(a) Interpretation: The meaning of the term ‘expanded octet’ needs to be explained. Concept introduction: The ideal structure of a given molecule is deduced based on the octet rule according to which every atom bonds to another atom such that each acquires an octet or eight electrons around it.

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Answer 1

Question

Chapter 7, Problem 77QAP

Interpretation Introduction

(a)

Interpretation:

The meaning of the term ‘expanded octet’ needs to be explained.

Concept introduction:

The ideal structure of a given molecule is deduced based on the octet rule according to which every atom bonds to another atom such that each acquires an octet or eight electrons around it.

Interpretation Introduction

(b)

Interpretation:

The meaning of the term ‘resonance’ needs to be explained.

Concept introduction:

In a given molecule, there are bonding electrons as well as in certain cases non-bonding or lone pairs of electrons. The phenomenon in which these electrons show a tendency to delocalize or move around the molecule thereby giving rise to intermediate structures is referred to as resonance.

Interpretation Introduction

(c)

Interpretation:

The meaning of the term ‘unshared electron pair’ needs to be explained.

Concept introduction:

The ideal structure of a given molecule is deduced based on the octet rule according to which every atom bonds to another atom such that each acquires an octet or eight electrons around it.

The electrons around an atom can either be involved in bonding or remain non-bonding

Interpretation Introduction

(d)

Interpretation:

The meaning of the term ‘odd electron species’ needs to be explained

Concept introduction:

The ideal structure of a given molecule is deduced based on the octet rule according to which every atom bonds to another atom such that each acquires an octet or eight electrons around it.

Species with unpaired electrons are exceptions to the octet rule, these are odd electron species

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Draw Lewis electron dot diagrams for the following species, indicating formal charges and resonance diagramswhere applicable.(a) HNC (central N atom)(b) SCN- (thiocyanate ion)(c) H2CNN (the first N atom is bonded to the carbon andthe second N)

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(a) CCI4 (b) HONO2 (c) (d) HCN CH3CH₂OH Write the electron dot formula for each of the following molecules

Answer 2

Question

Chapter 7, Problem 77QAP

Interpretation Introduction

(a)

Interpretation:

The meaning of the term ‘expanded octet’ needs to be explained.

Concept introduction:

The ideal structure of a given molecule is deduced based on the octet rule according to which every atom bonds to another atom such that each acquires an octet or eight electrons around it.

Interpretation Introduction

(b)

Interpretation:

The meaning of the term ‘resonance’ needs to be explained.

Concept introduction:

In a given molecule, there are bonding electrons as well as in certain cases non-bonding or lone pairs of electrons. The phenomenon in which these electrons show a tendency to delocalize or move around the molecule thereby giving rise to intermediate structures is referred to as resonance.

Interpretation Introduction

(c)

Interpretation:

The meaning of the term ‘unshared electron pair’ needs to be explained.

Concept introduction:

The ideal structure of a given molecule is deduced based on the octet rule according to which every atom bonds to another atom such that each acquires an octet or eight electrons around it.

The electrons around an atom can either be involved in bonding or remain non-bonding

Interpretation Introduction

(d)

Interpretation:

The meaning of the term ‘odd electron species’ needs to be explained

Concept introduction:

The ideal structure of a given molecule is deduced based on the octet rule according to which every atom bonds to another atom such that each acquires an octet or eight electrons around it.

Species with unpaired electrons are exceptions to the octet rule, these are odd electron species

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Answer 3

Question

Chapter 7, Problem 77QAP

Interpretation Introduction

(a)

Interpretation:

The meaning of the term ‘expanded octet’ needs to be explained.

Concept introduction:

The ideal structure of a given molecule is deduced based on the octet rule according to which every atom bonds to another atom such that each acquires an octet or eight electrons around it.

Interpretation Introduction

(b)

Interpretation:

The meaning of the term ‘resonance’ needs to be explained.

Concept introduction:

In a given molecule, there are bonding electrons as well as in certain cases non-bonding or lone pairs of electrons. The phenomenon in which these electrons show a tendency to delocalize or move around the molecule thereby giving rise to intermediate structures is referred to as resonance.

Interpretation Introduction

(c)

Interpretation:

The meaning of the term ‘unshared electron pair’ needs to be explained.

Concept introduction:

The ideal structure of a given molecule is deduced based on the octet rule according to which every atom bonds to another atom such that each acquires an octet or eight electrons around it.

The electrons around an atom can either be involved in bonding or remain non-bonding

Interpretation Introduction

(d)

Interpretation:

The meaning of the term ‘odd electron species’ needs to be explained

Concept introduction:

The ideal structure of a given molecule is deduced based on the octet rule according to which every atom bonds to another atom such that each acquires an octet or eight electrons around it.

Species with unpaired electrons are exceptions to the octet rule, these are odd electron species

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Answer 4

Question

Chapter 7, Problem 77QAP

Interpretation Introduction

(a)

Interpretation:

The meaning of the term ‘expanded octet’ needs to be explained.

Concept introduction:

The ideal structure of a given molecule is deduced based on the octet rule according to which every atom bonds to another atom such that each acquires an octet or eight electrons around it.

Interpretation Introduction

(b)

Interpretation:

The meaning of the term ‘resonance’ needs to be explained.

Concept introduction:

In a given molecule, there are bonding electrons as well as in certain cases non-bonding or lone pairs of electrons. The phenomenon in which these electrons show a tendency to delocalize or move around the molecule thereby giving rise to intermediate structures is referred to as resonance.

Interpretation Introduction

(c)

Interpretation:

The meaning of the term ‘unshared electron pair’ needs to be explained.

Concept introduction:

The ideal structure of a given molecule is deduced based on the octet rule according to which every atom bonds to another atom such that each acquires an octet or eight electrons around it.

The electrons around an atom can either be involved in bonding or remain non-bonding

Interpretation Introduction

(d)

Interpretation:

The meaning of the term ‘odd electron species’ needs to be explained

Concept introduction:

The ideal structure of a given molecule is deduced based on the octet rule according to which every atom bonds to another atom such that each acquires an octet or eight electrons around it.

Species with unpaired electrons are exceptions to the octet rule, these are odd electron species

Expert Solution & Answer

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Answer 5

Chapter 7, Problem 77QAP

Interpretation Introduction

(a)

Interpretation:

The meaning of the term ‘expanded octet’ needs to be explained.

Concept introduction:

The ideal structure of a given molecule is deduced based on the octet rule according to which every atom bonds to another atom such that each acquires an octet or eight electrons around it.

Interpretation Introduction

(b)

Interpretation:

The meaning of the term ‘resonance’ needs to be explained.

Concept introduction:

In a given molecule, there are bonding electrons as well as in certain cases non-bonding or lone pairs of electrons. The phenomenon in which these electrons show a tendency to delocalize or move around the molecule thereby giving rise to intermediate structures is referred to as resonance.

Interpretation Introduction

(c)

Interpretation:

The meaning of the term ‘unshared electron pair’ needs to be explained.

Concept introduction:

The ideal structure of a given molecule is deduced based on the octet rule according to which every atom bonds to another atom such that each acquires an octet or eight electrons around it.

The electrons around an atom can either be involved in bonding or remain non-bonding

Interpretation Introduction

(d)

Interpretation:

The meaning of the term ‘odd electron species’ needs to be explained

Concept introduction:

The ideal structure of a given molecule is deduced based on the octet rule according to which every atom bonds to another atom such that each acquires an octet or eight electrons around it.

Species with unpaired electrons are exceptions to the octet rule, these are odd electron species

Answer 6

Chapter 7, Problem 77QAP

Interpretation Introduction

(a)

Interpretation:

The meaning of the term ‘expanded octet’ needs to be explained.

Concept introduction:

The ideal structure of a given molecule is deduced based on the octet rule according to which every atom bonds to another atom such that each acquires an octet or eight electrons around it.

Answer 7

Chapter 7, Problem 77QAP

Interpretation Introduction

(a)

Interpretation:

The meaning of the term ‘expanded octet’ needs to be explained.

Concept introduction:

The ideal structure of a given molecule is deduced based on the octet rule according to which every atom bonds to another atom such that each acquires an octet or eight electrons around it.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The meaning of the term ‘resonance’ needs to be explained.

Concept introduction:

In a given molecule, there are bonding electrons as well as in certain cases non-bonding or lone pairs of electrons. The phenomenon in which these electrons show a tendency to delocalize or move around the molecule thereby giving rise to intermediate structures is referred to as resonance.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The meaning of the term ‘resonance’ needs to be explained.

Concept introduction:

In a given molecule, there are bonding electrons as well as in certain cases non-bonding or lone pairs of electrons. The phenomenon in which these electrons show a tendency to delocalize or move around the molecule thereby giving rise to intermediate structures is referred to as resonance.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The meaning of the term ‘unshared electron pair’ needs to be explained.

Concept introduction:

The ideal structure of a given molecule is deduced based on the octet rule according to which every atom bonds to another atom such that each acquires an octet or eight electrons around it.

The electrons around an atom can either be involved in bonding or remain non-bonding

Answer 11

Interpretation Introduction

(c)

Interpretation:

The meaning of the term ‘unshared electron pair’ needs to be explained.

Concept introduction:

The ideal structure of a given molecule is deduced based on the octet rule according to which every atom bonds to another atom such that each acquires an octet or eight electrons around it.

The electrons around an atom can either be involved in bonding or remain non-bonding

Answer 12

Interpretation Introduction

(d)

Interpretation:

The meaning of the term ‘odd electron species’ needs to be explained

Concept introduction:

The ideal structure of a given molecule is deduced based on the octet rule according to which every atom bonds to another atom such that each acquires an octet or eight electrons around it.

Species with unpaired electrons are exceptions to the octet rule, these are odd electron species

Answer 13

Interpretation Introduction

(d)

Interpretation:

The meaning of the term ‘odd electron species’ needs to be explained

Concept introduction:

The ideal structure of a given molecule is deduced based on the octet rule according to which every atom bonds to another atom such that each acquires an octet or eight electrons around it.

Species with unpaired electrons are exceptions to the octet rule, these are odd electron species

Answer 14

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Answer 15

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Answer 16

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Answer 17

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(a) Interpretation: The meaning of the term ‘expanded octet’ needs to be explained. Concept introduction: The ideal structure of a given molecule is deduced based on the octet rule according to which every atom bonds to another atom such that each acquires an octet or eight electrons around it.

Solution Summary: The author explains that the ideal structure of a given molecule is deduced based on the octet rule.

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