Principles of Instrumental Analysis
Principles of Instrumental Analysis
7th Edition
ISBN: 9781305577213
Author: Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher: Cengage Learning
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Chapter 7, Problem 7.3QAP

The Wien displacement law states that the wavelength maximum in micrometers for blackbody radiation isgiven by the relationship
   λ max T = 2.90 × 10 3
where T is the temperature in kelvins. Calculate the wavelength maximum for a blackbody that has been heated to (a) 4500 K, (b) 250 K, and (c) 1250 K.

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The acid-base indicator HX undergoes the following reaction in a dilute aqueous solution: HX (color 1) H+ + X- (color 2). The following absorbance data were obtained for a 0.00035 M solution of HX in 0.1 M NaOH and 0.1 M HCI. Measurements were made at wavelengths of 450 nm and 620 nm using a 1.0 cm glass cuvette. 450 620 A(460 nm) A(630 nm) 0.1 M NaOH 0.1 M HCI 0.065 0.435 0.895 0.150 In the 0.1M NaOH solution, the indicator will be almost 100% in the X- form, while in 0.1M HCI, the indicator will be nearly 100% protonated (HX). Calculate the acid dissociation constant for the indicator if a pH=5 buffer solution containing a very small amount of indicator exhibits an absorbance of 0.567 at 450 nm and 0.395 at 620 nm (measured in a 1 cm glass cuvette).
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