthesis of a
substituted benzene derivative Q.
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NH2
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Scheme 5
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(i)
Draw the structure of intermediate O.
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(ii) Draw the mechanism for the transformation of aniline N to intermediate O.
Spoilage
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[6 marks]
(iii) Identify the reagent X used to convert compound O to the iodinated compound
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P.
vueimado oilovonsa ni moitos nolisbnolov ayd toes ai tedw nisiqx
(iv) Identify the possible structures of compound Q.
[2 marks]
[2 marks]
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(v)
bus noires goiribbeolovo xnivollot adj to subora sidab
Draw the mechanism for the transformation of intermediate P to compound Q.
[5 marks]
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(vi) Account for the regiochemical outcome observed in the reaction forming
compound Q.
[3 marks]
PROBLEM 4 Solved
Show how 1-butanol can be converted into the following compounds:
a.
PROBLEM 5+
b.
d.
-C=
N
Which alkene is the major product of this dehydration?
OH
H2SO4
heat
Chapter 8 Solutions
Principles of Instrumental Analysis
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