Chemistry
3rd Edition
ISBN: 9780073402734
Author: Julia Burdge
Publisher: MCGRAW-HILL HIGHER EDUCATION
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Chapter 8, Problem 129AP
Interpretation Introduction
Interpretation:
The bond enthalpies of various bonds in the given compounds are to be compared and the effect of lone pairs on adjacent atoms on bond enthalpies is to be explained.
Concept introduction:
Bond Enthalpy is the energy required to break a bond of 1mole of a substance. It is given in
The Lewis dot symbols contain dots, which give information about valence electrons.
The Lewis dot symbols represent both bonds and lone pairs as dots.
The Lewis structures represent bonds as lines and lone pairs as dots.
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Draw the anti-Markovnikov product of the hydration of this alkene.
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AG/F-2° V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
-0.93
+0.38
-0.50
-0.51 -0.06
H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3
Acidic solution
Basic solution
-0.28
-0.50
3--1.12
-1.57
-2.05 -0.89
PO HPO H₂PO₂ →P → PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5
PH
P
0.0
-0.5
-1.0-
-1.5-
-2.0
H.PO,
-2.3+
-3 -2
-1
1
2
3
2
H,PO,
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
H,PO
4
S
Oxidation stale, N
Chapter 8 Solutions
Chemistry
Ch. 8.1 - Practice ProblemATTEMPT Write Lewis dot symbols...Ch. 8.1 - Practice Problem BUILD
Indicate the charge on...Ch. 8.1 - Practice ProblemCONCEPTUALIZE For each of the...Ch. 8.1 - 8.1.1 Using only a periodic table, determine the...Ch. 8.1 - 8.1.2 Using only a periodic table, determine the...Ch. 8.1 - To which group does element X belong if its Lewis...Ch. 8.1 - Prob. 4CPCh. 8.2 - Prob. 1PPACh. 8.2 - Practice ProblemBUILD Arrange the compounds NaF,...Ch. 8.2 - Practice ProblemCONCEPTUALIZE Common ions of four...
Ch. 8.2 - 8.2.1 Will the lattice energy of KF be larger or...Ch. 8.2 - 8.2.2 Using the following data, calculate the...Ch. 8.2 - 8.2.3 Lattice energies are graphed for three...Ch. 8.3 - Practice ProblemATTEMPT Using data from Figures...Ch. 8.3 - Prob. 1PPBCh. 8.3 - Prob. 1PPCCh. 8.4 - Practice Problem ATTEMPT Classify the following...Ch. 8.4 - Prob. 1PPBCh. 8.4 - Prob. 1PPCCh. 8.4 - In which of the following molecules are the bonds...Ch. 8.4 - Using data from Table 8.5, calculate the magnitude...Ch. 8.4 - Prob. 3CPCh. 8.4 - Prob. 4CPCh. 8.5 - Prob. 1PPACh. 8.5 - Prob. 1PPBCh. 8.5 - Two pairs of elements are highlighted in the...Ch. 8.5 - Identify the correct Lewis structure for formic...Ch. 8.5 - Identity the correct Lewis structure for hydrogen...Ch. 8.6 - Prob. 1PPACh. 8.6 - Prob. 1PPBCh. 8.6 - Prob. 1PPCCh. 8.6 - Determine the formal charges on H, C, and N,...Ch. 8.6 - 8.6.2 Which of the Lewis structures shown is most...Ch. 8.7 - Prob. 1PPACh. 8.7 - Practice ProblemBUILD Draw the Lewis structure for...Ch. 8.7 - Practice Problem CONCEPTUALIZE
Of the three Lewis...Ch. 8.7 - Indicate which of the following are resonance...Ch. 8.7 - 8.7.2 How many resonance structures can be drawn...Ch. 8.8 - Prob. 1PPACh. 8.8 - Prob. 1PPBCh. 8.8 - Practice Problem CONCEPTUALIZE
The hypothetical...Ch. 8.8 - In which of the following species does the central...Ch. 8.8 - Prob. 2CPCh. 8.8 - In which species does the central atom obey the...Ch. 8.8 - 8.8.4 How many lone pairs are there on the central...Ch. 8.9 - Prob. 1PPACh. 8.9 - Practice ProblemBUILD Use Lewis structures and...Ch. 8.9 - Prob. 1PPCCh. 8.9 - 8.9.1 Use data from Table 8.6 to estimate for the...Ch. 8.9 - Use data from Table 8.6 to estimate Δ H rxn for...Ch. 8.9 - Use bond enthalpies to determine Δ H rxn for the...Ch. 8.9 - Prob. 4CPCh. 8.10 - Practice ProblemATTEMPT Draw all possible...Ch. 8.10 - Prob. 1PPBCh. 8.10 - Practice ProblemCONCEPTUALIZE The Lewis structure...Ch. 8.11 - Prob. 1PPACh. 8.11 - Prob. 1PPBCh. 8.11 - Prob. 1PPCCh. 8.12 - Prob. 1PPACh. 8.12 - Prob. 1PPBCh. 8.12 - Prob. 1PPCCh. 8.13 - Prob. 1PPACh. 8.13 - Practice Problem BUILD
Using the following...Ch. 8.13 - Prob. 1PPCCh. 8 - 8.1
Which of the following atoms must always obey...Ch. 8 - Prob. 2KSPCh. 8 - Prob. 3KSPCh. 8 - Prob. 4KSPCh. 8 - What is a Lewis dot symbol? What elements do we...Ch. 8 - Use the second member of each group from Group 1A...Ch. 8 - Prob. 3QPCh. 8 - 8.4 Write Lewis dot symbols for the following...Ch. 8 - Write Lewis dot symbols for the following atoms...Ch. 8 - Prob. 6QPCh. 8 - Prob. 7QPCh. 8 - Name five metals and five nonmetals that are very...Ch. 8 - Prob. 9QPCh. 8 - Prob. 10QPCh. 8 - Prob. 11QPCh. 8 - The term molar mass was introduced in Chapter 3....Ch. 8 - Prob. 13QPCh. 8 - Prob. 14QPCh. 8 - Prob. 15QPCh. 8 - Explain how the lattice energy of an ionic...Ch. 8 - Prob. 17QPCh. 8 - Prob. 18QPCh. 8 - 8.19 Use the Born-Haber cycle outlined in Section...Ch. 8 - Calculate the lattice energy of CaCl 2 . Use data...Ch. 8 - An ionic bond is formed between a cation A + and...Ch. 8 - Prob. 22QPCh. 8 - Use Lewis dot symbols to show the transfer of...Ch. 8 - Write the Lewis dot symbols of the reactants and...Ch. 8 - 8.25 Describe Lewis’s contribution to our...Ch. 8 - Prob. 26QPCh. 8 - Prob. 27QPCh. 8 - Prob. 28QPCh. 8 - Prob. 29QPCh. 8 - Prob. 30QPCh. 8 - Prob. 31QPCh. 8 - Prob. 32QPCh. 8 - Prob. 33QPCh. 8 - Define electronegativity, and explain the...Ch. 8 - Prob. 35QPCh. 8 - Prob. 36QPCh. 8 - List the following bonds in order of increasing...Ch. 8 - Classify the following bonds as covalent, polar...Ch. 8 - 8.41 Classify the following bonds as covalent,...Ch. 8 - 8.42 List the following bonds in order of...Ch. 8 - Prob. 41QPCh. 8 - Prob. 42QPCh. 8 - Draw Lewis structures for the following molecules...Ch. 8 - Draw Lewis structures for the following molecules:...Ch. 8 - Prob. 45QPCh. 8 - Prob. 46QPCh. 8 - 8.51 Draw Lewis structures for the following ions:...Ch. 8 - Draw Lewis structures for the following ions: (a)...Ch. 8 - Prob. 49QPCh. 8 - Prob. 50QPCh. 8 - Prob. 51QPCh. 8 - Prob. 52QPCh. 8 - Prob. 53QPCh. 8 - 8.58 Draw three resonance structures for the...Ch. 8 - Prob. 55QPCh. 8 - Prob. 56QPCh. 8 - Draw three reasonable resonance structures for the...Ch. 8 - Draw three resonance structures for the molecule N...Ch. 8 - Prob. 59QPCh. 8 - Prob. 60QPCh. 8 - Prob. 61QPCh. 8 - Prob. 62QPCh. 8 - Prob. 63QPCh. 8 - Prob. 64QPCh. 8 - Prob. 65QPCh. 8 - The AlI 3 molecule has an incomplete octet around...Ch. 8 - Prob. 67QPCh. 8 - Prob. 68QPCh. 8 - 8.73 Write a Lewis structure for Does this...Ch. 8 - Prob. 70QPCh. 8 - Prob. 71QPCh. 8 - 8.76 Draw two resonance structures for the bromate...Ch. 8 - Prob. 73QPCh. 8 - What is bond enthalpy? Bond enthalpies of...Ch. 8 - Prob. 75QPCh. 8 - Prob. 76QPCh. 8 - Prob. 77QPCh. 8 - Prob. 78QPCh. 8 - For the reaction 2 C 2 H 6 ( g ) + 7 O 2 ( g ) → 4...Ch. 8 - Prob. 80QPCh. 8 - 8.85. Use average bond enthalpies from Table 8.6...Ch. 8 - Prob. 82APCh. 8 - Prob. 83APCh. 8 - Prob. 84APCh. 8 - Prob. 85APCh. 8 - Prob. 86APCh. 8 - 8.91 Describe some characteristics of an ionic...Ch. 8 - Prob. 88APCh. 8 - Prob. 89APCh. 8 - Prob. 90APCh. 8 - Prob. 91APCh. 8 - Prob. 92APCh. 8 - Prob. 93APCh. 8 - Prob. 94APCh. 8 - Prob. 95APCh. 8 - Prob. 96APCh. 8 - Prob. 97APCh. 8 - Prob. 98APCh. 8 - Prob. 99APCh. 8 - Prob. 100APCh. 8 - Which of the following species are isoelectronic:...Ch. 8 - Prob. 102APCh. 8 - 8.107 Draw two resonance structures for each...Ch. 8 - The following species have been detected in...Ch. 8 - The amide ion ( NH 2 − ) is a Brø�nsted base. Use...Ch. 8 - Prob. 106APCh. 8 - The triiodide ion ( I 3 − ) in which the I atoms...Ch. 8 - Prob. 108QPCh. 8 - In 1999, an unusual cation containing only...Ch. 8 - Prob. 110QPCh. 8 - Prob. 111QPCh. 8 - Prob. 112APCh. 8 - In the gas phase, aluminum chloride exists as a...Ch. 8 - Prob. 114APCh. 8 - Calculate Δ H º for the reaction H 2 ( g ) + I 2 (...Ch. 8 - Draw Lewis structures for the following organic...Ch. 8 - Prob. 117APCh. 8 - Prob. 118APCh. 8 - Prob. 119APCh. 8 - Write three resonance structures for (a) the...Ch. 8 - Prob. 121APCh. 8 - Prob. 122APCh. 8 - Prob. 123APCh. 8 - Prob. 124APCh. 8 - Prob. 125APCh. 8 - Prob. 126APCh. 8 - Prob. 127APCh. 8 - Among the common inhaled anesthetics are:...Ch. 8 - Prob. 129APCh. 8 - Prob. 130APCh. 8 - Prob. 131APCh. 8 - 8.136 Using this and data from Appendix 2,...Ch. 8 - Prob. 133QPCh. 8 - Prob. 134QPCh. 8 - Prob. 135QPCh. 8 - Prob. 136QPCh. 8 - Prob. 137QPCh. 8 - Prob. 138APCh. 8 - Prob. 139APCh. 8 - Although nitrogen dioxide ( NO 2 ) is a stable...Ch. 8 - 8.145 The chlorine nitrate molecule is believed...Ch. 8 - The hydroxyl radical ( OH ) plays an important...Ch. 8 - Prob. 143APCh. 8 - Prob. 144APCh. 8 - Prob. 1SEPPCh. 8 - 2. Use formal charges to choose the best of the...Ch. 8 - Prob. 3SEPPCh. 8 - Prob. 4SEPP
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