(a) Interpretation: Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted. Concept introduction: The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds. There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

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Answer 1

Question

Chapter 7, Problem 7.56AP

Interpretation Introduction

(a)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

Interpretation Introduction

(b)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

Interpretation Introduction

(c)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

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4. Provide a clear arrow-pushing mechanism for each of the following reactions. Do not skip proton transfers, do not combine steps, and make sure your arrows are clear enough to be interpreted without ambiguity. a. 2. 1. LDA 3. H3O+ HO

b. H3C CH3 H3O+ ✓ H OH

2. Provide reagents/conditions to accomplish the following syntheses. More than one step is required in some cases. a. CH3

Answer 2

Question

Chapter 7, Problem 7.56AP

Interpretation Introduction

(a)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

Interpretation Introduction

(b)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

Interpretation Introduction

(c)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

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Answer 3

Question

Chapter 7, Problem 7.56AP

Interpretation Introduction

(a)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

Interpretation Introduction

(b)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

Interpretation Introduction

(c)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

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Answer 4

Question

Chapter 7, Problem 7.56AP

Interpretation Introduction

(a)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

Interpretation Introduction

(b)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

Interpretation Introduction

(c)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

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Answer 5

Chapter 7, Problem 7.56AP

Interpretation Introduction

(a)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

Interpretation Introduction

(b)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

Interpretation Introduction

(c)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

Answer 6

Chapter 7, Problem 7.56AP

Interpretation Introduction

(a)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

Answer 7

Chapter 7, Problem 7.56AP

Interpretation Introduction

(a)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

Answer 10

Interpretation Introduction

(c)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

Answer 11

Interpretation Introduction

(c)

Interpretation:

Whether the given compound is conformational diastereomers, conformational enantiomers or identical is to be predicted.

Concept introduction:

The saturated six membered ring compounds are mostly expressed and explained in the chair conformations. This is because chair conformation is the most stable conformation of cyclohexane. Therefore, the chair conformation is most helpful in the studies of six carbon ring compounds.

There are two forms of chair conformation one is axial form if the substituent is at axial position and other is equatorial form if the substituent is at equatorial position.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 7 - Prob. 7.1P Ch. 7 - Prob. 7.2P Ch. 7 - Prob. 7.3P Ch. 7 - Prob. 7.4P Ch. 7 - Prob. 7.5P Ch. 7 - Prob. 7.6P Ch. 7 - Prob. 7.7P Ch. 7 - Prob. 7.8P Ch. 7 - Prob. 7.9P Ch. 7 - Prob. 7.10P

Solution Summary: The author explains that the saturated six-membered ring compounds are expressed and explained in the chair conformations.

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