Chapter 8, Problem 8.76QP

(a)

Interpretation Introduction

Interpretation:

From the given species that are arranged in the increasing order of their ionic radius has to be determined.

Concept Introduction:

Atomic radius:

Atomic radius is the distance between the atomic nucleus and outermost electron of an atom.  From the atomic radius, the size of atoms can be visualized.  But there is no specific distance from nucleus to electron due to electron cloud around the atom does not have well-defined boundary.

Atomic Number: Atomic number of the element is equal to the number of protons present in the nucleus of the element which is denoted by symbol Z. The superscript presents on the left side of the symbol of the element.

Periodic Table: The available chemical elements are arranged considering their atomic number, the electronic configuration and their properties. The elements placed on the left of the table are metals and non-metals are placed on right side of the table.

In periodic table the horizontal rows are called periods and the vertical column are called group. There are seven periods and 18 groups present in the table and some of those groups are given particular name as follows,

  $\begin{array}{l}\text{Group-1}\to \text{Alkali metal}\\ \text{Group-2}\to \text{Alkaline metals}\\ \text{Group-16}\to \text{Chalcogens}\\ \text{Group-17}\to \text{Halogens}\\ \text{Group-18}\to \text{Noble gases}\end{array}$

(b)

Interpretation Introduction

Interpretation:

The given set of isoelectronic species should be arranged according to the increasing order of their ionization energy.

Concept Introduction:

First ionization energy:

The ionization energy is the minimum energy required to remove the electron from an isolated atom which is in the gaseous state results to give gaseous ion with one positive charge.

${\text{atom}}_{\left(\text{g}\right)}\to {\text{ion with positive charge}}_{\left(\text{g}\right)}\text{ + electron}$

Second ionization:

Repeating the same process that is removal of another electron that is second electron from the resulting ion of first ionization is called second ionization.

Third ionization energy:

Removal of electron from ion that results from the second ionization is called third ionization which results to give ion with three positive charges which shows, three electrons gets removed from the atom and the energy associated with it is called third ionization energy.

Isoelectronic species: Two species are considered to be isoelectronic if they have equal number of electrons between them.