The scanning of a sample on surface of metal by probe in a scanning tunneling microscope has to be explained. Concept introduction: In quantum mechanics , tunneling relies on probability interpretation. Consider an atom, which contains an electron near a proton (A) and another proton (B) far from proton (A). In general, energy is needed to move electron from region of proton (A) to proton (B). But in quantum mechanics, the probability of electron in the atom being located far from proton A near proton B is small but not zero. This indicates that an electron belongs to proton A can find itself close to proton B without spending much energy. The electron is said to be tunneled from one proton to another.
The scanning of a sample on surface of metal by probe in a scanning tunneling microscope has to be explained. Concept introduction: In quantum mechanics , tunneling relies on probability interpretation. Consider an atom, which contains an electron near a proton (A) and another proton (B) far from proton (A). In general, energy is needed to move electron from region of proton (A) to proton (B). But in quantum mechanics, the probability of electron in the atom being located far from proton A near proton B is small but not zero. This indicates that an electron belongs to proton A can find itself close to proton B without spending much energy. The electron is said to be tunneled from one proton to another.
The scanning of a sample on surface of metal by probe in a scanning tunneling microscope has to be explained.
Concept introduction:
In quantum mechanics, tunneling relies on probability interpretation. Consider an atom, which contains an electron near a proton (A) and another proton (B) far from proton (A). In general, energy is needed to move electron from region of proton (A) to proton (B). But in quantum mechanics, the probability of electron in the atom being located far from proton A near proton B is small but not zero. This indicates that an electron belongs to proton A can find itself close to proton B without spending much energy. The electron is said to be tunneled from one proton to another.
Predict the major organic product(s) of the following reactions. Indicate which of the following mechanisms is in operation: SN1, SN2, E1, or E2.
(c)
(4pts)
Mechanism:
heat
(E1)
CH3OH
+
1.5pts each
_E1 _ (1pt)
Br
CH3OH
(d)
(4pts)
Mechanism:
SN1
(1pt)
(e)
(3pts)
1111 I
H
10
Ill!!
H
LDA
THF (solvent)
Mechanism: E2
(1pt)
NC
(f)
Bri!!!!!
CH3
NaCN
(3pts)
acetone
Mechanism: SN2
(1pt)
(SN1)
-OCH3
OCH3
1.5pts each
2pts for either product
1pt if incorrect
stereochemistry
H
Br
(g)
“,、
(3pts)
H
CH3OH
+21
Mechanism:
SN2
(1pt)
H
CH3
2pts
1pt if incorrect
stereochemistry
H
2pts
1pt if incorrect
stereochemistry
A mixture of butyl acrylate and 4'-chloropropiophenone has been taken for proton NMR analysis. Based on this proton NMR, determine the relative percentage of each compound in the mixture
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell