Chapter 8, Problem 36P

(a)

Interpretation Introduction

Interpretation:The major product of indicated reaction should be identified.

  

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

  

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include sodium borohydride, lithium aluminum hydride. The boron and lithium in these reagents tend to push the electron of $\text{B-H}$ bond towards carbonyl carbon as illustrated below;

  

Any organic compound must have no plane of symmetry in order to be chiral or optically active. The compounds with any plane of symmetry are achiral and optically inactive.

(b)

Interpretation Introduction

Interpretation:The major product of indicated reaction should be identified.

  

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

  

The aluminum and lithium in these reagents such as ${\text{LiAlH}}_{\text{4}}$ tend to push the electron of $\text{Al-H}$ bond towards carbonyl carbon.The work up finally yields alcohol as illustrated below:

  

(c)

Interpretation Introduction

Interpretation: The major product of indicated reaction should be identified.

  

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

  

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include sodium borohydride, lithium aluminum hydride. The boron and lithium in these reagents tend to push the electron of $\text{B-H}$ bond towards carbonyl carbon as illustrated below;

  

(d)

Interpretation Introduction

Interpretation: The major product of indicated reaction should be identified.

  

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

  

The aluminum and lithium in these reagents such as ${\text{LiAlH}}_{\text{4}}$ tend to push the electron of $\text{Al-H}$ bond towards carbonyl carbon.The work up finally yields alcohol as illustrated below:

  

(e)

Interpretation Introduction

Interpretation: The major product of indicated reaction should be identified.

  

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

  

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include sodium borohydride, lithium aluminum hydride. The boron and lithium in these reagents tend to push the electron of $\text{B-H}$ bond towards carbonyl carbon as illustrated below;

  

(f)

Interpretation Introduction

Interpretation: The major product of indicated reaction should be identified.

  

Concept introduction: The carbonyl bond is polar with partial postive charge on carbon and partial negative charge on oxygen as illustrated below.

  

Thus it can undergo hydride addition at carbon and proton addition at oxygen. Certain reagents that are useful for such hydride addition at carbonyl carbon include sodium borohydride, lithium aluminum hydride. The boron and lithium in these reagents tend to push the electron of $\text{B-H}$ bond towards carbonyl carbon as illustrated below;