Principles of Instrumental Analysis
7th Edition
ISBN: 9781305577213
Author: Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher: Cengage Learning
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Chapter 7, Problem 7.6QAP
Describe the differences and similarities between spontaneous and stimulated emission.
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Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass
spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained.
Draw the structures of these fragments.
For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.
Chapter 7 Solutions
Principles of Instrumental Analysis
Ch. 7 - Prob. 7.1QAPCh. 7 - Prob. 7.2QAPCh. 7 - The Wien displacement law states that the...Ch. 7 - Prob. 7.4QAPCh. 7 - Prob. 7.5QAPCh. 7 - Describe the differences and similarities between...Ch. 7 - Prob. 7.7QAPCh. 7 - Prob. 7.8QAPCh. 7 - Prob. 7.9QAPCh. 7 - Prob. 7.10QAP
Ch. 7 - Why is glass better than fused silica as a prism...Ch. 7 - Prob. 7.12QAPCh. 7 - Prob. 7.13QAPCh. 7 - Prob. 7.14QAPCh. 7 - Prob. 7.15QAPCh. 7 - Prob. 7.16QAPCh. 7 - Prob. 7.17QAPCh. 7 - Prob. 7.18QAPCh. 7 - Prob. 7.19QAPCh. 7 - Prob. 7.20QAPCh. 7 - Prob. 7.21QAPCh. 7 - Prob. 7.22QAPCh. 7 - Prob. 7.23QAPCh. 7 - Prob. 7.24QAP
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