Chemistry: Principles and Reactions
8th Edition
ISBN: 9781305079373
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
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Question
Chapter 7, Problem 46QAP
Interpretation Introduction
(a)
Interpretation:
The identity of NNO from the context of dipoles needs to be established.
Concept introduction:
Chemical bonds can be broadly classified as ionic (formed by complete transfer of electrons) or covalent (formed by mutual sharing of electrons)- Covalent bonds can be further classified as polar, if there is an unequal distribution of electrons or non-polar in case of symmetrical distribution of electrons.
- Polar bonds have positive and negative ends called dipoles. These are absent in non-polar bonds.
Interpretation Introduction
(b)
Interpretation:
The identity of ONCl from the context of dipoles needs to be established.
Concept introduction:
- Chemical bonds can be broadly classified as ionic (formed by complete transfer of electrons) or covalent (formed by mutual sharing of electrons)
- Covalent bonds can be further classified as polar, if there is an unequal distribution of electrons or non-polar in case of symmetrical distribution of electrons.
- Polar bonds have positive and negative ends called dipoles. These are absent in non-polar bonds.
Interpretation Introduction
(c)
Interpretation:
The identity of
Concept introduction:
- Chemical bonds can be broadly classified as ionic (formed by complete transfer of electrons) or covalent (formed by mutual sharing of electrons)
- Covalent bonds can be further classified as polar, if there is an unequal distribution of electrons or non-polar in case of symmetrical distribution of electrons.
- Polar bonds have positive and negative ends called dipoles. These are absent in non-polar bonds.
Interpretation Introduction
(d)
Interpretation:
The identity of O3 from the context of dipoles needs to be established.
Concept introduction:
- Chemical bonds can be broadly classified as ionic (formed by complete transfer of electrons) or covalent (formed by mutual sharing of electrons)
- Covalent bonds can be further classified as polar, if there is an unequal distribution of electrons or non-polar in case of symmetrical distribution of electrons.
- Polar bonds have positive and negative ends called dipoles. These are absent in non-polar bonds.
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Why does NO3- Violate the octet rule
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Chapter 7 Solutions
Chemistry: Principles and Reactions
Ch. 7 - Prob. 1QAPCh. 7 - Prob. 2QAPCh. 7 - Follow the directions of Question 1 for (a) IO2-...Ch. 7 - Follow the directions of Question 1 for (a) CIF4-...Ch. 7 - Follow the directions of Question 1 for (a) OCl2...Ch. 7 - Follow the directions of Question 1 for (a) C22-...Ch. 7 - Oxalic acid, H2C2O4, is a poisonous compound found...Ch. 7 - Radio astronomers have detected the isoformyl ion,...Ch. 7 - Draw Lewis structures for the following species....Ch. 7 - Follow the directions of Question 9 for the...
Ch. 7 - Dinitrogen pentoxide, N2O5, when bubbled into...Ch. 7 - Formic acid is the irritating substance that gets...Ch. 7 - Two different molecules have the formula C2H2Cl2....Ch. 7 - Two different molecules have the formula C2H6O....Ch. 7 - Prob. 15QAPCh. 7 - Prob. 16QAPCh. 7 - Write a Lewis structure for (a) XeF3+ (b) PCl4+...Ch. 7 - Write a Lewis structure for (a) BCl4 (b) ClO- (c)...Ch. 7 - Write reasonable Lewis structures for the...Ch. 7 - Write reasonable Lewis structures for the...Ch. 7 - Prob. 21QAPCh. 7 - Draw resonance structures for (a) SeO3 (b) CS32-...Ch. 7 - Prob. 23QAPCh. 7 - Prob. 24QAPCh. 7 - The skeleton structure for disulfur dinitride,...Ch. 7 - Borazine, B3N3H6, has the skeleton Draw the...Ch. 7 - What is the formal charge on the indicated atom in...Ch. 7 - Prob. 28QAPCh. 7 - Below are two different Lewis structures for...Ch. 7 - Below are two different Lewis structures for the...Ch. 7 - Predict the geometry of the following species: (a)...Ch. 7 - Predict the geometry of the following species: (a)...Ch. 7 - Predict the geometry of the following species: (a)...Ch. 7 - Predict the geometry of the following species: (a)...Ch. 7 - Predict the geometry of the following species: (a)...Ch. 7 - Predict the geometry of the following species: (a)...Ch. 7 - Give all the ideal bond angles (109.5, 120, or...Ch. 7 - Prob. 38QAPCh. 7 - Prob. 39QAPCh. 7 - An objectionable component of smog is acetyl...Ch. 7 - The uracil molecule is one of the bases in DNA....Ch. 7 - Niacin is one of the B vitamins (B3). Estimate the...Ch. 7 - Which of the species with octets in Question 31...Ch. 7 - Which of the species with octets in Question 32...Ch. 7 - Which of the species with octets in Question 33...Ch. 7 - Prob. 46QAPCh. 7 - There are three compounds with the formula...Ch. 7 - There are two different molecules with the formula...Ch. 7 - Give the hybridization of the central atom in each...Ch. 7 - Give the hybridization of the central atom in each...Ch. 7 - Give the hybridization of the central atom in each...Ch. 7 - Give the hybridization of the central atom in each...Ch. 7 - Give the hybridization of the central atom in each...Ch. 7 - Give the hybridization of the central atom in each...Ch. 7 - In each of the following polyatomic ions, the...Ch. 7 - Follow the directions of Question 55 for the...Ch. 7 - Give the hybridization of each atom (except H) in...Ch. 7 - Acrylonitrile, C3H3N is the building mer Orlon....Ch. 7 - What is the hybridization of nitrogen inCh. 7 - What is the hybridization of carbon inCh. 7 - Give the hybridization of the central atom...Ch. 7 - Give the hybridization of the central atom...Ch. 7 - Give the number of sigma and pi bonds in the...Ch. 7 - Give the number of sigma and pi bonds in the...Ch. 7 - Give the number of sigma and pi bonds in each...Ch. 7 - Give the number of sigma and pi bonds in each...Ch. 7 - In which of the following molecules does the...Ch. 7 - Consider the pyrosulfate ion, S2O72-. It has no...Ch. 7 - Consider acetyl salicylic acid, better known as...Ch. 7 - Complete the table on next page.Ch. 7 - Given the following electro negativities...Ch. 7 - Based on the concept of formal charge, what is the...Ch. 7 - Describe the geometry of the species in which...Ch. 7 - Consider the following molecules: SiH4, PH3, H2S....Ch. 7 - Prob. 75QAPCh. 7 - In each of the following molecules, a central atom...Ch. 7 - Prob. 77QAPCh. 7 - A compound of chlorine and fluorine, CIFx, reacts...Ch. 7 - Draw the Lewis structure and describe the geometry...Ch. 7 - Consider the polyatomic ion IO65-. How many pairs...Ch. 7 - It is possible to write a simple Lewis structure...Ch. 7 - Phosphoryl chloride, POCl3, has the skeleton...
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- Explain why nonmetal atoms in Period 3 and beyond can accommodate greater than an octet of electrons and those in Period 2 cannot do so.arrow_forwardGive the number of sigma and pi bonds in each species in Question 59.arrow_forwardWhich elements can have expanded octets? Which elements cannot have expanded octets?arrow_forward
- 29. Which of the following particles has a central atom that does NOT obey the octet rule in its most stable form? (А) HCN (B) H2O (C) BеНz (D) PCI3arrow_forwardis it acceptable to have more than an octet of electrons on an element in period 3 or below? true or falsearrow_forwardIn which of the following does the central atom obey the octet rule: NO2, SF4, NH3, SO3, ClO2, and ClO2-? Are any of these species odd-electron molecules or ions?arrow_forward
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