OWLV2 FOR MOORE/STANITSKI'S CHEMISTRY:
5th Edition
ISBN: 9781285460369
Author: STANITSKI
Publisher: Cengage Learning
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Question
Chapter 7, Problem 92QRT
Interpretation Introduction
Interpretation:
The maximum number of water molecules that can be hydrogen bonded directly to an acetic acid molecule should be identified and the hydrogen bonds have to be denoted with dotted lines.
Concept introduction:
Hydrogen bonding:
The attractive force that holds two polar molecules (containing Hydrogen and highly electronegative atom, such as N, O, or F) is called as hydrogen boding. This is also called as intermolecular hydrogen bonding.
The hydrogen bonding takes place within a molecule is called as intramolecular hydrogen bonding.
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Dispersion forces are produced when
an electronegative atom pulls on the electron of a hydrogen atom so much that the proton of the
hydrogen can closely interact with the electronegative atom of another molecule
electronegative atoms pull electrons toward one area of the molecule, creating regions of partial
positive and partial negative charge that are attracted to regions of other molecules with the
opposite charge
electrons are transferred from one atom to another to produce anions and cations that are then
held together in a rigid lattice
electrons in molecular compounds are constantly moving and produce short-term regions of
positive and negative charge that are attracted to regions of other molecules with the opposite
charge
For each compound in the table below, decide whether there would be any hydrogen-bondir
of the compound and molecules of water.
compound
hydrogen-bonding force
Between
Between molecules of
formula or Lewis
molecules of the
compound?
the compound and
molecules of water?
name
structure
H :O:
yes
yes
acetic acid
Н-с — с — о — н
no
no
H.
yes
yes
formyl chloride
CHOCI
no
no
H
yes
yes
methanol
H - C-0- H
no
no
H.
For each compound in the table below, decide whether there would be any hydrogen-bonding force between molecules of the compound, or between molecules
of the compound and molecules of water.
name
acetic acid
dimethyl ether
compound
hypobromous acid
formula or Lewis
structure
H :0:
H-C-C-O-H
H
H
H-C-0-C H
H
H
T
HBrO
|
H
Between
molecules of the
compound?
yes
O O
no
O yes
no
yes
hydrogen-bonding force
no
Between molecules of
the compound and
molecules of water?
O O
yes
no
yes
no
yes
no
X
Chapter 7 Solutions
OWLV2 FOR MOORE/STANITSKI'S CHEMISTRY:
Ch. 7.2 - Identify the electron-region geometry, the...Ch. 7.2 - Based on the discussion so far, identify a...Ch. 7.2 - Prob. 7.2PSPCh. 7.2 - Determine the electron-region geometry and the...Ch. 7.2 - Prob. 7.2CECh. 7.2 - Prob. 7.3ECh. 7.2 - Prob. 7.4PSPCh. 7.4 - Using hybridization and sigma and pi bonding,...Ch. 7.4 - Prob. 7.4CECh. 7.5 - Decide whether each molecule is polar and, if so,...
Ch. 7.5 - Prob. 7.5ECh. 7.6 - Prob. 7.8PSPCh. 7.6 - Prob. 7.7CECh. 7.6 - Prob. 7.9PSPCh. 7.7 - Prob. 7.8CECh. 7.7 - Prob. 7.9CECh. 7 - Write the Lewis structures and give the...Ch. 7 - The structural formula for the open-chain form of...Ch. 7 - Describe the VSEPR model. How is the model used to...Ch. 7 - What is the difference between the electron-region...Ch. 7 - Prob. 3QRTCh. 7 - Prob. 4QRTCh. 7 - If you have three electron regions around a...Ch. 7 - Prob. 6QRTCh. 7 - Prob. 7QRTCh. 7 - Prob. 8QRTCh. 7 - Prob. 9QRTCh. 7 - Prob. 10QRTCh. 7 - Prob. 11QRTCh. 7 - Prob. 12QRTCh. 7 - Prob. 13QRTCh. 7 - Prob. 14QRTCh. 7 - Prob. 15QRTCh. 7 - Prob. 16QRTCh. 7 - Write Lewis structures for XeOF2 and ClOF3. Use...Ch. 7 - Write Lewis structures for HCP and [IOF4]. Use...Ch. 7 - Prob. 19QRTCh. 7 - Prob. 20QRTCh. 7 - Explain why (I3)+ is bent, but (I3) is linear.Ch. 7 - Prob. 22QRTCh. 7 - Prob. 23QRTCh. 7 - Give approximate values for the indicated bond...Ch. 7 - Give approximate values for the indicated bond...Ch. 7 - Prob. 26QRTCh. 7 - Compare the FClF angles in ClF2+ and ClF2. From...Ch. 7 - Prob. 28QRTCh. 7 - Prob. 29QRTCh. 7 - Prob. 30QRTCh. 7 - Prob. 31QRTCh. 7 - Describe the geometry and hybridization of carbon...Ch. 7 - Describe the geometry and hybridization for each C...Ch. 7 - Describe the hybridization around the central atom...Ch. 7 - The hybridization of the two carbon atoms differs...Ch. 7 - The hybridization of the two nitrogen atoms...Ch. 7 - Identify the type of hybridization, approximate...Ch. 7 - Prob. 38QRTCh. 7 - Prob. 39QRTCh. 7 - Prob. 40QRTCh. 7 - Prob. 41QRTCh. 7 - Methylcyanoacrylate is the active ingredient in...Ch. 7 - Prob. 43QRTCh. 7 - Prob. 44QRTCh. 7 - Prob. 45QRTCh. 7 - Prob. 46QRTCh. 7 - Which of these molecules has a net dipole moment?...Ch. 7 - Prob. 48QRTCh. 7 - Use molecular structures and noncovalent...Ch. 7 - Prob. 50QRTCh. 7 - Explain why water “beads up” on a freshly waxed...Ch. 7 - Explain why water will not remove tar from your...Ch. 7 - Prob. 53QRTCh. 7 - Prob. 54QRTCh. 7 - Prob. 55QRTCh. 7 - Prob. 56QRTCh. 7 - The structural formula for vitamin C is Give a...Ch. 7 - Prob. 58QRTCh. 7 - Prob. 59QRTCh. 7 - Prob. 60QRTCh. 7 - Prob. 61QRTCh. 7 - Prob. 62QRTCh. 7 - Prob. 63QRTCh. 7 - Prob. 64QRTCh. 7 - Prob. 65QRTCh. 7 - Prob. 66QRTCh. 7 - Methylcyanoacrylate is the active ingredient in...Ch. 7 - Prob. 68QRTCh. 7 - Prob. 69QRTCh. 7 - Use Lewis structures and VSEPR theory to predict...Ch. 7 - In addition to CO, CO2, and C3O2, there is another...Ch. 7 - Prob. 72QRTCh. 7 - Prob. 73QRTCh. 7 - Prob. 74QRTCh. 7 - Prob. 75QRTCh. 7 - In the gas phase, positive and negative ions form...Ch. 7 - Prob. 77QRTCh. 7 - Prob. 78QRTCh. 7 - Prob. 79QRTCh. 7 - Prob. 80QRTCh. 7 - Prob. 81QRTCh. 7 - Prob. 82QRTCh. 7 - Prob. 83QRTCh. 7 - Prob. 84QRTCh. 7 - Prob. 85QRTCh. 7 - Prob. 86QRTCh. 7 - Prob. 87QRTCh. 7 - Prob. 88QRTCh. 7 - Prob. 89QRTCh. 7 - Prob. 90QRTCh. 7 - Prob. 91QRTCh. 7 - Prob. 92QRTCh. 7 - Prob. 93QRTCh. 7 - Prob. 94QRTCh. 7 - Which of these are examples of hydrogen bonding?Ch. 7 - Prob. 96QRTCh. 7 - Prob. 97QRTCh. 7 - Prob. 98QRTCh. 7 - Halothane, which had been used as an anesthetic,...Ch. 7 - Ketene, C2H2O, is a reactant for synthesizing...Ch. 7 - Gamma hydroxybutyric acid, GHB, infamous as a date...Ch. 7 - There are two compounds with the molecular formula...Ch. 7 - Piperine, the active ingredient in black pepper,...Ch. 7 - Prob. 105QRTCh. 7 - Two compounds have the molecular formula N3H3. One...Ch. 7 - Prob. 108QRTCh. 7 - Prob. 109QRTCh. 7 - Prob. 110QRTCh. 7 - Prob. 111QRTCh. 7 - Prob. 7.ACPCh. 7 - Prob. 7.BCPCh. 7 - Prob. 7.CCPCh. 7 - Prob. 7.DCP
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- 1 highest, 4 lowestarrow_forwardFor each compound in the table below, decide whether there would be any hydrogen-bonding force between molecules of the compound, or between molecules of the compound and molecules of water. name methanimine methylamine ammonial compound formula or Lewis structure H H-C=N-H H H 1 C 1 H H T N-H NH₂ Between molecules of the compound? yes O no Oo yes O no yes hydrogen-bonding force O no Between molecules of the compound and molecules of water? O yes O no O yes O no O yes O noarrow_forwardFor each compound in the table below, decide whether there would be any hydrogen-bonding force between molecules of the compound, or between molecules of the compound and molecules of water. compound hydrogen-bonding force Between Between molecules of formula or Lewis molecules of the the compound and molecules of water? name structure compound? yes yes iodomethane CH,I no no H :0: yes yes н —с —с-ӧ — н | acetic acid no no H :0: yes yes formic acid Н — С — ӧ — н no no O O O O O Oarrow_forward
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- Do not give handwriting solution.arrow_forwardReview Question 11.28 In a polar covalent bond, how do you determine which atom has a partial negative charge (5-) and which has a partial positive charge (8+)? The more electronegative atom in the bond between two atoms will more strongly attract electrons so it will have a partial charge because the charge. The less electronegative atom will have a partial bonding pair of electrons has been pulled away by the more electronegative atom.arrow_forward5. Both oxygen atoms in acetic acid (CH3CO₂H) are capable of hydrogen bonding, a feature that contributes greatly to the high boiling point of pure acetic acid. In water This also acetic acid molecules hydrogen bond with water molecules, a factor which increases the solubility of acetic acid in water. Depict all possible hydrogen bonds between water molecules and each oxygen of a molecule of acetic acid. Use a dotted line to highlight each hydrogen bond. Which atom on a water molecule will be attracted to an oxygen atom on acetic acid? Why? X HIC H H-C-C Ö: :O-H 1arrow_forward
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